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Work is a process-based quantity, and its measurement typically requires interaction with a measuring device multiple times. While classical systems allow for non-invasive and accurate measurements, quantum systems present unique challenges…

Quantum Physics · Physics 2025-06-17 Giulia Rubino , Karen V. Hovhannisyan , Paul Skrzypczyk

The characteristic function for the joint measurement of the changes of two commuting observables upon an external forcing of a quantum system is derived. In particular, the statistics of the internal energy, the exchanged heat and the work…

Statistical Mechanics · Physics 2009-02-18 Peter Talkner , Michele Campisi , Peter Hänggi

Based on the observation that the thermodynamic equilibrium free energy of an open quantum system in contact with a thermal environment can be understood as the difference between the free energy of the total system and that of the bare…

Statistical Mechanics · Physics 2009-06-01 Michele Campisi , Peter Talkner , Peter Hänggi

Thermodynamics constrains changes to the energy of a system, both deliberate and random, via its first and second laws. When the system is not in equilibrium, fluctuation theorems such as the Jarzynski equality further restrict the…

A result of great theoretical and experimental interest, Jarzynski equality predicts a free energy change $\Delta F$ of a system at inverse temperature $\beta$ from an ensemble average of non-equilibrium exponential work, i.e., $\langle…

Statistical Mechanics · Physics 2017-10-18 Juan D. Jaramillo , Jiawen Deng , Jiangbin Gong

We present a generalization of Jarzynski's Equality, applicable to quantum systems, relating discretized mechanical work and free-energy changes. The theory is based on a step-wise pulling protocol. We find that work distribution functions…

Quantum Physics · Physics 2012-09-21 Van A. Ngo , Stephan Haas

We propose a method to evaluate general thermodynamic fluctuations in open quantum systems, based on performing a two-point measurement scheme on the system using dynamics-dependent thermodynamic observables. Our approach allows one to…

Quantum Physics · Physics 2026-04-30 Alessandra Colla , Andrea Smirne , Heinz-Peter Breuer , Bassano Vacchini

When a thermally isolated system performs a driving process in the quasistatic regime, its variation of average energy is equal to its quasistatic work. Even though presenting this simple definition, few attempts have been made to describe…

Statistical Mechanics · Physics 2025-02-17 Pierre Nazé

The fluctuation theorems, and in particular, the Jarzynski equality, are the most important pillars of modern non-equilibrium statistical mechanics. We extend the quantum Jarzynski equality together with the Two-Time Measurement Formalism…

Statistical Mechanics · Physics 2018-03-01 Anthony Bartolotta , Sebastian Deffner

The characteristic function of the work performed by an external time-dependent force on a Hamiltonian quantum system is identified with the time-ordered correlation function of the exponentiated system's Hamiltonian. A similar expression…

Statistical Mechanics · Physics 2009-11-13 Peter Talkner , Eric Lutz , Peter Hanggi

In this paper we present a first-principles analysis of the nonequilibrium work distribution and the free energy difference of a quantum system interacting with a general environment (with arbitrary spectral density and for all…

Quantum Physics · Physics 2012-02-07 Y. Subasi , B. L. Hu

The Jarzynski equality allows the calculation of free-energy differences using values of work measured from nonequilibrium trajectories. The number of trajectories required to accurately estimate free-energy differences in this way grows…

Statistical Mechanics · Physics 2025-05-13 Stephen Whitelam

The Jarzynski equality relates the free energy difference between two equilibrium states to the fluctuating irreversible work afforded to switch between them. The prescribed fixed temperature for the equilibrium states implicitly constrains…

Statistical Mechanics · Physics 2020-09-03 Tobias Thalheim , Marco Braun , Gianmaria Falasco , Klaus Kroy , Frank Cichos

The validity of the Jarzynski equation for a very simple, exactly solvable quantum system is analyzed. The implications of two different definitions of work proposed in the literature are investigated. The first one derives from…

Statistical Mechanics · Physics 2009-11-11 A. Engel , R. Nolte

Non-equilibrium quantum thermodynamics is essential to describe new devices that operate far from the regime where the usual thermodynamical laws are obeyed. When quantum fluctuations dominate, defining and measuring work and heat, two…

We investigate the connection between recent results in quantum thermodynamics and fluctuation relations by adopting a fully quantum mechanical description of thermodynamics. By including a work system whose energy is allowed to fluctuate,…

Quantum Physics · Physics 2017-03-27 Álvaro M. Alhambra , Lluis Masanes , Jonathan Oppenheim , Christopher Perry

Quantum work fluctuation theorem (FT) commonly requires the system initially prepared in an equilibrium state. Whether there exists universal exact quantum work FT for initial state beyond equilibrium needs further discussions. Here, I…

Statistical Mechanics · Physics 2024-01-12 Bao-Ming Xu

We consider the quantum mechanical generalization of Crooks Fluctuation Theorem and Jarzynski Equality for an open quantum system. The explicit expression for microscopic work for an arbitrary prescribed protocol is obtained, and the…

Statistical Mechanics · Physics 2008-12-31 H. T. Quan , H. Dong

The nonequilibrium work relation, or Jarzynski equality, establishes a statistical relationship between a series of nonequilibrium experiments on a system subjected to thermal fluctuations and a hypothetical experiment at thermodynamic…

Statistical Mechanics · Physics 2024-11-19 Jean-Luc Garden

In open quantum systems, a clear distinction between work and heat is often challenging, and extending the quantum Jarzynski equality to systems evolving under general quantum channels beyond unitality remains an open problem in quantum…

Quantum Physics · Physics 2020-08-10 Akira Sone , Yi-Xiang Liu , Paola Cappellaro
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