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Related papers: Modified Jarzynski equality in a microcanonical en…

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We study the quantum Jarzynski relation for driven quantum models embedded in various environments. We do so by generalizing a proof presented by Mukamel [Phys. Rev. Lett 90, 170604 (2003)] for closed quantum systems. In this way, we are…

Statistical Mechanics · Physics 2007-12-04 Jens Teifel , Günter Mahler

In this paper, we draw attention to the problem of phase transitions in systems with locally affine microcanonical entropy, in which partial equivalence of (microcanonical and canonical) ensembles is observed. We focus on a very simple spin…

Statistical Mechanics · Physics 2020-02-19 Agata Fronczak , Piotr Fronczak , Grzegorz Siudem

Most natural and engineered processes, such as biomolecular reactions, protein folding, and population dynamics, occur far from equilibrium and, therefore, cannot be treated within the framework of classical equilibrium thermodynamics. The…

Soft Condensed Matter · Physics 2016-01-07 Aykut Argun , Ali-Reza Moradi , Erçağ Pince , Gokhan Baris Bagci , Giovanni Volpe

For a two-level quantum mechanical system, we derive microscopically the exact expression for the fluctuation of microscopic work in a multi-step non-equilibrium process, and we rigorously prove that in an isothermal process, the…

Statistical Mechanics · Physics 2008-08-19 H. T. Quan , S. Yang , C. P. Sun

The Jarzynski equality (JE), which relates works of non-equilibrium trajectories to the free energy difference of the initial and final states of the non-equilibrium process, provides an efficient way to calculate free energies of systems…

Soft Condensed Matter · Physics 2016-04-20 Biao Wan , Cheng Yang , Yanting Wang , Xin Zhou

We point out that most of the classical thermodynamics results in the paper have been known in the literature, see Kestin and Woods, for quite some time and are not new, contrary to what the authors imply. As shown by Kestin, these results…

Chemical Physics · Physics 2017-11-10 P. D. Gujrati

Jarzynski Equality (JE) and the thermodynamic integration method are conventional methods to calculate free energy difference (FED) between two equilibrium states with constant temperature of a system. However, a number of ensemble samples…

Statistical Mechanics · Physics 2020-09-01 Weitao Chen

The Jarzynski equality (JE), which connects the equilibrium free energy with non-equilibrium work statistics, plays a crucial role in quantum thermodynamics. Although practical quantum systems are usually multi-level systems, most tests of…

Quantum Physics · Physics 2023-10-26 Wenquan Liu , Zhibo Niu , Wei Cheng , Xin Li , Chang-Kui Duan , Zhangqi Yin , Xing Rong , Jiangfeng Du

It has been established that the inclusive work for classical, Hamiltonian dynamics is equivalent to the two-time energy measurement paradigm in isolated quantum systems. However, a plethora of other notions of quantum work has emerged, and…

Statistical Mechanics · Physics 2021-04-08 Akira Sone , Sebastian Deffner

The nonequilibrium fluctuation relation is a cornerstone of quantum thermodynamics. It is widely believed that the system-bath heat exchange obeys the famous Jarzynski-W\'{o}jcik fluctuation theorem. However, this theorem is established in…

Quantum Physics · Physics 2024-08-01 Wei Wu , Jun-Hong An

We apply the method of gauge transformation to spin glasses under the microcanonical ensemble to study the possibility of ensemble inequivalence in systems with long-range interactions and quenched disorder. It is proved that all the…

Disordered Systems and Neural Networks · Physics 2015-03-17 Hidetoshi Nishimori

Ensemble inequivalence occurs when a systems thermodynamic properties vary depending on the statistical ensemble used to describe it. This phenomenon is known to happen in systems with long-range interactions and has been observed in many…

Statistical Mechanics · Physics 2026-04-09 Daniel Arrufat-Vicente , David Mukamel , Stefano Ruffo , Nicolo Defenu

A main goal of single-molecule experiments is to evaluate equilibrium free energy differences by applying fluctuation relations to repeated work measurements along irreversible processes. We quantify the error that is made in a free energy…

Statistical Mechanics · Physics 2009-06-22 Alessandro Mossa , Sara de Lorenzo , Josep Maria Huguet , Felix Ritort

We derive a general information-theoretic equality for a system undergoing two projective measurements separated by a general temporal evolution. The equality implies the non-negativity of the mutual information between the measurement…

Quantum Physics · Physics 2015-06-04 Vlatko Vedral

We derive integral quantum fluctuation theorems and quantum Jarzynski equalities for a feedback-controlled system and a memory which registers outcomes of the measurement. The obtained equalities involve the information content, which…

Statistical Mechanics · Physics 2014-01-30 Ken Funo , Yu Watanabe , Masahito Ueda

The Jarzynski Equality is a well-known and widely used identity, relating the free energy difference between two states of a system to the work done over some arbitrary, nonequilibrium transformation between the two states. Despite being…

Statistical Mechanics · Physics 2018-12-18 Stuart J. Davie , Owen G. Jepps , Lamberto Rondoni , James C. Reid , Debra J. Searles

A Hamiltonian model living in a bounded phase space and with long-range interactions is studied. It is shown, by analytical computations, that there exists an energy interval in which the microcanonical entropy is a decreasing convex…

Statistical Mechanics · Physics 2019-05-01 Fabio Miceli , Marco Baldovin , Angelo Vulpiani

We experimentally verify the Jarzynski and W\"ojcik quantum heat exchange fluctuation relation by implementing the interferometric technique in liquid-state Nuclear Magnetic Resonance setup and study the exchange heat statistics between two…

Statistical Mechanics · Physics 2019-10-30 Soham Pal , T S Mahesh , Bijay Kumar Agarwalla

We combine the formalisms of diagonal entropy and Jarzynski Equality to study the thermodynamic properties of closed quantum systems. Applying this approach to a quantum harmonic oscillator, the diagonal entropy offers a notion of…

Quantum Physics · Physics 2013-07-09 Van A. Ngo , Stephan Haas

Ensemble inequivalence has been observed in several systems. In particular it has been recently shown that negative specific heat can arise in the microcanonical ensemble in the thermodynamic limit for systems with long-range interactions.…

Statistical Mechanics · Physics 2009-11-07 F. Leyvraz , S. Ruffo