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Despite the importance of the Second Law of Thermodynamics, it is not absolute. Statistical mechanics implies that, given sufficient time, systems near equilibrium will spontaneously fluctuate into lower-entropy states, locally reversing…

High Energy Physics - Theory · Physics 2015-05-30 Anthony Aguirre , Sean M. Carroll , Matthew C. Johnson

Sub-Gaussian and subexponential distributions are introduced and applied to study the fluctuation-response relation out of equilibrium. A bound on the difference in expected values of an arbitrary sub-Gaussian or subexponential physical…

Statistical Mechanics · Physics 2020-11-04 Yan Wang

The microscopic foundation of the generalized equilibrium statistical mechanics based on the Tsallis entropy is given by using the Gibbs idea of statistical ensembles of the classical and quantum mechanics. The equilibrium distribution…

Statistical Mechanics · Physics 2007-05-23 A. S. Parvan

In this paper we develop a generalized formalism for equilibrium thermodynamic systems when an information is shared between the system and the reservoir. The information results in a correction to the entropy of the system. This extension…

Statistical Mechanics · Physics 2013-05-10 Alessio Gagliardi , Aldo Di Carlo

The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…

Soft Condensed Matter · Physics 2009-10-30 Elliott H. Lieb , Jakob Yngvason

A continuum plasticity model for metals is presented from considerations of non-equilibrium thermodynamics. Of specific interest is the application of a fluctuation relation that subsumes the second law of thermodynamics en route to…

Materials Science · Physics 2016-03-31 S Roy Chowdhury , D Roy , J N Reddy

In the framework of Lindblad theory for open quantum systems, we calculate the entropy of a damped quantum harmonic oscillator which is initially in a quasi-free state. The maximally predictable states are identified as those states…

Quantum Physics · Physics 2016-09-08 Gh. -S. Paraoanu

We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open…

Quantum Physics · Physics 2022-05-31 Alessandra Colla , Heinz-Peter Breuer

The thermodynamic uncertainty relation expresses a universal trade-off between precision and entropy production, which applies in its original formulation to current observables in steady-state systems. We generalize this relation to…

Statistical Mechanics · Physics 2018-12-06 Timur Koyuk , Udo Seifert , Patrick Pietzonka

Traditional derivation of Gibbs canonical distribution and the justification of thermodynamics are based on the assumption concerning an isoenergetic ergodicity of a system of $n$ weakly interacting identical subsystems and passage to the…

Exactly Solvable and Integrable Systems · Physics 2007-05-23 V. V. Kozlov

The paper concerns the theory of parabolic equations on a broad class of closed subsets of Euclidean space possessing a kind of tangent structure. A necessary framework for considering evolutionary problems is developed, and fundamental…

Analysis of PDEs · Mathematics 2023-11-07 Łukasz Chomienia

Quantum many-body states that frequently appear in physics often obey an entropy scaling law, meaning that an entanglement entropy of a subsystem can be expressed as a sum of terms that scale linearly with its volume and area, plus a…

Quantum Physics · Physics 2021-05-26 Isaac H. Kim

When liquids are cooled sufficiently rapidly below their melting temperature, they may bypass crystalization and, instead, enter a long-lived metastable supercooled state that has long been the focus of intense research. Although they…

Statistical Mechanics · Physics 2023-12-05 Zohar Nussinov

We derive a variational expression for the correlation time of physical observables in steady-state diffusive systems. As a consequence of this variational expression, we obtain lower bounds on the correlation time, which provide speed…

Statistical Mechanics · Physics 2023-03-24 Andreas Dechant , Jerome Garnier-Brun , Shin-ichi Sasa

According to contemporary views, equilibrium constant is relevant only to true thermodynamic equilibria in isolated systems with one chemical reaction. The paper presents a novel formula that ties-up equilibrium constant and chemical system…

Chemical Physics · Physics 2008-02-11 B. Zilbergleyt

The article presents results of preliminary study of solutions to recently offered basic thermodynamic equation for equilibrium in chemical systems with focus on chaotic behavior. Classical part of that equation was investigated earlier in…

Chemical Physics · Physics 2016-09-08 B. Zilbergleyt

The equations of state for an ideal generalized gas, like an ideal quantum gas, are expressed in terms of power laws of the temperature. The reduction of an ideal generalized gas to an ideal classical case occurs when the characteristic…

Statistical Mechanics · Physics 2015-06-25 B. H. Lavenda

We investigate the long-time behavior of solutions of quasilinear hyperbolic systems with transparent boundary conditions when small source terms are incorporated in the system. Even if the finite-time stability of the system is not…

Analysis of PDEs · Mathematics 2017-09-29 Martin Gugat , Vincent Perrollaz , Lionel Rosier

For a colloidal particle driven by a constant force across a periodic potential, we investigate the distribution of entropy production both experimentally and theoretically. For short trajectories, the fluctuation theorem holds…

Statistical Mechanics · Physics 2009-11-13 T. Speck , V. Blickle , C. Bechinger , U. Seifert

For different phases to coexist in equilibrium at constant temperature $T$ and pressure $P$, the condition of equal chemical potential $\mu$ must be satisfied. This condition dictates that, for a single-component system, the maximum number…

Soft Condensed Matter · Physics 2016-11-23 Kenji Akahane , John Russo , Hajime Tanaka