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Intramolecular energy transfer driven by near-field effects plays an important role in applications ranging from biophysics and chemistry to nano-optics and quantum communications. Advances in strong light-matter coupling in molecular…

Mesoscale and Nanoscale Physics · Physics 2025-07-14 Kristin B. Arnardottir , Piper Fowler-Wright , Christos Tserkezis , Brendon W. Lovett , Jonathan Keeling

We propose a new type of spatially periodic structure, i.e. polaritonic crystal (PolC), to observe a "slow"/"stopped" light phenomenon due to coupled atom-field states (polaritons) in a lattice. Under the tightbinding approximation, such a…

Quantum Gases · Physics 2015-05-18 A. P. Alodjants , I. O. Barinov , S. M. Arakelian

Strong light-matter coupling provides a versatile and novel means to manipulate chemical processes. Here we develop a theoretical framework to investigate the spectroscopy and dynamics of a molecular ensemble embedded in an optical cavity…

Quantum Physics · Physics 2023-06-16 Bing Gu

Light-matter interactions can occur when an ensemble of molecular resonators is placed in a confined electromagnetic field. In the strong coupling regime the rapid exchange of energy between the molecules and the electromagnetic field…

Mesoscale and Nanoscale Physics · Physics 2020-08-10 Philip A. Thomas , Wai Jue Tan , Henry A. Fernandez , William L. Barnes

A quantum system composed of a molecule and an atomic ensemble, confined in a microscopic cavity, is investigated theoretically. The indirect coupling between atoms and the molecule, realized by their interaction with the cavity radiation…

Chemical Physics · Physics 2020-05-05 Tamás Szidarovszky , Gábor J. Halász , Ágnes Vibók

Polaritons are unique hybrid light-matter states that offer an alternative way to manipulate chemical processes and change material properties. In this work we theoretically demonstrate that singlet fission dynamics can be accelerated under…

Chemical Physics · Physics 2021-10-06 Clàudia Climent , David Casanova , Johannes Feist , Francisco J. García-Vidal

Forming new hybrid quasiparticles by strong light-matter coupling is a promising tool for tailoring photophysics and photochemistry of molecules. Thus, the ultrafast dynamics of polaritons formed upon strong light-matter coupling has been…

Chemical Physics · Physics 2025-05-23 Luca Nils Philipp , Eva Münzel , Julian Lüttig , Roland Mitrić

Intermolecular bonds are weak compared to covalent bonds, but they are strong enough to influence the properties of large molecular systems. In this work, we investigate how strong light-matter coupling inside an optical cavity can modify…

Chemical Physics · Physics 2021-03-17 Tor S. Haugland , Christian Schäfer , Enrico Ronca , Angel Rubio , Henrik Koch

Vibrational polaritons are formed by strong coupling of molecular vibrations and photon modes in an optical cavity. Experiments have demonstrated that vibrational strong coupling can change molecular properties and even affect chemical…

Quantum Physics · Physics 2025-01-14 Thomas Schnappinger , Cyril Falvo , Markus Kowalewski

Light-matter systems allow to realize a strongly correlated phase where photons are present. In these systems strong correlations are achieved by optical nonlinearities, which appear due to the coupling of photons to atomic-like structures.…

Mesoscale and Nanoscale Physics · Physics 2011-06-10 Michael Knap , Enrico Arrigoni , Wolfgang von der Linden

Coupling between light and material excitations underlies a wide range of optical phenomena. Polaritons are eigenstates of a coupled system with hybridized wave function. Owing to their hybrid composition, polaritons exhibit at the same…

Optics · Physics 2022-12-27 Denis G. Baranov , Christian Schäfer , Maxim V. Gorkunov

Polaritons are an emerging platform for exploration of synthetic materials [1] and quantum information processing [2] that draw properties from two disparate particles: a photon and an atom. Cavity polaritons are particularly promising, as…

Optical polaritons appear when a material excitation strongly couples to the optical mode. Such strong coupling between molecular transitions and optical cavities results in far-reaching opportunities in modifying fundamental properties of…

Modifying the energy landscape of existing molecular emitters is an attractive challenge with favourable outcomes in chemistry and organic optoelectronic research. It has recently been explored through strong light-matter coupling studies…

We consider parametric interactions of laser pulses in a coherent macroscopic ensemble of resonant atoms, which are possible in the strong coupling regime of light-matter interaction. The spectrum condensation (lasing at collective vacuum…

Quantum Physics · Physics 2007-05-23 I. B. Mekhov , V. S. Egorov , V. N. Lebedev , P. V. Moroshkin , I. A. Chekhonin , S. N. Bagayev

Strong coupling between vibrational transitions in molecules within a resonant optical microcavity leads to the formation of collective, delocalized vibrational polaritons. There are many potential applications of "polaritonic chemistry,"…

Chemical Physics · Physics 2021-11-05 Rong Duan , Joseph N. Mastron , Yin Song , Kevin J. Kubarych

The interaction of organic molecules and molecular aggregates with electromagnetic fields that are strongly confined inside optical cavities within nanoscale volumes, has allowed the observation of exotic quantum regimes of light-matter…

Quantum Physics · Physics 2018-01-30 Felipe Herrera , Frank C. Spano

Despite the potential paradigm breaking capability of microcavities to control chemical processes, the extent to which photonic devices change properties of molecular materials is still unclear, in part due to challenges in modeling hybrid…

Chemical Physics · Physics 2021-12-30 Raphael F. Ribeiro

Magnon-polaritons are hybrid light-matter quasiparticles originating from the strong coupling between magnons and photons. They have emerged as a potential candidate for implementing quantum transducers and memories. Owing to the dampings…

Quantum Physics · Physics 2017-11-15 Dengke Zhang , Xiao-Qing Luo , Yi-Pu Wang , Tie-Fu Li , J. Q. You

We demonstrate strong coupling between molecular excited states and surface plasmon modes of a slit array in a thin metal film. The coupling manifests itself as an anti-crossing behavior of the two newly formed polaritons. As the coupling…

Mesoscale and Nanoscale Physics · Physics 2012-08-17 Adi Salomon , Robert J. Gordon , Yehiam Prior , Tamar Seideman , Maxim Sukharev