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Intermolecular interactions are pivotal for aggregation, solvation, and crystallization. We demonstrate that the collective strong coupling of several molecules to a single optical mode results in notable changes in the molecular…

Quantum Physics · Physics 2024-02-19 Matteo Castagnola , Tor S. Haugland , Enrico Ronca , Henrik Koch , Christian Schäfer

Phase transitions, where observable properties of a many-body system change discontinuously, can occur in both open and closed systems. Ultracold atoms have provided an exemplary model system to demonstrate the physics of closed-system…

Optical microcavities and metallic nanostructures have been shown to significantly modulate the dynamics and spectroscopic response of molecular systems. We present a study of the nonlinear optics of a model consisting of $N$ anharmonic…

Light-matter interactions are known to lead to the formation of polariton states through what is called strong coupling, leading to the formation of two hybrid states usually tagged as Upper and Lower Polaritons. Here, we consider a similar…

Polaritons - hybrid light-matter states formed in cavity - strongly change the properties of the underlying matter. In optical or plasmonic nanocavities, polaritons decay by radiative emission of the cavity, which is accessible…

Chemical Physics · Physics 2022-10-19 Csaba Fábri , Gábor J. Halász , Lorenz S. Cederbaum , Ágnes Vibók

Molecular polaritons are hybrid light-matter states that enable the exploration of potential cavity-modified chemistry. The development of dynamical, first-principles approaches for simulating molecular polaritons is important for…

Chemical Physics · Physics 2025-07-18 Millan F. Welman , Tao E. Li , Sharon Hammes-Schiffer

Quantum dynamics of the photoisomerization of a single 3,3'-diethyl-2,2'-thiacynine iodide molecule embedded in an optical microcavity was theoretically studied. The molecule was coupled to a single cavity mode via the quantum Rabi…

Quantum Physics · Physics 2019-10-01 Juan B. Pérez-Sánchez , Joel Yuen-Zhou

Exciton-polaritons are hybrid elementary excitations of light and matter that, thanks to their nonlinear properties, enable a plethora of physical phenomena ranging from room temperature condensation to superfluidity. While polaritons are…

Mesoscale and Nanoscale Physics · Physics 2022-03-23 Davide Nigro , Vincenzo D'Ambrosio , Daniele Sanvitto , Dario Gerace

Polaritons, mixed light-matter quasiparticles, undergo a transition to a condensed, macroscopically coherent state at low temperatures or high densities. Recent experiments show that coupling light to organic molecules inside a microcavity…

Quantum Gases · Physics 2014-03-06 Justyna A. Cwik , Sahinur Reja , Peter B. Littlewood , Jonathan Keeling

We theoretically study how the peculiar properties of the vacuum state of an ultra-strongly coupled system can affect basic light-matter interaction processes. In this unconventional electromagnetic environment, an additional emitter no…

Quantum Physics · Physics 2025-03-06 Daniele De Bernardis , Gian Marcello Andolina , Iacopo Carusotto

We investigate the steady states of a lossy array of nonlinear optical resonators that are driven by lasers and interact via mutual photon tunneling. For weak nonlinearities, we find two-mode squeezing of polaritons in modes whose…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Michael J. Hartmann

We develop a theory for light propagating in an atomic Bose-Einstein condensate in the presence of strong interactions. The resulting many-body correlations are shown to have profound effects on the optical properties of this interacting…

Quantum Gases · Physics 2020-05-06 A. Camacho-Guardian , K. Knakkergaard Nielsen , T. Pohl , G. M. Bruun

We introduce crystal polaritons, hybrid excitations formed when the collective excitations of a periodic quantum-emitter array strongly couple to the resonant Bloch modes of a metasurface. This realizes a cavity-QED platform in which…

Strong light-matter coupling is a quantum process in which light and matter are coupled together, generating hybridized states. This is similar to the notion of molecular hybridization, but one of the components is light. Here, we utilized…

Applied Physics · Physics 2024-02-20 Jhuma Dutta , Pooja Bhatt , Kuljeet Kaur , Daniel E. Gómez , Jino George

This perspective provides a brief introduction into the theoretical complexity of polaritonic chemistry, which emerges from the hybrid nature of strongly coupled light-matter states. To tackle this complexity, the importance of ab initio…

Chemical Physics · Physics 2022-06-29 Dominik Sidler , Michael Ruggenthaler , Christian Schäfer , Enrico Ronca , Angel Rubio

Microcavity polaritons are light-matter quasiparticles that arise from the strong coupling between excitons and photons confined in a semiconductor microcavity. They typically operate at visible or near visible wavelengths. They combine the…

Mesoscale and Nanoscale Physics · Physics 2020-11-06 Dmitry D. Solnyshkov , Guillaume Malpuech , Philippe St-Jean , Sylvain Ravets , Jacqueline Bloch , Alberto Amo

Polaritons are a superposition of light and matter, that combine Strong Interferences (of light) with Weak Interactions (of excitons), making them WISI (Weakly-Interacting, Strongly-Interfering) particles. Their condensation is the main…

Quantum Gases · Physics 2026-05-18 Fabrice Laussy

As pioneering experiments have shown, strong vibrational coupling between molecular vibrations and light modes in an optical cavity can significantly alter molecular properties and even affect chemical reactivity. However, the current…

Chemical Physics · Physics 2024-07-26 Thomas Schnappinger , Markus Kowalewski

Nonperturbative coupling between cavity photons and excitons leads to formation of hybrid light-matter excitations termed polaritons. In structures where photon absorption leads to creation of excitons with aligned permanent dipoles, the…

Mesoscale and Nanoscale Physics · Physics 2018-11-30 Emre Togan , Hyang-Tag Lim , Stefan Faelt , Werner Wegscheider , Atac Imamoglu

Using microscopic models in which both photons and excitons are treated as microscopic degrees of freedom, we discuss polaritons of two cases: One is the case when excitonic parameters are time dependent. The time dependence causes creation…

Quantum Physics · Physics 2011-04-15 Akira Shimizu , Teruaki Okushima , Kazuki Koshino
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