Related papers: Modeling Complex Organic Molecules Formation in Co…
Context. The number of identified complex organic molecules (COMs) in inter- and circumstellar gas-phase environments is steadily increasing. Recent laboratory studies show that many such species form on icy dust grains. At present only…
Hot molecular cores (HMCs) are intermediate stages of high-mass star formation and are also known for their rich emission line spectra at (sub-)mm wavebands. The observed spectral feature of HMCs such as total number of emission lines and…
We investigate the chemical segregation of complex O-bearing species (including the largest and most complex ones detected to date in space) towards Orion KL, the closest high-mass star-forming region. The molecular line images obtained…
No statistical study of COMs toward a large sample of high-mass protostars with ALMA has been carried out so far. We aim to study six N-bearing species: CH$_3$CN, HNCO, NH$_2$CHO, C$_2$H$_5$CN, C$_2$H$_3$CN and CH$_3$NH$_2$ in a large…
Dimethyl ether is one of the most abundant interstellar complex organic molecules. Yet its formation route remains elusive. In this work, we have performed electronic structure and kinetics calculations to derive the rate coefficients for…
Complex Organic Molecules (COMs) are believed to form in the ice mantle of dust grains and are released to the gas by thermal sublimation when grain mantles are heated to temperatures of $T_{\rm d}\gtrsim 100\,\rm K$. However, some COMs are…
The reactivity of interstellar carbon atoms (C) on the water-dominated ices is one of the possible ways to form interstellar complex organic molecules (iCOMs). In this work, we report a quantum chemical study of the coupling reaction of C…
Classical hot cores are rich in molecular emission, and they show a high abundance of complex organic molecules (COMs). The emergence of molecular complexity is poorly constrained in the early evolution of hot cores. Using the Atacama Large…
Cooperative adsorption of gases by porous frameworks permits more efficient uptake and removal than does the more usual non-cooperative (Langmuir-type) adsorption. Cooperativity, signaled by a step-like isotherm, is usually attributed to a…
Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…
We review recent studies of organic molecule formation in dense molecular clouds and in comets. We summarise the known organic inventories of molecular clouds and recent comets, particularly Hale-Bopp. The principal chemical formation…
Molecular inventories in starless cores are powerful tools for probing the physical and chemical structures at the earliest stages of star formation. Wide-band spectral scans are invaluable for obtaining a comprehensive view of the chemical…
Molecular oxygen has been detected in the coma of comet 67P/Churyumov-Gerasimenko with abundances in the 1-10% range by the ROSINA-DFMS instrument on board the Rosetta spacecraft. Here we find that the radiolysis of icy grains in…
Astrophysical observations show complex organic molecules (COMs) in the gas phase of protoplanetary disks. X-rays emitted from the central young stellar object (YSO) that irradiate interstellar ices in the disk, followed by the ejection of…
A number of recent experimental studies have shown that solid-state complex organic molecules (COMs) can form under conditions that are relevant to the CO freeze-out stage in dense clouds. In this work, we show that alcohols can be formed…
Complex organic molecules (COMs) are known to be abundant toward some low-mass young stellar objects (YSOs), but how these detections relate to typical COM abundance are not yet understood. We aim to constrain the frequency distribution of…
We present an extended version of the 2-phase gas-grain code NAUTILUS to the 3-phase modelling of gas and grain chemistry of cold cores. In this model, both the mantle and the surface are considered as chemically active. We also take into…
Interstellar complex organic molecules (COMs) in solar-like young stellar objects (YSOs), particularly within protostellar disks, are of significant interest due to their potential connection to prebiotic chemistry in emerging planetary…
In star-forming regions, molecular cloud history and dynamics set the trend in the chemical composition. Ice formation, in particular, is affected by the evolution of physical conditions, which can lead to different ice compositions within…
We present a detailed model for the thermal balance, chemistry, and radiative transfer within quiescent dense molecular cloud cores that contain a central protostar. Large variations in the gas temperature are expected to affect the…