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The van der Waals atom-surface attraction, scaling as C3 z-3 for z the atom-surface distance, is expected to be valid in the distance range 1-1000 nm, covering 8-10 orders of magnitudes in the interaction energy. A Cs vapour nanocell allows…

Wetting behaviour of surfaces is believed to be affected by van der Waals (vdW) forces, however, there is no clear demonstration of this. With the isolation of two-dimensional vdW layered materials it is possible to test this hypothesis. In…

Mesoscale and Nanoscale Physics · Physics 2022-01-26 Meenakshi Annamalai , Kalon Gopinadhan , Sang A Han , Surajit Saha , Hye Jeong Park , Eun Bi Cho , Brijesh Kumar , Sang-Woo Kim , T Venkatesan

We theoretically examined how the dielectric screening of two-dimensional layered materials affects the dipolar interaction between interlayer excitons in few-layer van der Waals structures. Our analysis indicates that the dipolar…

Mesoscale and Nanoscale Physics · Physics 2024-02-14 Yuhang Hou , Hongyi Yu

Large area van der Waals (vdW) thin films are assembled materials consisting of a network of randomly stacked nanosheets. The multi-scale structure and the two-dimensional nature of the building block mean that interfaces naturally play a…

We analyze the vibrational properties of diamondoid compounds via Raman spectroscopy. The compounds are interconnected with carbon-carbon single bonds that exhibit exceptionally large bond lengths up to 1.71 A. Attractive dispersion…

Van der Waals layered and 2D materials constitute an extraordinary playground for condensed matter physics, since the strong confinement of wavefunctions to two dimensions supports a diverse set of correlated phenomena. By creating…

Mesoscale and Nanoscale Physics · Physics 2023-08-14 Joohyung Park , Ayan N. Batyrkhanov , J. R. Schaibley , Oliver L. A. Monti

Recently, the novel system of linear carbon chains inside of double-walled carbon nanotubes has extended the length of $sp^1$ hybridized carbon chains from 44 to thousands of atoms [L. Shi et al., Nat. Mater. 15, 634 (2016)]. The…

Mesoscale and Nanoscale Physics · Physics 2017-05-09 M. Wanko , Seymur Cahangirov , Lei Shi , Philip Rohringer , Zachary J. Lapin , Lukas Novotny , Paola Ayala , Thomas Pichler , Angel Rubio

We study the van der Waals interaction of a metallic or narrow-gap semiconducting nanowire with a surface, in the regime of intermediate wire-surface distances $(v_{F}/c)L \ll d \ll L $ or $L \ll d \ll (c/v_{F})L $, where $L$ is the…

Strongly Correlated Electrons · Physics 2017-09-27 K. A. Makhnovets , A. K. Kolezhuk

Van der Waals forces as interactions between neutral and polarisable particles act at small distances between two objects. Their theoretical origin lies in the electromagnetic interaction between induced dipole moments caused by the vacuum…

Chemical Physics · Physics 2019-06-05 Johannes Fiedler , Clas Persson , Mathias Boström , Stefan Y. Buhmann

Quantum electromagnetic fluctuations induce forces between neutral particles, known as the van der Waals (vdW) and Casimir interactions. These fundamental forces, mediated by virtual photons from the vacuum, play an important role in basic…

Quantum Physics · Physics 2021-05-10 Ephraim Shahmoon , Igor Mazets , Gershon Kurizki

The isolation of a growing number of two-dimensional (2D) materials has inspired worldwide efforts to integrate distinct 2D materials into van der Waals (vdW) heterostructures. Given that any passivated, dangling bond-free surface will…

Materials Science · Physics 2016-08-02 Deep Jariwala , Tobin J. Marks , Mark C. Hersam

Van der Waals (vdW) forces play a fundamental role in the structure and behavior of diverse systems. Thanks to development of functionals that include non-local correlation, it is possible to study the effects of vdW interactions in systems…

Path-integral molecular dynamics simulations based on density functional theory employing exchange-correlation density functionals capable of treating nonlocal van der Waals (vdW) interactions self-consistently provide a remarkably accurate…

Chemical Physics · Physics 2014-02-13 Jeffrey M. McMahon , Miguel A. Morales , Brian Kolb , Timo Thonhauser

Van der Waals torque determines the relative rotational motion between anisotropic objects, being of relevance to low-dimensional systems. Here we demonstrate a substantial torque between anisotropic two-dimensional materials that arises…

Computational Physics · Physics 2024-12-17 Zepu Kou , Yuquan Zhou , Zonghuiyi Jiang , Alexandre Tkatchenko , Xiaofei Liu

We propose a new approach to calculate van der Waals forces between nanoparticles where the van der Waals energy can be reduced to the energy of elementary surface plasmon oscillations in nanoparticles. The general theory is applied to…

Other Condensed Matter · Physics 2015-01-27 V. V. Klimov , A. Lambrecht

While photons in free space barely interact, matter can mediate interactions between them resulting in optical nonlinearities. Such interactions at the single-quantum level result in an on-site photon repulsion, crucial for photon-based…

Mesoscale and Nanoscale Physics · Physics 2020-06-24 Weijie Li , Xin Lu , Sudipta Dubey , Luka Devenica , Ajit Srivastava

We analyze van der Waals interactions between two rigid polymers with sequence-specific, anisotropic polarizabilities along the polymer backbones, so that the dipole moments fluctuate parallel to the polymer backbones. Assuming that each…

Soft Condensed Matter · Physics 2020-10-01 Bing-Sui Lu , Ali Naji , Rudolf Podgornik

The study of novel 2D platforms implementing magnetism in tunable van der Waals (vdW) homo- and hetero-structures paves the way to innovative spintronics and magnetic devices. In this study, we unravel the intriguing properties of few-layer…

Mesoscale and Nanoscale Physics · Physics 2022-09-07 Giovanni Cantele , Felice Conte , Ludovica Zullo , Domenico Ninno

In this paper, an exchange functional which is compatible with the non-local Rutgers-Chalmers correlation functional (vdW-DF) is presented. This functional, when employed with vdW-DF, demonstrates remarkable improvements on intermolecular…

Chemical Physics · Physics 2012-03-12 Valentino R. Cooper

Van der Waals (vdW) interactions are essential for describing molecules and materials, from drug design and catalysis to battery applications. These omnipresent interactions must also be accurately included in machine-learned force fields.…

Chemical Physics · Physics 2026-02-26 Evgeny Moerman , Adil Kabylda , Almaz Khabibrakhmanov , Alexandre Tkatchenko