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We present two algorithms, one quantum and one classical, for estimating partition functions of quantum spin Hamiltonians. The former is a DQC1 (Deterministic quantum computation with one clean qubit) algorithm, and the first such for…

Quantum Physics · Physics 2023-02-01 Andrew Jackson , Theodoros Kapourniotis , Animesh Datta

The expectation value of the Hamiltonian using a model wave function is widely used to estimate the eigenvalues of electronic Hamiltonians. We explore here a modified formula for models based on long-range interaction. It scales differently…

Chemical Physics · Physics 2024-06-13 Anthony Scemama , Andreas Savin

We revisit quantum phase estimation algorithms for the purpose of obtaining the energy levels of many-body Hamiltonians and pay particular attention to the statistical analysis of their outputs. We introduce the mean phase direction of the…

Quantum Physics · Physics 2020-08-20 P. M. Q. Cruz , G. Catarina , R. Gautier , J. Fernández-Rossier

Over the past three decades significant reductions have been made to the cost of estimating ground-state energies of molecular Hamiltonians with quantum computers. However, comparatively little attention has been paid to estimating the…

Identifying the Hamiltonian of a quantum system from experimental data is considered. General limits on the identifiability of model parameters with limited experimental resources are investigated, and a specific Bayesian estimation…

Quantum Physics · Physics 2019-10-15 S. G. Schirmer , F. C. Langbein

The Hamiltonian operator plays a central role in quantum theory being a generator of unitary quantum dynamics. Its expectation value describes the energy of a quantum system. Typically being a non-unitary operator, the action of the…

Quantum Physics · Physics 2021-08-03 Tatiana A. Bespalova , Oleksandr Kyriienko

A central roadblock in the realization of variational quantum eigensolvers on quantum hardware is the high overhead associated with measurement repetitions, which hampers the computation of complex problems, such as the simulation of mid-…

Quantum Physics · Physics 2026-05-13 Davide Bincoletto , Jakob S. Kottmann

Imaginary-time evolution plays an important role in algorithms for computing ground-state and thermal equilibrium properties of quantum systems, but can be challenging to simulate on classical computers. Many quantum algorithms for…

Quantum Physics · Physics 2025-07-22 Annie Ray , Esha Swaroop , Ningping Cao , Michael Vasmer , Anirban Chowdhury

The estimation of many-qubit observables is an essential task of quantum information processing. The generally applicable approach is to decompose the observables into weighted sums of multi-qubit Pauli strings, i.e., tensor products of…

Quantum Physics · Physics 2025-03-17 Liubov A. Markovich , Attaallah Almasi , Sina Zeytinoğlu , Johannes Borregaard

The preparation of Hamiltonian eigenstates is essential for many applications in quantum computing; the efficiency with which this can be done is of key interest. A canonical approach exploits the quantum phase estimation (QPE) algorithm.…

Quantum Physics · Physics 2022-12-05 Richard Meister , Simon C. Benjamin

We study the efficiency of algorithms simulating a system evolving with Hamiltonian $H=\sum_{j=1}^m H_j$. We consider high order splitting methods that play a key role in quantum Hamiltonian simulation. We obtain upper bounds on the number…

Quantum Physics · Physics 2010-10-12 Anargyros Papageorgiou , Chi Zhang

Efficiently characterising quantum systems, verifying operations of quantum devices and validating underpinning physical models, are central challenges for the development of quantum technologies and for our continued understanding of…

Estimating parameters of quantum systems is usually done by performing a sequence of predetermined experiments and post-processing the resulting data. It is known that online design, where the choice of the next experiment is based on the…

Quantum Physics · Physics 2018-06-08 Ian Hincks , Thomas Alexander , Michal Kononenko , Benjamin Soloway , David G. Cory

We consider the problem of learning the Hamiltonian of a quantum system from estimates of Gibbs-state expectation values. Various methods for achieving this task were proposed recently, both from a practical and theoretical point of view.…

Quantum Physics · Physics 2024-10-31 Adam Artymowicz , Hamza Fawzi , Omar Fawzi , Samuel O. Scalet

The variational quantum eigensolver (VQE) stands as a prominent quantum-classical hybrid algorithm for near-term quantum computers to obtain the ground states of molecular Hamiltonians in quantum chemistry. However, due to the…

Quantum Physics · Physics 2024-02-28 Chenfeng Cao , Hiroshi Yano , Yuya O. Nakagawa

Precision control of a quantum system requires accurate determination of the effective system Hamiltonian. We develop a method for estimating the Hamiltonian parameters for some unknown two-state system and providing uncertainty bounds on…

Phase estimation is a quantum algorithm for measuring the eigenvalues of a Hamiltonian. We propose and rigorously analyse a randomized phase estimation algorithm with two distinctive features. First, our algorithm has complexity independent…

Quantum Physics · Physics 2022-08-09 Kianna Wan , Mario Berta , Earl T. Campbell

We address quantum estimation in situations where one has at disposal data from the measurement of an incomplete set of observables and some a priori information on the state itself. By expressing the a priori information in terms of a bias…

Quantum Physics · Physics 2009-11-13 Stefano Olivares , Matteo G. A. Paris

We derive out a complete series expression of Hamiltonian eigenvalues without any approximation and cut in the general quantum systems based on Wang's formal framework \cite{wang1}. In particular, we then propose a calculating approach of…

Quantum Physics · Physics 2009-11-12 Zhou Li , An Min Wang

We address several estimation problems in quantum optics by means of the maximum-likelihood principle. We consider Gaussian state estimation and the determination of the coupling parameters of quadratic Hamiltonians. Moreover, we analyze…

Quantum Physics · Physics 2009-11-06 G. Mauro D'Ariano , Matteo G. A. Paris , Massimiliano F. Sacchi