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Chemical reactions involve the movement of charges, and this work presents a mathematical model for describing chemical reactions in electrolytes. The model is developed using an energy variational method that aligns with classical…

Chemical Physics · Physics 2023-11-02 Shixin Xu , Robert Eisenberg , Zilong Song , Huaxiong Huang

Complex dynamical networks consisting of many components that interact and produce each other are difficult to understand, especially, when new components may appear. In this paper we outline a theory to deal with such systems. The theory…

Molecular Networks · Quantitative Biology 2007-06-13 Peter Dittrich , Pietro Speroni di Fenizio

Existential rules are a very popular ontology-mediated query language for which the chase represents a generic computational approach for query answering. It is straightforward that existential rule queries exhibiting chase termination are…

Logic in Computer Science · Computer Science 2021-07-19 Camille Bourgaux , David Carral , Markus Krötzsch , Sebastian Rudolph , Michaël Thomazo

It is standard in chemistry to represent a sequence of reactions by a single overall reaction, often called a complex reaction in contrast to an elementary reaction. Photosynthesis $6 \text{CO}_2+6 \text{H}_2\text{O} \to \…

Combinatorics · Mathematics 2022-03-28 Linard Hoessly , Carsten Wiuf , Panqiu Xia

Reaction-diffusion equations on infinite graphs can have an infinite number of stationary solutions. These solutions are generally described as roots of a countable system of algebraic equations. As a generalization of periodic stationary…

Dynamical Systems · Mathematics 2024-12-31 Vladimír Švígler , Jonáš Volek

We introduce an algorithm that conjectures the structure of a permutation class in the form of a disjoint cover of "rules"; similar to generalized grid classes. The cover is usually easily verified by a human and translated into an…

Combinatorics · Mathematics 2017-05-12 Christian Bean , Bjarki Gudmundsson , Henning Ulfarsson

Let $\Delta =\{ \delta_1,\delta_2,...,\delta_m \} $ be a finite set of 2-connected patterns, i.e. graphs up to vertex relabelling. We study the generating function $D_{\Delta }(z,u_1,u_2,...,u_m),$ which counts polygon dissections and marks…

Combinatorics · Mathematics 2018-08-29 Vasiliki Velona

The difficulties of automatic extraction of definitions and methods from scientific documents lie in two aspects: (1) the complexity and diversity of natural language texts, which requests an analysis method to support the discovery of…

Computation and Language · Computer Science 2023-07-06 Yutian Sun , Hai Zhuge

Simulating chemical reaction networks is often computationally demanding, in particular due to stiffness. We propose a novel simulation scheme where long runs are not simulated as a whole but assembled from shorter precomputed segments of…

Logic in Computer Science · Computer Science 2022-06-22 Martin Helfrich , Milan Češka , Jan Křetínský , Štefan Martiček

Form a pure mathematical point of view, common functional forms representing different physical phenomena can be defined. For example, rates of chemical reactions, diffusion and heat transfer are all governed by exponential-type…

Machine Learning · Computer Science 2019-10-01 Navid Zobeiry , Keith D. Humfeld

We present a systematic mathematical analysis of the qualitative steady-state response to rate perturbations in large classes of reaction networks. This includes multimolecular reactions and allows for catalysis, enzymatic reactions,…

Dynamical Systems · Mathematics 2017-11-22 Bernhard Brehm , Bernold Fiedler

A new criterion is developed which provides a check as to whether a chosen set of polarization observables is complete with respect to the determination of all independent $T$-matrix elements of a reaction of the type $a+b\to c+d+...$. As…

Nuclear Theory · Physics 2009-10-31 Hartmuth Arenhoevel , Winfried Leidemann , Edward L. Tomusiak

Chemical reactions often proceed through the formation and the consumption of intermediate species. An example is the creation and subsequent degradation of the substrate-enzyme complexes in an enzymatic reaction. In this paper we provide a…

Dynamical Systems · Mathematics 2018-05-22 Daniele Cappelletti , Carsten Wiuf

Due to the intrinsic complexity and nonlinearity of chemical reactions, direct applications of traditional machine learning algorithms may face with many difficulties. In this study, through two concrete examples with biological background,…

Molecular Networks · Quantitative Biology 2020-06-02 Wuyue Yang , Liangrong Peng , Yi Zhu , Liu Hong

In the first part of this paper, we propose new optimization-based methods for the computation of preferred (dense, sparse, reversible, detailed and complex balanced) linearly conjugate reaction network structures with mass action dynamics.…

Dynamical Systems · Mathematics 2014-07-15 Matthew D. Johnston , David Siegel , Gábor Szederkényi

Retrosynthesis is the process of recursively decomposing target molecules into available building blocks. It plays an important role in solving problems in organic synthesis planning. To automate or assist in the retrosynthesis analysis,…

Quantitative Methods · Quantitative Biology 2020-11-06 Chaochao Yan , Qianggang Ding , Peilin Zhao , Shuangjia Zheng , Jinyu Yang , Yang Yu , Junzhou Huang

Many physical systems--from mechanical lattices and electrical circuits to biological tissues and architected metamaterials--can be understood as networks transmitting physical quantities. We present a unified mathematical framework for…

Soft Condensed Matter · Physics 2025-08-07 José M. Ortiz-Tavárez , William Stephenson , Xiaoming Mao

Functional ANOVA offers a principled framework for interpretability by decomposing a model's prediction into main effects and higher-order interactions. For independent features, this decomposition is well-defined, strongly linked with SHAP…

Machine Learning · Statistics 2026-03-04 Baptiste Ferrere , Nicolas Bousquet , Fabrice Gamboa , Jean-Michel Loubes , Joseph Muré

In chemical reaction network theory, ordinary differential equations are used to model the temporal change of chemical species concentration. As the functional form of these ordinary differential equations systems is derived from an…

Molecular Networks · Quantitative Biology 2025-02-27 Anna C. M. Thöni , William E. Robinson , Yoram Bachrach , Wilhelm T. S. Huck , Tal Kachman

Chemical reaction networks (CRNs) exhibit complex dynamics governed by their underlying network structure. In this paper, we propose a novel approach to study the dynamics of CRNs by representing them on species graphs (S-graphs). By…

Molecular Networks · Quantitative Biology 2024-04-24 Keisuke Sugie , Dimitri Loutchko , Tetsuya J. Kobayashi