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Under cold conditions in dense cores, gas-phase molecules and atoms are depleted from the gas-phase to the surface of interstellar grains. Considering the time scales and physical conditions within these cores, a portion of these molecules…

Astrophysics of Galaxies · Physics 2021-08-11 V. Wakelam , E. Dartois , M. Chabot , S. Spezzano , D. Navarro-Almaida , J. -C. Loison , A. Fuente

Cold atomic and molecular gas are commonly observed in the winds of both external galaxies and the Milky Way, yet the survival and origin of these cool phases within hot galactic winds is poorly understood. To help gain insight into these…

Millimeter and centimeter observations are discovering an increasing number of interstellar complex organic molecules (iCOMs) in a large variety of star forming sites, from the earliest stages of star formation to protoplanetary disks and…

Instrumentation and Methods for Astrophysics · Physics 2021-06-09 Maria Angela Corazzi , John Robert Brucato , Giovanni Poggiali , Linda Podio , Davide Fedele , Claudio Codella

We present experimental constraints on the insertion of oxygen atoms into methane to form methanol in astrophysical ice analogs. In gas-phase and theoretical studies this process has previously been demonstrated to have a very low or…

Earth and Planetary Astrophysics · Physics 2017-08-23 Jennifer B. Bergner , Karin I. Oberg , Mahesh Rajappan

We present a new model for the creation of cool cores in rich galaxy clusters within a LambdaCDM cosmological framework using the results from high spatial dynamic range, adaptive mesh hydro/N-body simulations. It is proposed that cores of…

Astrophysics · Physics 2007-05-23 J. O. Burns , P. M. Motl , M. L. Norman , G. L. Bryan

Complex Organic Molecules (COMs) have been found toward low-mass protostars but the origins of the COM emission are still unclear. It can be associated with, for example, hot corinos, outflows, and/or accretion shock/disk atmosphere. We…

Complex organic molecules (COMs) have been observed towards several low-mass young stellar objects (LYSOs). Small and heterogeneous samples have so far precluded conclusions on typical COM abundances, as well as the origin(s) of abundance…

Solar and Stellar Astrophysics · Physics 2017-06-21 Jennifer B. Bergner , Karin I. Öberg , Robin T. Garrod , Dawn M. Graninger

This paper presents a systematic survey of the deuterated and 13C isotopologues of a variety of oxygen-bearing complex organic molecules on Solar System scales toward the protostar IRAS 16293-2422B. We use the data from an unbiased…

The large number of possible structures of metal-organic frameworks (MOFs) and their limitless potential applications has motivated molecular modelers and researchers to develop methods and models to efficiently assess MOF performance. Some…

Materials Science · Physics 2021-10-04 Krishnendu Mukherjee , Alexander W. Dowling , Yamil Colón

The association reaction S + CO {\to} OCS + hnu has been identified as being particularly important for the prediction of gas-phase OCS abundances by chemical models of dark clouds. We performed detailed ab-initio calculations for this…

Astrophysics of Galaxies · Physics 2015-06-03 Jean-Christophe Loison , Philippe Halvick , Astrid Bergeat , Kevin M. Hickson , Valentine Wakelam

Recent observations have shown that Nitrogen-bearing complex organic species are present in large quantities in star-forming regions. Thus, investigating the N-bearing species in a hot molecular core, such as G10.47+0.03, is crucial to…

Astrophysics of Galaxies · Physics 2023-01-18 Suman Kumar Mondal , Wasim Iqbal , Prasanta Gorai , Bratati Bhat , Valentine Wakelam , Ankan Das

Methanol ice is embedded in interstellar ice mantles present in dense molecular clouds. We aim to measure the sputtering efficiencies starting from different ice mantles of varying compositions experimentally, in order to evaluate their…

Astrophysics of Galaxies · Physics 2020-02-19 E. Dartois , M. Chabot , A. Bacmann , P. Boduch , A. Domaracka , H. Rothard

Transparent conducting oxides (TCOs) play an essential role in modern optoelectronic devices through their combination of electrical conductivity and optical transparency. We review recent progress in our understanding of multi-component…

Materials Science · Physics 2013-09-18 Aron Walsh , Juarez L. F. Da Silva , Su-Huai Wei

Despite its potential reactivity due to ring strain, ethylene oxide (c-C2H4O) is a complex molecule that seems to be stable under the physical conditions of an interstellar dense core; indeed it has been detected towards several high-mass…

Astrophysics of Galaxies · Physics 2015-06-11 A. Occhiogrosso , S. Viti , M. D. Ward , S. D. Price

Observational studies reveal that complex organic molecules (COMs) can be found in various objects associated with different star formation stages. The identification of COMs in prestellar cores, i.e., cold environments in which thermally…

Solar and Stellar Astrophysics · Physics 2017-06-28 Gleb Fedoseev , Ko-Ju Chuang , Sergio Ioppolo , Danna Qasim , Ewine F. van Dishoeck , Harold Linnartz

In cold molecular clouds, UV photolysis of icy grain mantles generates radicals that lead to new molecule formation. When radical diffusion is limited by low temperatures, oxygen atom addition and insertion reactions, enabled by photolysis…

Astrophysics of Galaxies · Physics 2025-07-29 Michelle R. Brann , Karin I. Öberg , Mahesh Rajappan

(Abridged) Complex organic molecules (COMs) are considered essential precursors to prebiotic species. While COMs were once expected to be efficiently destroyed under UV-irradiated conditions, detections in photodissociation regions (PDRs)…

We present the results of a spectral-line survey of the W51e1/e2 star-forming region at 68-88 GHz. 79 molecules and their isotopologues were detected, from simple diatomic or triatomic molecules, such as SO, SiO, and CCH, to complex organic…

Remote and in-situ observations of cometary gases have revealed the presence of a wealth of complex organic molecules, including carbon chains, alcohols, imines and the amino acid glycine. Such chemical complexity in cometary material…

Earth and Planetary Astrophysics · Physics 2021-04-28 M. A Cordiner , S. B. Charnley

We develop a detailed chemical model for the starless cores of strongly magnetized molecular clouds, with the ambipolar diffusion-driven dynamic evolution of the clouds coupled to the chemistry through ion abundances. We concentrate on two…

Astrophysics · Physics 2009-11-07 Zhi-Yun Li , V. I. Shematovich , D. S. Wiebe , B. M. Shustov
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