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Recently several reports showing ultra-high electrostrain (> 1 %) have appeared in Pb-free piezoceramics. However, there is lack of clarity on the nature of the ultrahigh strain. Here, we demonsrate that the ultrahigh strain is a…

Applied Physics · Physics 2023-12-27 Gobinda Das Adhikary , John Daniels , Luke Giles , Rajeev Ranjan

Ultrahigh electrostrains (greater than 1%) in several piezoceramic systems have been reported since 2022, which attract more and more interest in the field of piezoelectricity; however, the mechanism is still unclear. Here, we have directly…

Applied Physics · Physics 2023-12-07 Shuo Tian , Bin Li , Yejing Dai

The origin of "giant" flexoelectricity, orders of magnitude larger than theoretically predicted, yet frequently observed, is under intense scrutiny. There is mounting evidence correlating giant flexoelectric-like effects with parasitic…

Materials Science · Physics 2018-11-21 Amir Abdollahi , Fabian Vasquez-Sancho , Gustau Catalan

Recently, a series of reports showing ultra-high electrostrain (> 1 %) have appeared in several Pb-free piezoceramics. The ultrahigh electrostrain has been attributed exclusively to the defect dipoles created in these systems. We examine…

Since 2022, large apparent strains (>1%) with highly asymmetrical strain-electric field (S-E) curves have been reported in various thin piezoceramic materials, attributed to a bidirectional electric-field-induced bending (electrobending)…

Materials Science · Physics 2025-03-05 Yi Cheng , Shuo Tian , Bin Li , Yejing Dai

Large bipolar strain of up to 0.36% (peak-to-peak value) was measured in BiFeO3 ceramics at low frequency (0.1 Hz) and large amplitude (140 kV/cm) of the driving field. This strain is comparable to that achievable in highly efficient…

Materials Science · Physics 2011-12-06 Tadej Rojac , Marija Kosec , Dragan Damjanovic

A comprehensive understand of the intrinsic piezoelectric anisotropy stemming from diverse chemical and physical factors is a key step for the rational design of highly anisotropic materials. We performed high-throughput calculations on…

Materials Science · Physics 2023-10-26 Fanhao Jia , Shaowen Xu , Shunbo Hu , Jianguo Chen , Yongchen Wang , Yuan Li , Wei Ren , Jinrong Cheng

We report on the frequency and stress dependence of the direct piezoelectric d33 coefficient in BiFeO3 ceramics. The measurements reveal considerable piezoelectric nonlinearity, i.e., dependence of d33 on the amplitude of the dynamic…

Materials Science · Physics 2015-06-11 Tadej Rojac , Andreja Bencan , Goran Drazic , Marija Kosec , Dragan Damjanovic

Bulk polycrystalline piezoelectric ceramics are extensively used in wide ranging applications as actuators, transducers, and sensors. For actuator applications, it is desirable that the piezoelectric ceramic gives as large electric field…

Materials Science · Physics 2022-08-16 Gobinda Das Adhikary , Rajeev Ranjan

The lattice strain and domain switching behaviour was investigated as a function of cyclic field and grain orientation for a pseudorhombohedral composition of the high Curie point piezoelectric system xBiScO3 - (1-x)PbTiO3 (x = 0.40) by…

Materials Science · Physics 2015-08-05 Lalitha KV , Chris M. Fancher , Jacob L. Jones , Rajeev Ranjan

A key property that drives research in ferroelectric perovskite oxides is their strong piezoelectric response in which an electric field is induced by an applied strain, and vice-versa for the converse piezoelectric effect. We have achieved…

Materials Science · Physics 2015-06-11 J. Sinsheimer , S. J. Callori , B. Bein , Y. Benkara , J. Daley , J. Coraor , D. Su , P. W. Stephens , M. Dawber

The contributory mechanisms associated with high piezoelectric response in piezoelectric ceramics have been examined by in-situ electric field dependent high energy synchro x-ray diffraction study. A comparative study of electric field…

Materials Science · Physics 2015-08-25 Lalitha K. V. , Chris M. Fancher , Jacob L. Jones , Rajeev Ranjan

Piezoelectrics are materials that linearly deform in response to an applied electric field. As a fundamental prerequisite, piezoelectric material must possess a non centrosymmetric crystal structure. For more than a century, this remains…

Upon application of a uniform strain, internal sub-lattice shifts within the unit cell of a non-centrosymmetric dielectric crystal result in the appearance of a net dipole moment: a phenomenon well known as piezoelectricity. A macroscopic…

Materials Science · Physics 2015-05-13 R. Maranganti , P. Sharma

Piezoelectrics with negative longitudinal piezoelectric coefficients will contract in the direction of an applied electric field. Such piezoelectrics are thought to be rare but there is no fundamental physics preventing the realization of…

Materials Science · Physics 2017-11-22 Shi Liu , R. E. Cohen

Some highly ordered compounds of graphene oxide (GO), e.g., the so-called clamped and unzipped GO, are shown to have piezoelectric responses via first-principles density functional calculations. By applying an electric field perpendicular…

Materials Science · Physics 2014-04-08 Zhenyue Chang , Wenyi Yan , Jin Shang , Jefferson Zhe Liu

Recent realizations of ultrathin freestanding perovskite oxides offer a unique platform to probe novel properties in two-dimensional oxides. Here, we observed a giant flexoelectric response in freestanding BiFeO3 and SrTiO3 in their bent…

Strain can efficiently modulate the bandgap and carrier mobilities in two-dimensional (2D) materials. Conventional mechanical strain-application methodologies that rely on flexible, patterned or nano-indented substrates are severely limited…

An unresolved issue in the commonly used Pb(Zr1-xTix)O3 (PZT) ceramics is understanding the intrinsic piezoelectric behaviors of its crystal around the morphotropic phase boundary (MPB). Here, we demonstrate a novel approach to grow c-axis…

Materials Science · Physics 2024-08-26 Desheng Fu , Seiji Sogen , Hisao Suzuki

We have measured the bending-induced polarization of Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystals with compositions at the relaxor-ferroelectric phase boundary. The crystals display very large flexoelectricity, with flexocoupling coefficients an…

Materials Science · Physics 2015-06-18 Jackeline Narvaez , Gustau Catalan
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