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Based on differential thermal analysis (DTA) and X-ray powder diffraction (XRD), a description of the system Nd$_2$O$_3$--Lu$_2$O$_3$--Sc$_2$O$_3$ was obtained by thermodynamic assessment. Four fields of primary crystallization could be…

Materials Science · Physics 2018-11-14 Tamino Hirsch , Christo Guguschev , Albert Kwasniewski , Steffen Ganschow , Detlef Klimm

The first-principles calculations have been performed to investigate the ground state properties of cubic scandium trifluoride (ScF$_3$) perovskite. Using modified hybrid exchange-correlation functionals within the density functional theory…

Materials Science · Physics 2012-11-27 P. Zhgun , D. Bocharov , S. Piskunov , A. Kuzmin , J. Purans

The cubic perovsike strontium titanate SrTiO$_3$ (STO) is one of the most studied, polarizable transition metal oxides. When excess charge is introduced to this material, e.g., through doping or atomic defects, STO tends to host polarons:…

Materials Science · Physics 2022-09-13 Florian Ellinger , Muhammad Shafiq , Iftikhar Ahmad , Michele Reticcioli , Cesare Franchini

Single-crystalline perovskite oxide membranes provide a powerful platform to access physical properties that are inaccessible in bulk crystals and substrate-clamped thin films. Within this context, the deliberate fabrication of tailored…

Materials Science · Physics 2026-04-15 Marti Ramis , Markos Paradinas , Jose M. Caicedo , Claudio Cazorla , Roger Guzman , Mariona Coll

The surface structure of the SrTiO$_3$(110) polar surface is studied by scanning tunneling microscopy and X-ray photoelectron spectroscopy. Monophased reconstructions in (5$\times$1), (4$\times$1), (2$\times$8), and (6$\times$8) are…

Materials Science · Physics 2015-05-20 Zhiming Wang , Fang Yang , Zhiqiang Zhang , Yuanyuan Tang , Jiagui Feng , Kehui Wu , Qinlin Guo , Jiandong Guo

The efficiency and stability of halide perovskite-based solar cells and light-emitting diodes directly depend on the intricate dynamics of solid-solid crystallization[1-23]. In this study, we employ a multi-scale approach using random phase…

Materials Science · Physics 2024-04-09 Paramvir Ahlawat

The Raman spectra on the cleaved surface of La$_{2-x}$Sr$_x$CuO$_4$ is found to be different from those on the mechanically polished or chemically etched surface. On the cleaved surface, the step-like increase of the scattering intensity…

Superconductivity · Physics 2007-05-23 S. Sugai , Y. Takayanagi , N. Hayamizu

We have studied the surface of pure and oxidized Pt$_3$Zr(0001) by scanning tunneling microscopy (STM), Auger electron microscopy, and density functional theory (DFT). The well-annealed alloy surface shows perfect long-range chemical order.…

PbTiO3 has the highest tetragonal distortion (c/a=1.064) and highest spontaneous polarization among perovskite titanates. But, it is hazardous and hence one needs to reduce Pb content by substituting or reducing Pb content for use in…

A simple theoretical model is proposed to describe the recent experimental results on formation of induced superconducting state and anomalous tunneling characteristics in selectively doped multilayered nanostructures based on La$_2$CuO$_4$…

Superconductivity · Physics 2009-11-13 V. M. Loktev , Yu. G. Pogorelov

We report the first single crystal growth of the correlated metal LaNiO3 using a high-pressure optical-image floating zone furnace. The crystals were studied using single crystal/powder x-ray diffraction, resistivity, specific heat, and…

Materials Science · Physics 2017-10-17 Junjie Zhang , Hong Zheng , Yang Ren , J. F. Mitchell

Halide perovskites are a promising class of materials for optoelectronic applications, due to their excellent optoelectronic performance. However, they suffer several dynamical degradation problems, the characterization of which is…

Materials Science · Physics 2021-11-01 Sander Raaijmakers , Mike Pols , José Manuel Vicent-Luna , Shuxia Tao

SrTiO$_3$ is a highly efficient photocatalyst for the overall water splitting reaction under UV irradiation. However, an atomic-level understanding of the active surface sites responsible for the oxidation and reduction reactions is still…

Growth of perovskite oxide thin films on Si in crystalline form has long been a critical obstacle for the integration of multifunctional oxides into Si-based technologies. In this study, we propose pulsed laser deposition of a crystalline…

Materials Science · Physics 2017-05-15 Sang A Lee , Jae-Yeol Hwang , Eun Sung Kim , Sung Wng Kim , Woo Seok Choi

Single crystals of PrNiO3 were grown under an oxygen pressure of 295 bar using a unique high-pressure optical-image floating zone furnace. The crystals, with volume in excess of 1 mm3, were characterized structurally using single crystal…

Potassium tantalate KTaO3 is a cubic, paraelectric perovskite ceramic that exhibits surprising ductility at room temperature as most recently reported. Much like strontium titanate (SrTiO3), plastic deformation is accommodated by…

Materials Science · Physics 2025-02-05 Pierre Hirel , Franck Junior Kakdeu Yewou , Jiawen Zhang , Wenjun Lu , Xufei Fang , Philippe Carrez

We extend our previous first-principles theory for perovskite ferroelectric phase transitions to treat also antiferrodistortive phase transitions. Our approach involves construction of a model Hamiltonian from a Taylor expansion,…

Materials Science · Physics 2008-02-03 David Vanderbilt , W. Zhong

A novel approach to control the grain size of oxide thin film materials has been investigated. Perovskite BaTiO3 shows interesting grain structures when deposited on gold predeposited, (111)-oriented, singlecrystal SrTiO3 substrates. Solid…

Mesoscale and Nanoscale Physics · Physics 2010-04-20 Yaodong Yang , Jianjun Yao , Yu U. Wang , Jiefang Li , Jaydip Das , Dwight Viehland

In this paper, we use permutation elements to record cylinder decompositions of a square-tiled surface $X$. Collecting all such possible permutation elements that record cylinder decompositions, we can enumerate the $SL_2(\mathbb{Z})$ orbit…

Dynamical Systems · Mathematics 2012-07-17 Kuo-Chiang Tan

We propose to insert TiO layers to perovskite ATiO$_{3}$ to form a superlattice and use first-principles calculations to investigate its basic properties. Our computational analysis shows that the structure, which consists of repeated…

Materials Science · Physics 2020-02-11 S. Raza , R. Zhang , N. Zhang , Z. Li , L. Liu , F. Zhang , D. Wang , C. -L. Jia