English

On the sum of chemical reactions

Combinatorics 2022-03-28 v2 Dynamical Systems Molecular Networks Quantitative Methods

Abstract

It is standard in chemistry to represent a sequence of reactions by a single overall reaction, often called a complex reaction in contrast to an elementary reaction. Photosynthesis 6CO2+6H2O C6H12O66 \text{CO}_2+6 \text{H}_2\text{O} \to \ \text{C}_6\text{H}_{12}\text{O}_6 + 6O2+\ 6 \text{O}_2 is an example of such complex reaction. We introduce a mathematical operation that corresponds to summing two chemical reactions. Specifically, we define an associative and non-communicative operation on the product space N0n×N0n\mathbb{N}_0^n\times \mathbb{N}_0^n (representing the reactant and the product of a chemical reaction, respectively). The operation models the overall effect of two reactions happening in succession, one after the other. We study the algebraic properties of the operation and apply the results to stochastic reaction networks, in particular to reachability of states, and to reduction of reaction networks.

Keywords

Cite

@article{arxiv.2105.04353,
  title  = {On the sum of chemical reactions},
  author = {Linard Hoessly and Carsten Wiuf and Panqiu Xia},
  journal= {arXiv preprint arXiv:2105.04353},
  year   = {2022}
}