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Soft x-rays were applied to induce graphitization of diamond through a non-thermal solid-to-solid phase transition. This process was observed within poly-crystalline diamond with a time-resolved experiment using ultrashort soft x-ray pulses…

Diamond bulk irradiated with a free-electron laser pulse of 6100 eV photon energy, 5 fs duration, at the $\sim 19-25$ eV/atom absorbed doses, is studied theoretically on its way to warm dense matter state. Simulations with our hybrid code…

Materials Science · Physics 2018-03-30 Nikita Medvedev , Beata Ziaja

We present the results of an experiment where amorphous carbon was irradiated by femtosecond x-ray free electron laser pulses. The 830 eV laser pulses induce a phase transition in the material which is characterized ex-situ. The phase…

The energetic evaluations of graphite-to-diamond transition by electron irradiation are performed. The heat conduction problem is solved for the diamond synthesis when a pulse-periodic source of energy is located within a graphite cylinder;…

Materials Science · Physics 2014-09-03 E. M. Sarkisyan , K. B. Oganesyan , N. Sh. Izmailian , E. A. Ayryan

Optically induced ultrafast electronic excitations with sufficiently long lifetimes may cause strong effects on phase transitions like structural and nonmetal to metal ones. Examples are transitions diamond to graphite, graphite to…

Materials Science · Physics 2010-09-21 K. H. Bennemann

Diamond to graphite transformation is a complex kinetically driven process which has been studied under various conditions for its fundamental importance. We report the transformation of diamond embedded ceramic matrix composites during…

We investigate photoinization, energy deposition, plasma formation and the ultrafast optical breakdown in crystalline silicon irradiated by intense near-infrared laser pulses with pulse duration $\tau \le $ 100 fs. The occurrence of…

Materials Science · Physics 2021-11-24 Tzveta Apostolova , Boyan Obreshkov

Graphite and diamond have comparable free energies, yet forming diamond from graphite is far from easy. In the absence of a catalyst, pressures that are significantly higher than the equilibrium coexistence pressures are required to induce…

Materials Science · Physics 2015-05-20 Rustam Z. Khaliullin , Hagai Eshet , Thomas D. Kuhne , Jorg Behler , Michele Parrinello

We unveil the diamondization mechanism of few-layer graphene compressed in the presence of water, providing robust evidence for the pressure-induced formation of 2D diamond. High-pressure Raman spectroscopy provides evidence of a phase…

Secondary electron cascades are responsible for significant ionizations in macroscopic samples during irradiation with X-rays. A quantitative analysis of these cascades is needed, e.g. for assessing damage in optical components at X-ray…

Condensed Matter · Physics 2015-06-24 Beata Ziaja , Abraham Szoeke , Janos Hajdu

The degree of laser-induced graphitisation from a sp3-bonded to a sp2-bonded carbon fraction in a single crystal chemical vapour deposited (CVD) diamond under a varying fluence of an ultrashort pulsed laser (30 fs, 800 nm, 1 kHz)…

Chemical Physics · Physics 2022-03-30 Bakhtiar Ali , Han Xu , Dashavir Chetty , Robert T. Sang , Igor V. Litvinyuk , Maksym Rybachuk

The pressure-induced structural transition from graphite to diamond is investigated by semi-empirical molecular dynamics simulation. The result shows that the graphite-diamond transition is a cooperative process with large fluctuation. We…

Materials Science · Physics 2016-08-31 Akihito Kikuchi , Shinji Tsuneyuki

To investigate the mechanism of radiation detection in diamonds, we developed a real time time dependent density functional theory based calculation scheme to evaluate changes in the density of states induced by alpha ray irradiation. A…

Materials Science · Physics 2025-08-27 Atsuhiro Umemoto , Yoshiyuki Miyamoto

Three dimensional waveguides within the bulk of diamond are manufactured using ultrafast laser fabrication. High intensities within the focal volume of the laser cause breakdown of the diamond into a graphitic phase leading to a stress…

Optics · Physics 2016-07-29 Arnaud Courvoisier , Martin J. Booth , Patrick S. Salter

We demonstrate enhancement of X-ray excited optical luminescence in a 100-micron-thick diamond plate by introduction of defect states via electron beam irradiation and subsequent high-temperature annealing. The resulting X-ray…

Instrumentation and Detectors · Physics 2020-02-20 Stanislav Stoupin , Sergey Antipov , Alexander M. Zaitsev

The demands on optical components to tolerate high radiation dose and manipulate hard x-ray beams that can fit the experiment requirements, are constantly increasing due to the advancements in the available x-ray sources. Here we have…

The direct graphite-to-diamond transformation mechanism has been a subject of intense study and remains debated concerning the initial stages of the conversion, the intermediate phases, and their transformation pathways. Here, we…

Low-energy ion beam modification was proposed to create graphene on the top of the insulated diamond-like carbon films. In such low-temperature fabrication process the surface of the amorphous carbon could crystallize to graphene as a…

Materials Science · Physics 2015-05-27 Savcho Tinchev

In the recent years graphitization of ion-beam induced amorphous layers became the basic tool for device fabrication in diamond. The etchable graphitic layers can be removed to form free-standing membranes into which the desired structures…

Materials Science · Physics 2016-08-26 S. Rubanov , B. A. Fairchild , A. Suvorova , P. Olivero , S. Prawer

X-ray diffraction of silicon irradiated with tightly focused femtosecond x-ray pulses (photon energy: 11.5 keV, pulse duration: 6 fs) was measured at various x-ray intensities up to $4.6\times10^{19}$ W/cm$^2$. The measurement reveals that…

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