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We have calculated electronic and optical properties of Si/BeSe$_{0.41}$Te$_{0.59}$ heterostructures by a semiempirical $sp^{3}s^{*}$ tight-binding method. Tight-binding parameters and band bowing of BeSe$_{0.41}$Te$_{0.59}$ are considered…

Materials Science · Physics 2009-07-01 Titus Sandu W. P. Kirk

We report the capability to simulate in a quantum mechanical tight-binding (TB) atomistic fashion NW devices featuring several hundred to millions of atoms and diameter up to 18 nm. Such simulations go far beyond what is typically…

Mesoscale and Nanoscale Physics · Physics 2021-02-05 Aryan Afzalian , Tim Vasen , Peter Ramvall , Matthias Passlack

In recent years, metal halide perovskites (MHPs) for optoelectronic applications have attracted the attention of the scientific community due to their outstanding performance. The fundamental understanding of their physicochemical features…

Materials Science · Physics 2021-04-06 J. M. Vicent-Luna , S. Apergi , S. Tao

We present a method which computes many-electron energies and eigenfunctions by a full configuration interaction which uses a basis of atomistic tight-binding wave functions. This approach captures electron correlation as well as atomistic…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Erik Nielsen , Rajib Rahman , Richard P. Muller

Ab-initio, self-consistent electronic energy bands of rutile TiO2 are reported within the local density functional approximation (LDA). Our first principle, non-relativistic and ground state calculations employed a local density functional…

Materials Science · Physics 2012-03-23 C. E. Ekuma , D. Bagayoko

This article is a pedagogical introduction to density-functional tight-binding (DFTB) method. We derive it from the density-functional theory, give the details behind the tight-binding formalism, and give practical recipes for…

Materials Science · Physics 2009-11-02 Pekka Koskinen , Ville Mäkinen

Semiconducting transition metal dichalcogenides present a complex electronic band structure with a rich orbital contribution to their valence and conduction bands. The possibility to consider the electronic states from a tight-binding model…

Materials Science · Physics 2016-11-15 J. A. Silva-Guillén , P. San-Jose , R. Roldán

Magneto-optical traps are central to atomic and molecular quantum technologies and precision tests of fundamental physics, where both sensitivity and bandwidth scale strongly with atom number and loading rate. We demonstrate that employing…

This chapter discusses contemporary quantum chemical methods and provides general insights into modern electronic structure theory with a focus on heavy-element-containing compounds. We first give a short overview of relativistic…

Chemical Physics · Physics 2020-02-18 Aleksandra Leszczyk , Paweł Tecmer , Katharina Boguslawski

We employ a tight-binding parametrization based on the Slater Koster model in order to fit the band structures of single-layer, bilayer and bulk black phosphorus obtained from first-principles calculations. We find that our model, which…

Mesoscale and Nanoscale Physics · Physics 2017-12-13 Marcos G. Menezes , Rodrigo B. Capaz

Topological states of matter, first discovered in quantum systems, have opened new avenues for wave manipulation beyond the quantum realm. In elastic media, realizing these topological effects requires identifying lattices that support the…

Materials Science · Physics 2025-03-24 Pegah Azizi , Rahul Dev Kundu , Weichen Li , Kai Sun , Xiaojia Shelly Zhang , Stefano Gonella

Interatomic potentials provide a means to simulate extended length and time scales that are outside the reach of ab initio calculations. The development of an interatomic potential for a particular material requires the optimization of the…

Materials Science · Physics 2023-03-14 Aparna P. A. Subramanyam , Jan Jenke , Alvin Noe Ladines , Ralf Drautz , Thomas Hammerschmidt

The energy positions of frontier orbitals in organic electronic materials are often studied experimentally by (inverse) photoemission spectroscopy and theoretically within density functional theory. However, standard exchange-correlation…

Bi2Se3 and Bi2Te3 are layered compounds of technological importance, being excellent thermoelectric materials as well as topological insulators. We report density functional theory calculations of the atomic, electronic and thermoelectric…

Materials Science · Physics 2013-08-08 Xin Luo , Michael B. Sullivan , Su Ying Quek

Semi-Empirical Tight Binding (TB) is known to be a scalable and accurate atomistic representation for electron transport for realistically extended nano-scaled semiconductor devices that might contain millions of atoms. In this paper an…

Materials Science · Physics 2015-06-18 Ganesh Hegde , Michael Povolotskyi , Tillmann Kubis , Timothy Boykin , Gerhard Klimeck

We have performed first-principles calculations of Si/SiO$_2$ superlattices in order to examine their electronic states, confinement and optical transitions, using linearized-augmented-plane-wave techniques and density-functional theory.…

Materials Science · Physics 2009-11-07 Pierre Carrier , Laurent J. Lewis , M. W. Chandre Dharma-wardana

This research work introduces the DFT through FP-LAPW+lo technique in WIEN2k software to obtain information about structural, thermoelectric, and optoelectronic characteristics of CaZnC and CaZnSi materials. The structural optimization was…

Materials Science · Physics 2025-12-29 P. K. Kamlesh , U. K. Gupta , S. Verma , M. Rani , Y. Toual , A. S. Verma

Quantum parameter estimation is central to many fields such as quantum computation, communications and metrology. Optimal estimation theory has been instrumental in achieving the best accuracy in quantum parameter estimation, which is…

Quantum Physics · Physics 2015-06-18 Shibdas Roy , Ian R. Petersen , Elanor H. Huntington

We outline a partial-fractions decomposition method for determining the one-particle spectral function and single-particle density of states of a correlated electronic system on a finite lattice in the non self-consistent T-matrix…

Strongly Correlated Electrons · Physics 2009-11-10 R. J. Gooding , F. Marsiglio , S. Verga , K. S. D. Beach

A method is presented for calculating binding energies and other properties of extended interacting systems using the projected density of transitions (PDoT) which is the probability distribution for transitions of different energies…

Strongly Correlated Electrons · Physics 2009-10-31 Roger Haydock
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