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There are only a very few known relations in statistical dynamics that are valid for systems driven arbitrarily far-from-equilibrium. One of these is the fluctuation theorem, which places conditions on the entropy production probability…

Statistical Mechanics · Physics 2009-09-25 Gavin E. Crooks

The transient quantum fluctuation theorems of Crooks and Jarzynski restrict and relate the statistics of work performed in forward and backward forcing protocols. So far these theorems have been obtained under the assumption that the work…

Statistical Mechanics · Physics 2014-02-07 B. Prasanna Venkatesh , Gentaro Watanabe , Peter Talkner

Five previously unknown inequalities relating equilibrium free energy differences and non-equilibrium work fluctuations are derived, and lucid path to derivation of many similar inequalities is presented. These results are based upon…

Statistical Mechanics · Physics 2011-05-24 Alexander Davydov

A new method is proposed for a treatment of ideal quantum gases in the microcanonical ensemble near the thermodynamic limit. The method allows rigorous asymptotic calculations of the average number of particles and particle number…

Nuclear Theory · Physics 2011-07-19 V. V. Begun , M. I. Gorenstein , A. P. Kostyuk , O. S. Zozulya

Optical modes possessing orbital angular momentum constitute a very useful platform for experimental studies on the quantum limits of Thermodynamics. Here, we present experimental results for entangled photon pairs subjected to thin…

Microcanonical description is characterized by the presence of an internal symmetry closely related with the dynamical origin of this ensemble: the reparametrization invariance. Such symmetry possibilities the development of a non…

Statistical Mechanics · Physics 2007-05-23 L. Velazquez , F. Guzman

Entropy production for a system not in the thermodynamic limit is formulated using Hill's nanothermodynamics, in which a macroscopic ensemble of such systems is considered. External influence of the environment on the average nanosystem is…

Statistical Mechanics · Physics 2011-03-21 J. Carrete , L. M. Varela , L. J. Gallego

In the present work, we study the entropy productions in a system controlled by double control parameters. By introducing a thermal fluctuation part, we solve the problem that the second law of the thermodynamics seems to be violated by the…

Statistical Mechanics · Physics 2015-08-21 Jang-il Sohn

It is shown that the work fluctuations and work distribution functions are fundamentally different in systems with short-range versus long-range correlations. The two cases considered with long- range correlations are magnetic work…

Statistical Mechanics · Physics 2017-07-26 T. R. Kirkpatrick , J. K. Bhattacherjee , J. V. Sengers

We present an exact microcanonical formulation, in the thermodynamic limit, for a system of $N$ noninteracting particles with $p$ equally spaced energy levels $\{0,\epsilon,2\epsilon,\ldots,(p-1)\epsilon\}$. Writing the microcanonical…

Statistical Mechanics · Physics 2026-05-05 J. Ricardo de Sousa

We consider the Microcanonical Variational Principle for the vortex system in a bounded domain. In particular we are interested in the thermodynamic properties of the system in domains of second kind, i.e. for which the equivalence of…

Mathematical Physics · Physics 2023-12-27 Dario Benedetto , Emanuele Caglioti , Margherita Nolasco

We consider a time-dependent quantum linear oscillator coupled to a bath at an arbitrary strength. We then introduce a generalized Jarzynski equality (GJE) which includes the terms reflecting the system-bath coupling. This enables us to…

Statistical Mechanics · Physics 2014-03-03 Ilki Kim

For classical systems driven out of equilibrium, Crooks derived a relation (the Crooks-Jarzynski relation), whose special cases include a relation (the Crooks relation) equivalent to the Kawasaki non-linear response relation. We derive a…

Statistical Mechanics · Physics 2014-05-26 Hiroshi Matsuoka

For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this…

Statistical Mechanics · Physics 2010-02-08 Eliran Boksenbojm , Bram Wynants , Christopher Jarzynski

We derive the thermodynamic entropy of the mean field $\phi^{6}$ spin model in the framework of the micro-canonical ensemble as a function of the energy and magnetization. Using the theory of large deviations and Rugh's micro-canonical…

Statistical Mechanics · Physics 2014-02-14 S. A. Alavi , S. Sarvari

The equivalence of thermodynamic results in the canonical and the microcanonical ensembles has been questioned in some calculations for spin models with long-range interactions. We show that these claims of inequivalence are related to an…

Statistical Mechanics · Physics 2015-01-19 Vera B. Henriques , Silvio R. Salinas

Based only on classical Hamiltonian dynamics, we prove the maximum work principle in a system where macroscopic dynamical degrees of freedom are intrinsically coupled to microscopic degrees of freedom. Unlike recent identities between…

Statistical Mechanics · Physics 2015-05-26 Christian Maes , Hal Tasaki

Generalizations of the microcanonical and canonical ensembles for paths of Markov processes have been proposed recently to describe the statistical properties of nonequilibrium systems driven in steady states. Here we propose a theory of…

Statistical Mechanics · Physics 2013-09-18 Raphael Chetrite , Hugo Touchette

The characteristic function for the joint measurement of the changes of two commuting observables upon an external forcing of a quantum system is derived. In particular, the statistics of the internal energy, the exchanged heat and the work…

Statistical Mechanics · Physics 2009-02-18 Peter Talkner , Michele Campisi , Peter Hänggi

We consider a mean-field system described by a general collective variable $M$, driven out of equilibrium by the manipulation of a parameter $\mu$. Given a general dynamics compatible with its equilibrium distribution, we derive the…

Statistical Mechanics · Physics 2007-05-23 A. Imparato , L. Peliti