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Polydisperse systems are commonly encountered when dealing with soft matter in general or any non simple fluid. Yet their treatment within the framework of statistical thermodynamics is a delicate task as the latter has been essentially…
Quantum thermodynamics with open systems is often based on the quantum optical weak-coupling master equation or on operational repeated interaction models, whereas early works on thermalisation and on decoherence theory were mostly…
Understanding better the dynamics and steady states of systems strongly coupled to thermal baths is a great theoretical challenge with promising applications in several fields of quantum technologies. Among several strategies to gain access…
Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…
We formulate the problem of approach to equilibrium in algebraic quantum statistical mechanics and study some of its structural aspects, focusing on the relation between the zeroth law of thermodynamics (approach to equilibrium) and the…
The minimum entropy production principle provides an approximative variational characterization of close-to-equilibrium stationary states, both for macroscopic systems and for stochastic models. Analyzing the fluctuations of the empirical…
For a closed bi-partite quantum system partitioned into system proper and environment we interprete the microcanonical and the canonical condition as constraints for the interaction between those two subsystems. In both cases the possible…
The steady states of two gases of hard spheres or disks separated by an adiabatic piston in presence of a temperature gradient are discussed. The temperature field is generated by two thermal walls at different temperatures, each of them in…
We propose a means for constructing highly accurate equations of state (EOS) for elemental solids and liquids essentially from first principles, based upon a particular decomposition of the underlying condensed matter Hamiltonian for the…
This work extends the Cahn--Larch\'e thermodynamic framework to binary alloys in which two coherent solid phases coexist with an incoherent liquid and investigates how coherency strain energy modifies classical eutectic and peritectic…
This work presents a general unifying theoretical framework for quantum non-equilibrium systems. It is based on a re-statement of the dynamical problem as one of inferring the distribution of collision events that move a system toward…
The equilibrium conditions of a system consisting of a box with gas divided by a piston are revised. The apparent indetermination of the problem is solved by explicitly imposing the constancy of the internal energy when the Entropy Maximum…
Steady-state flow of an incompressible fluid in parallel pipes can simultaneously satisfy two contradictory extremum principles in the entropy production, depending on the flow conditions. For a constant total flow rate, the flow can…
We present a general sufficiency condition for the presence of multipartite entanglement in thermal states stemming from the ground state entanglement. The condition is written in terms of the ground state entanglement and the partition…
A theory of quantum state reduction is advanced. It is based on two principles: (1) Gauge decomposition; (2) Maximum entropy. To wit: (1) The reduction decomposition of a state vector is the Schmidt decomposition with respect to the states…
Thermodynamic extensivity is commonly introduced as a postulate -- the homogeneity of degree one in thermodynamic potentials. We provide a constructive derivation of this property from microscopic conditions on the pair potential, without…
We derive a general approximate solution to the problem of minimizing the conditional entropy of a qudit-qubit system resulting from a local projective measurement on the qubit, which is valid for general entropic forms and becomes exact in…
A general nonequilibrium thermodynamic theory is developed for time-dependent Langevin dynamics, starting from the common definition of nonequilibrium Gibbs entropy. It is shown that the notations appearing in the First and the Second Law…
The long-time relaxation of ideal two dimensional magnetohydrodynamic turbulence subject to the conservation of two infinite families of constants of motion---the magnetic and the "cross" topology invariants--is examined. The analysis of…
Attempts to establish microcanonical entropy as an adiabatic invariant date back to works of Gibbs and Hertz. More recently, a consistency relation based on adiabatic invariance has been used to argue for the validity of Gibbs (volume)…