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The origins of enhanced piezoelectric coupling along nonpolar crystallographic directions in ferroelectric BaTiO3 are investigated using in situ neutron spectroscopy. It is observed that an electric field applied away from the equilibrium…

Thin ferroelectric BaTiO$_3$ films often exhibit continuous transitions instead of the first-order behavior of bulk crystals, a discrepancy usually attributed to epitaxial strain or dimensionality. Using quasi-adiabatic nanocalorimetry on…

We report the nanoscale electrical imaging results in hexagonal $Lu_{0.6}Sc_{0.4}FeO_3$ single crystals using conductive atomic force microscopy (C-AFM) and scanning microwave impedance microscopy (MIM). While the dc and ac response of the…

Materials Science · Physics 2018-08-28 Xiaoyu Wu , Kai Du , Lu Zheng , Di Wu , Sang-Wook Cheong , Keji Lai

We investigate ferroelectric- and resistive switching behavior in 18-nm-thick epitaxial BaTiO$_3$ (BTO) films in a model electrolyte-ferroelectric-semiconductor (EFS) configuration. The system is explored for its potential as a…

The lattice strain and domain switching behaviour was investigated as a function of cyclic field and grain orientation for a pseudorhombohedral composition of the high Curie point piezoelectric system xBiScO3 - (1-x)PbTiO3 (x = 0.40) by…

Materials Science · Physics 2015-08-05 Lalitha KV , Chris M. Fancher , Jacob L. Jones , Rajeev Ranjan

Atomic force microscopy was used to investigate ferroelectric switching and nanoscale domain dynamics in epitaxial PbZr0.2Ti0.8O3 thin films. Measurements of the writing time dependence of domain size reveal a two-step process in which…

Disordered Systems and Neural Networks · Physics 2013-11-07 P. Paruch , T. Giamarchi , T. Tybell , J. -M. Triscone

Ferroelectric domain walls are nanoscale objects that can be created, positioned, and erased on demand. They often embody functional properties that are distinct from the surrounding bulk material. Enhanced conductivity, for instance, is…

Materials Science · Physics 2024-10-29 Elzbieta Gradauskaite , Chia-Jung Yang , Shovon Pal , Manfred Fiebig , Morgan Trassin

We report on linear and non-linear dielectric property measurements of BaTiO3 - CoFe2O4 (BTO-CFO) ferroelectro-magnetic nano-composites and pure BaTiO3 and CoFe2O4 samples with Scanning Near Field Microwave Microscopy. The permittivity…

Materials Science · Physics 2009-11-11 Yi Qi , H. Zheng , R. Ramesh , Steven M. Anlage

Broadband dielectric spectroscopy (BDS) of pure 5OCB and nanocolloids consisting of 5OCB and paraelectric or ferroelectric BaTiO${_3}$ nanoparticles (NPs) was performed on varying pressure or temperature. We found strong impact of NPs on…

Soft Condensed Matter · Physics 2017-08-16 S. Starzonek , S. J. Rzoska , A. Drozd-Rzoska , Krzysztof Czupryński , S. Kralj

Interface physics in oxide heterostructures is pivotal in material's science. Domain walls (DWs) in ferroic systems are examples of naturally occurring interfaces, where order parameter of neighboring domains is modified and emerging…

Materials Science · Physics 2015-10-08 Josep Fontcuberta , Vassil Skumryev , Vladimir Laukhin , Xavier Granados , Ekhard K. H. Salje

Ferroelectric domain nucleation and growth in multiferroic BiFeO3 films is observed directly by applying a local electric field with a conductive tip inside a scanning transmission electron microscope. The nucleation and growth of a…

Domain walls in ferroelectrics exhibit a plethora of phases and functionalities not found in the bulk. The interplay of electrostatic, chemical, topological, and distortive inhomogeneities at the walls can be so complex, however, that this…

Mesoscale and Nanoscale Physics · Physics 2017-02-23 Gabriele De Luca , Marta D. Rossell , Jakob Schaab , Nathalie Viart , Manfred Fiebig , Morgan Trassin

We report experimentally achieving first-ever electric field periodic poling of single crystal barium titanate (BTO, or BaTiO3) thin film on insulator. Owing to the outstanding optical nonlinearities of BTO, this result is a key step…

Ferroelectric domain structures, separated by domain walls, often display unconventional physics and hold significant potential for applications in nano-devices. Most naturally growth domain walls are charge-neutral to avoid increased…

Materials Science · Physics 2024-12-17 Yunfei Hong , Junkai Deng , Yang Yang , Ri He , Zhicheng Zhong , Xiangdong Ding , Jun Sun , Jefferson Zhe Liu

The exotic topological domains in ferroelectrics and multiferroics have attracted extensive interest in recent years due to their novel functionalities and potential applications in nanoelectronic devices. One of the key challenges for such…

We present in-situ transmission electron microscopy observations of domain wall motion in thin freestanding potassium niobate single-crystals. We observe that not all domains of a given polarization orientation are equally switchable in…

Materials Science · Physics 2007-05-23 A. Krishnan , M. M. J. Treacy , M. E. Bisher , P. Chandra , P. B. Littlewood

The origin of the unusual 90^o ferroelectric / ferroelastic domains, consistently observed in recent studies on meso and nanoscale free-standing single crystals of BaTiO3 [Schilling et al., Physical Review B, 74, 024115 (2006); Schilling et…

Materials Science · Physics 2009-04-13 I. A. Luk'yanchuk , A. Schilling , J. M. Gregg , G. Catalan , J. F. Scott

We study the electrocaloric (EC) effect in bulk BaTiO$_3$ (BTO) using molecular dynamics simulations of a first principles-based effective Hamiltonian, combined with direct measurements of the adiabatic EC temperature change in BTO single…

Deterministic polarization reversal in ferroelectric and multiferroic films is critical for their exploitation in nanoelectronic devices. While ferroelectricity has been studied for nearly a century, major discrepancies in the reported…

Electrically tunable metasurfaces leveraging the strong Pockel's effect in barium titanate (BaTiO$_3$ or BTO) are a promising platform for reconfigurable free-space optical devices. However, the high cost, limited scalability, and…