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Work in the paradigm of the quantum fluctuation theorems of Crooks and Jarzynski is determined by projective measurements of energy at the beginning and end of the force protocol. In analogy to classical systems, we consider an alternative…

Statistical Mechanics · Physics 2015-08-04 B. Prasanna Venkatesh , Gentaro Watanabe , Peter Talkner

Fluctuation relations allow for the computation of equilibrium properties, like free energy, from an ensemble of non-equilibrium dynamics simulations. Computing them for quantum systems, however, can be difficult, as performing dynamic…

Quantum Physics · Physics 2021-09-07 Lindsay Bassman , Katherine Klymko , Diyi Liu , Norman M. Tubman , Wibe A. de Jong

We extend the quantum jump method to nearly adiabatically driven open quantum systems in a way that allows for an accurate account of the external driving in the system-environment interaction. Using this framework, we construct the…

Quantum Physics · Physics 2015-03-30 S. Suomela , J. Salmilehto , I. G. Savenko , T. Ala-Nissila , M. Möttönen

Of indisputable relevance for non-equilibrium thermodynamics, fluctuations theorems have been generalized to the framework of quantum thermodynamics, with the notion of work playing a key role in such contexts. The typical approach consists…

Quantum Physics · Physics 2023-06-28 Thales Augusto Barbosa Pinto Silva , Renato Moreira Angelo

Characterizing fluctuations of work in coherent quantum systems is notoriously problematic. Here we reveal the ultimate source of the problem by proving that ($\mathfrak{A}$) energy conservation and ($\mathfrak{B}$) the Jarzynski…

Quantum Physics · Physics 2024-05-08 Karen V. Hovhannisyan , Alberto Imparato

There are two related theorems which hold even in far from equilibrium, namely fluctuation theorem and Jarzynski equality. Fluctuation theorem states the existence of symmetry of fluctuation of entropy production, while Jarzynski equality…

Statistical Mechanics · Physics 2009-11-10 T. Monnai

Jarzynski equality and related fluctuation theorems can be formulated for various setups. Such an equality was recently derived for nonunitary quantum evolutions described by unital quantum operations, i.e., for completely positive,…

Quantum Physics · Physics 2014-01-24 Alexey E. Rastegin , Karol Życzkowski

Fluctuation theorems impose constraints on possible work extraction probabilities in thermodynamical processes. These constraints are stronger than the usual second law, which is concerned only with average values. Here, we show that such…

Quantum Physics · Physics 2020-02-21 Paul Boes , Rodrigo Gallego , Nelly H. Y. Ng , Jens Eisert , Henrik Wilming

We present a general quantum fluctuation theorem for the entropy production of an open quantum system coupled to multiple environments, not necessarily at equilibrium. Such a general theorem, when restricted to the weak-coupling and…

Quantum Physics · Physics 2022-06-29 Gabriele De Chiara , Alberto Imparato

It has been established that the inclusive work for classical, Hamiltonian dynamics is equivalent to the two-time energy measurement paradigm in isolated quantum systems. However, a plethora of other notions of quantum work has emerged, and…

Statistical Mechanics · Physics 2021-04-08 Akira Sone , Sebastian Deffner

In this Letter we investigate the concept of quantum work and its measurability from the viewpoint of quantum measurement theory. Very often, quantum work and fluctuation theorems are discussed in the framework of projective two-point…

Quantum Physics · Physics 2022-08-11 Konstantin Beyer , Roope Uola , Kimmo Luoma , Walter T. Strunz

Jarzynski's theorem is a well-known equality in statistical mechanics, which relates fluctuations in the work performed during a non-equilibrium transformation of a system, to the free-energy difference between two equilibrium ensembles. In…

High Energy Physics - Lattice · Physics 2016-08-16 Michele Caselle , Gianluca Costagliola , Alessandro Nada , Marco Panero , Arianna Toniato

Generalized measurements of an observable performed on a quantum system during a force protocol are investigated and conditions that guarantee the validity of the Jarzynski equality and the Crooks relation are formulated. In agreement with…

Statistical Mechanics · Physics 2014-03-14 Gentaro Watanabe , B. Prasanna Venkatesh , Peter Talkner , Michele Campisi , Peter Hänggi

The Jarzynski equality, which relates equilibrium free-energy difference to an average of non-equilibrium work, plays a central role in modern non-equilibrium statistical thermodynamics. In this paper, we study a weaker consequence of this…

Statistical Mechanics · Physics 2026-01-06 Dani R. Castellanos , Petr Jizba

The transient quantum fluctuation theorems of Crooks and Jarzynski restrict and relate the statistics of work performed in forward and backward forcing protocols. So far these theorems have been obtained under the assumption that the work…

Statistical Mechanics · Physics 2014-02-07 B. Prasanna Venkatesh , Gentaro Watanabe , Peter Talkner

Many studies of quantum-size heat engines assume that the dynamics of an internal system is unitary and that the extracted work is equal to the energy loss of the internal system. Both assumptions, however, should be under scrutiny. In the…

Statistical Mechanics · Physics 2017-04-05 Yohei Morikuni , Hiroyasu Tajima , Naomichi Hatano

We derive exact fluctuation equalities for open systems that recover free energy differences between two equilibrium endpoints connected by nonequilibrium processes with arbitrary dynamics and coupling. The exponential of the free energy…

Statistical Mechanics · Physics 2025-12-15 Mohammad Rahbar , Christopher J. Stein

The imaginary-time path integral representation of the canonical partition function of a quantum system and non-equilibrium work fluctuation relations are combined to yield methods for computing free energy differences in quantum systems…

Statistical Mechanics · Physics 2009-11-13 Ramses van Zon , Lisandro Hernandez de la Pena , Gilles H. Peslherbe , Jeremy Schofield

The universal quantum work relation connects a functional of an arbitrary observable averaged over the forward process to the free energy difference and another functional averaged over the time-reversed process. Here, we ask the question…

Quantum Physics · Physics 2012-04-18 Arun Kumar Pati , Mamata Sahoo , Biswajit Pradhan

We reconsider a well-known relationship between the fluctuation theorem and the second law of thermodynamics by evaluating a probability measure-valued process. In order to establish a bridge between microscopic and macroscopic behaviors,…

Statistical Mechanics · Physics 2015-03-19 Yuki Sughiyama , Masayuki Ohzeki