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The recently discovered ferroelectric nematic (NF) liquid crystals (LC) have been reported to show an extraordinarily large value of the real part of the dielectric constant at low frequencies. However, it was argued by Clark et al in…

The recently discovered ferroelectric nematic liquid crystals have been reported to exhibit very large dielectric permittivity values. Here, we report a systematic investigation of the dielectric behavior of a prototypical ferroelectric…

Soft Condensed Matter · Physics 2024-02-05 Aitor Erkoreka , Josu Martinez-Perdiguero , Richard J. Mandle , Alenka Mertelj , Nerea Sebastián

Numerous measurements of the dielectric constant $\epsilon$ of the recently discovered ferroelectric nematic ($N_F$) liquid crystal (LC) phase report extraordinarily large values of $\epsilon^\prime$ (up to ~30,000). We show that what is in…

Soft Condensed Matter · Physics 2024-02-26 Noel A. Clark , Xi Chen , Joseph E. Maclennan , Matthew A. Glaser

The magnitude of the relative permittivity of the ferroelectric nematic phase (NF) is under a lively scientific discussion since the phase was recently discovered. Dielectric spectroscopy measurements (DSM) give a huge value of relative…

Soft Condensed Matter · Physics 2024-09-05 Vojko Matko , Ewa Gorecka , Damian Pociecha , Joanna Matraszek , Nataša Vaupotič

Since the recent discoveries, ferroelectric nematics became of upmost interest due to their outstanding ferroelectric properties. In this work, we prepared a series of polar molecules revealing a ferroelectric nematic phase (NF) with a very…

We studied dielectric properties of a polar nematic phase (NF) sandwiched between two gold or ITO electrodes, serving as a cell surfaces. In bulk, NF is expected to exhibit a Goldstone mode (phason), because polarization can uniformly…

Understanding the system-level spectral immittance response of capacitive energy storage devices with analytically tractable physics-based models is not only important for the progress of the technology, but also allows to develop new…

Applied Physics · Physics 2022-02-22 Anis Allagui , Hachemi Benaoum , Hichem Eleuch , Chunlei Wang

Dielectric spectroscopy is known as one of the most powerful techniques for studying ferroelectric and other polar materials. Since the discovery of ferroelectricity in Liquid Crystals, it has been successfully employed for the…

Materials Science · Physics 2025-04-25 Yuri P. Panarin , Neelam Yadav , Rahul Uttam , Wanhe Jiang , Georg H. Mehl , Jagdish K. Vij

Ferroelectric materials have remained one of the foci of condensed matter physics and materials science for over 50 years. In the last 20 years, the development of voltage-modulated scanning probe microscopy techniques, exemplified by…

Materials Science · Physics 2017-01-06 Rama K. Vasudevan , Nina Balke , Peter Maksymovych , Stephen Jesse , Sergei V. Kalinin

Memristors are considered key building blocks for the development of neuromorphic computing hardware. For ferroelectric memristors with a capacitor-like structure, the polarization direction modulates the height of the Schottky barriers --…

Applied Physics · Physics 2024-05-20 C. Ferreyra , M. Badillo , M. J. Sánchez , M. Acuautla , B. Noheda , D. Rubi

The recent quest for improved functional materials like high permittivity dielectrics and/or multiferroics has triggered an intense wave of research. Many materials have been checked for their dielectric permittivity or their polarization…

Materials Science · Physics 2009-11-13 Mario Maglione , M. A. Subramanian

Ferroelectric nematic (NF) liquid crystals combine liquid-like fluidity and orientational order of conventional nematics with macroscopic electric polarization comparable in magnitude to solid state ferroelectric materials. Here, we present…

Soft Condensed Matter · Physics 2025-02-04 Calum J. Gibb , Jordan Hobbs , Richard J. Mandle

Ferroelectric nematic liquid crystals are currently being subject to a plethora of investigations since they are of great fundamental interest and could potentially foster promising applications. However, many basic aspects are still poorly…

Soft Condensed Matter · Physics 2024-05-20 Aitor Erkoreka , Josu Martinez-Perdiguero

We present a thorough analysis of the foundations of models of stabilization of negative capacitance (NC) in a ferroelectric (FE) layer by capacitance matching to a dielectric layer, which claim that the FE is stabilized in a low…

Mesoscale and Nanoscale Physics · Physics 2020-03-03 J. A. Kittl , J. -P. Locquet , M. Houssa , V. V. Afanasiev

Hafnium oxide (HfO2)-based ferroelectrics offer remarkable promise for memory and logic devices in view of their compatibility with traditional silicon CMOS technology, high switchable polarization, good endurance and thickness scalability.…

Applied Physics · Physics 2020-04-29 Liam Collins , Umberto Celano

We study the electrode polarization behaviour of different Na-Ca-phosphosilicate glasses by measuring the differential capacitance between blocking Pt electrodes. At low applied dc bias voltages, we detect a linear capacitance regime with…

Disordered Systems and Neural Networks · Physics 2009-11-11 C. R. Mariappan , T. P. Heins , B. Roling

This paper provides a brief introduction to the phenomenological aspects of the polarization in ferrroelectric materials, and then an analysis of a few selected topics related to the modelling of ferroelectrics. The description of…

Emerging Technologies · Computer Science 2023-11-08 David Esseni , Francesco Driussi , Daniel Lizzit , Marco Massarotto , Mattia Segatto

We discuss the particle size driven tunability of the coexistence of ferromagnetism and ferroelectricity in Pr0.67Ca0.33MnO3(PCMO) with the help of x ray diffraction, magnetization, impedance spectroscopy, and remanent polarization…

Strongly Correlated Electrons · Physics 2014-12-25 Vinay Kumar Shukla , Soumik Mukhopadhyay , Kalipada Das , A. Sarma , I. Das

First-principles modeling of ferroelectric capacitors presents several technical challenges, due to the coexistence of metallic electrodes, long-range electrostatic forces and short-range interface chemistry. Here we show how these aspects…

Materials Science · Physics 2011-03-03 Massimiliano Stengel , David Vanderbilt , Nicola A. Spaldin

Polar metals with ferroelectric-like displacements in metals have been achieved recently, half century later than Anderson and Blount's prediction. However, the genuine ferroelectricity with electrical dipolar switching has not yet been…

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