Related papers: Formulation of Entropy through Work by Carnot Mach…

We present a new outlook on the climate system thermodynamics, studying some of its macroscopic properties in terms of the 1st and 2nd laws of thermodynamics. We review and clarify the notion of efficiency of the climate system by…

Here we deconstruct, and then in a reasoned way reconstruct, the concept of "entropy of a system," paying particular attention to where the randomness may be coming from. We start with the core concept of entropy as a COUNT associated with…

From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…

In a companion article it was shown in a certain precise sense that, for any thermodynamical theory that respects the Kelvin-Planck Second Law, the Hahn-Banach Theorem immediately ensures the existence of a pair of continuous functions of…

The microscopic explanation of entropy has been challenged from both experimental and theoretical point of view. The expression of entropy is derived from the first law of thermodynamics indicating that entropy or the second law of…

The Carnot theory is unique among the theories of heat developed before the emergence of thermodynamics because it considers the relationship between heat and work. The theory is contained in Carnot's book published in 1824, which includes…

Based on quantum statistical mechanics and microscopic quantum dynamics, we prove Planck's and Kelvin's principles for macroscopic systems in a general and realistic setting. We consider a hybrid quantum system that consists of the…

Starting from the most general formulation of stochastic thermodynamics---i.e. a thermodynamically consistent nonautonomous stochastic dynamics describing systems in contact with several reservoirs---, we define a procedure to identify the…

We compute the low-temperature configurational entropy of a two-dimensional supercooled liquid. Our method, based on a higher-dimensional version of the Grassberger--Procaccia algorithm, can be implemented in a manner that is entirely…

The entropy of a thermally isolated system should not decrease after a quench or external driving. For a classical system following Hamiltonian dynamics, we show how this statement emerges for a large system in the sense that the extensive…

This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…

Gibbs-Boltzmann entropy leads to systems that have a strong dependence on initial conditions. In reality, most materials behave quite independently of initial conditions. Nonextensive entropy or Tsallis entropy leads to nonextensive…

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where…

We develop non-equilibrium theory by using averages in time and space as a generalized way to upscale thermodynamics in non-ergodic systems. The approach offers a classical perspective on the energy dynamics in fluctuating systems. The rate…

This paper is accountable only to explicitly stated physical assumptions and strict logical inference. Its goal is to run a rigorous stress test of second-law claims within the Clausius framework. We work directly with \textbf{Clausius's…

Thermodynamic entropy is determined by a heat measurement through the Clausius equality. The entropy then formalizes a fundamental limitation of operations by the second law of thermodynamics. The entropy is also expressed as the Shannon…

In this paper, through a criticism of what we call the paradigmatic view of thermodynamics, we aim at showing a new perspective attained in this matter. The generalization of heat as internal energy (generalization of the kinetic energy…

We study nonequilibrium thermodynamic properties of a driven one-dimensional quantum fluid by combining nonlinear Luttinger liquid theory with the quantum kinetic equation. In particular, we derive an entropy production consistent with the…

We present some novel thermodynamic ideas based on the Maupertuis principle. By considering Hamiltonians written in terms of appropriate action-angle variables we show that thermal states can be characterized by the action variables and by…

We propose entropy functions based on fractional calculus. We show that this new entropy has the same properties than the Shannon entropy except additivity, therefore making this entropy non-extensive. We show that this entropy function…