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We address the calculation of microcanonical reaction rates for processes involving significant nuclear quantum effects using ring-polymer molecular dynamics (RPMD), both with and without electronically non-adiabatic transitions. After…

Statistical Mechanics · Physics 2020-04-22 Xuecheng Tao , Philip Shushkov , Thomas F. Miller

We extend the capabilities of correlation energy functionals based on the adiabatic-connection fluctuation-dissipation theorem by implementing the analytical atomic forces within the random phase approximation (RPA), in the context of plane…

Materials Science · Physics 2026-03-19 Damian Contant , Maria Hellgren

The direct ring coupled-cluster doubles (drCCD)-based random phase approximation (RPA) has provided an attractive framework for the development and application of RPA-related methods. However, a potential unphysical solution issue recently…

Chemical Physics · Physics 2025-08-18 Ruiheng Song , Xiliang Gong , Hong-Zhou Ye

The relative energies of different phases or polymorphs of molecular solids can be small, less than a kiloJoule/mol. Reliable description of such energy differences requires high quality treatment of electron correlations, typically beyond…

Chemical Physics · Physics 2024-02-19 Khanh Ngoc Pham , Marcin Modrzejewski , Jiří Klimeš

We discuss that in the random phase approximation (RPA) the first derivative of the energy with respect to the Green's function is the self-energy in the GW approximation. This relationship allows us to derive compact equations for the RPA…

Chemical Physics · Physics 2017-03-22 Benjamin Ramberger , Tobias Schäfer , Georg Kresse

Analytical forces have been derived in the Lagrangian framework for several random phase approximation (RPA) correlated total energy methods based on the range separated hybrid (RSH) approach, which combines a short-range density functional…

Chemical Physics · Physics 2016-03-16 Bastien Mussard , Peter G. Szalay , János G. Ángyán

This paper establishes an approximation theorem for randomized neural networks (RaNNs) whose hidden-layer parameters are uniformly sampled from a prescribed bounded domain. Our analysis shows that, for RaNNs of the form $\mathop{\sum}_i W_i…

Numerical Analysis · Mathematics 2026-04-13 Ran Bi , Weibing Deng

The collective excitation phenomena in atomic nuclei are studied in two different formulations of the Random Phase Approximation (RPA): (i) RPA based on correlated realistic nucleon-nucleon interactions constructed within the Unitary…

Nuclear Theory · Physics 2009-11-11 N. Paar , P. Papakonstantinou , H. Hergert , R. Roth

In view of the application to supernova simulations, we calculate neutrino reaction rates with nucleons via the neutral and charged currents in the supernova core in the relativistic random phase approximation (RPA) and study their effects…

Astrophysics · Physics 2009-10-31 Shoichi Yamada , Hiroshi Toki

In correlated electron materials, the application of many-body techniques for the study of interaction effects or unconventional superconductivity often requires the formulation of an effective low-energy model that contains only the…

Strongly Correlated Electrons · Physics 2013-05-30 Carsten Honerkamp

We report the successful adaptation of the quasi-boson approximation, a technique traditionally employed in nuclear physics, to the analysis of the two-dimensional electron gas. We show that the correlation energy estimated from this…

Strongly Correlated Electrons · Physics 2025-05-05 Tobias M. R. Wolf , Chunli Huang

We propose a staggered mesh method for correlation energy calculations of periodic systems under the random phase approximation (RPA), which generalizes the recently developed staggered mesh method for periodic second order…

Computational Physics · Physics 2023-04-10 Xin Xing , Lin Lin

We present a comparative study of particle-hole and particle-particle channels of random-phase approximation (RPA) for molecular dissociations of different bonding types. We introduced a \textit{direct} particle-particle RPA scheme, in…

Materials Science · Physics 2019-06-05 Muhammad N. Tahir , Xinguo Ren

We present a constrained Random Phase Approximation (cRPA) method, termed spectral cRPA (s-cRPA), and compare it to established cRPA approaches for Scandium and Copper by varying the 3d shell filling. The s-cRPA method generally produces…

Strongly Correlated Electrons · Physics 2025-12-02 Merzuk Kaltak , Alexander Hampel , Martin Schlipf , Indukuru Ramesh Reddy , Bongjae Kim , Georg Kresse

The Gaussian expansion method (GEM) is extensively applied to the calculations in the random-phase approximation (RPA). We adopt the mass-independent basis-set that has been tested in the mean-field calculations. By comparing the RPA…

Nuclear Theory · Physics 2015-05-13 H. Nakada , K. Mizuyama , M. Yamagami , M. Matsuo

This Ph.D. thesis derives the equations of the Faddeev Random Phase Approximation (FRPA) and applies the method to a set of small atoms and molecules. The occurence of RPA instabilities in the dissociation limit is addressed in molecules…

Chemical Physics · Physics 2015-06-11 Matthias Degroote

Liquid-liquid phase separation underlies phenomena ranging from protein condensate formation to the phase coexistence of synthetic polymers. Although the random phase approximation (RPA) is widely used to predict such phase behavior, its…

Soft Condensed Matter · Physics 2026-05-05 Kiyoharu Kawana , Kyosuke Adachi

We have developed a fully consistent framework for calculations in the Quasiparticle Random Phase Approximation (QRPA) with $NN$ interactions from the Similarity Renormalization Group (SRG) and other unitary transformations of realistic…

Nuclear Theory · Physics 2011-07-04 H. Hergert , P. Papakonstantinou , R. Roth

A stochastic approach to time-dependent density functional theory (TDDFT) is developed for computing the absorption cross section and the random phase approximation (RPA) correlation energy. The core idea of the approach involves…

Chemical Physics · Physics 2016-11-04 Yi Gao , Daniel Neuhauser , Roi Baer , Eran Rabani

We formulate a microscopic theory to calculate cross section of the radiative neutron capture reaction on neutron-rich nuclei using the continuum random-phase approximation (cRPA) to the time-dependent density functional theory (TDDFT).…

Nuclear Theory · Physics 2023-06-28 Teruyuki Saito , Masayuki Matsuo