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Spinel compounds AB$_{2}$X$_{4}$ consist of both tetrahedral (AX$_{4}$) and octahedral (BX$_{6}$) environments with the former forming a diamond lattice and the latter a geometrically frustrated pyrochlore lattice. Exploring the fascinating…

Chemical Physics · Physics 2023-03-29 Qiang Zhang , Wei Tian , Roshan K. Nepal , Ashfia Huq , Stephen Nagler , J. F. DiTusa , Rongying Jin

Iron-bearing oxides undergo a series of pressure-induced electronic, spin and structural transitions that can cause seismic anomalies and dynamic instabilities in Earth's mantle and outer core. We employ x-ray diffraction and x-ray emission…

Strongly Correlated Electrons · Physics 2023-07-10 E. Greenberg , R. Nazarov , A. Landa , J. Ying , R. Q. Hood , B. Hen , R. Jeanloz , V. B. Prakapenka , V. V. Struzhkin , G. Kh. Rozenberg , I. Leonov

The application of pressure can induce transitions between unconventional quantum phases in correlated materials. The inorganic compound TiOCl, composed of chains of S=1/2 Ti ions, is an ideal realization of a spin-Peierls system with a…

Strongly Correlated Electrons · Physics 2018-02-21 Costel R. Rotundu , Jiajia Wen , Wei He , Yongseong Choi , Daniel Haskel , Young S. Lee

The magnetic structure for the newly discovered iron-arsenide compound \CaFeAs has been studied by neutron powder diffraction. Long-range magnetic order is detected below 85K, with an incommensurate modulation described by the propagation…

Strongly Correlated Electrons · Physics 2011-06-30 P. Manuel , L. C. Chapon , I. S. Todorov , D. Y. Chung , J. -P. Castellan , S. Rosenkranz , R. Osborn , P. Toledano , M. G. Kanatzidis

The Fe(1+x)Sb compound has been synthesized close to stoichiometry with x = 0.023(8). The compound was investigated by 57Fe M\"ossbauer spectroscopy in the temperature range 4.2 - 300 K. The antiferromagnetic ordering temperature was found…

Strongly Correlated Electrons · Physics 2016-01-20 K. Komedera , A. K. Jasek , A. Blachowski , K. Ruebenbauer , A. Krzton-Maziopa

We present comprehensive high magnetic field studies of the alternating weakly coupled ferro-antiferromagnetic (FM-AFM) spin-$1/2$ chain compound Cu$_2$(OH)$_3$Br, with the structure of the natural mineral botallackite. Our measurements…

Strongly Correlated Electrons · Physics 2024-12-17 K. Yu. Povarov , Y. Skourskii , J. Wosnitza , D. E. Graf , Z. Zhao , S. A. Zvyagin

Synchrotron X-ray diffraction patterns were measured and analyzed for a polycrystalline sample of the room-temperature ferromagnet Sr3.12Er0.88Co4O10.5 from 300 to 650 K, from which two structural phase transitions were found to occur…

Strongly Correlated Electrons · Physics 2009-11-13 Shintaro Ishiwata , Wataru Kobayashi , Ichiro Terasaki , Kenichi Kato , Masaki Takata

Alkali superoxides differ from conventional transition metal magnets, exhibit magnetism from partially occupied oxygen molecular $\pi^*$-orbitals. Among them, CsO$_2$ stands out for its potential to exhibit novel quantum collective…

Strongly Correlated Electrons · Physics 2024-11-12 Ryota Ono , Ravi Kaushik , Sergey Artyukhin , Martin Jansen , Igor Solovyev , Russell A. Ewings

We present a systematic study of the magnetic properties of L1$_0$ binary alloys FeNi, CoNi, MnAl and MnGa via two different density functional theory approaches. Our calculations show large magnetocrystalline anisotropies in the order…

Materials Science · Physics 2015-02-23 Alexander Edström , Jonathan Chico , Adam Jakobsson , Anders Bergman , Jan Rusz

The rare-earth based ternary intermetallic compounds $R_2TX_3$ ($R$ = rare-earth, $T$ = transition-metal, $X$ = Si, Ge, Ga, In) have attracted considerable interest due to a wide range of interesting low temperature properties. Here we…

Strongly Correlated Electrons · Physics 2019-10-25 M. Smidman , C. Ritter , D. T. Adroja , S. Rayaprol , T. Basu , E. V. Sampathkumaran , A. D. Hillier

Murunskite (K$_2$FeCu$_3$S$_4$) is a bridging compound between the only two known families of high-temperature superconductors. It is a semiconductor like the parent compounds of cuprates, yet isostructural to metallic iron-pnictides.…

In this paper we demonstrate the application of high magnetic fields to study the magnetic properties of low dimensional spin systems. We present a case study on the series of 2-leg spin-ladder compounds…

High entropy oxides (HEO) are a recently introduced class of oxide materials, which are characterized by a large number of elements (i.e. five or more) sharing one lattice site which crystallize in a single phase structure. One complex…

The sesquioxide, Ce$_{2}$O$_{3}$, has been a material of intense interest in recent years due to reports of an anomalous giant magnetodielectric effect and emergent mixed crystal field-phonon (vibronic) excitations below a putative…

We investigate the effect of Mn substitution in Fe$_2$Ti$_{1-x}$Mn$_x$Sn on electronic structure and magnetic and electrical transport properties. The spin-polarized density of states calculations using density-functional theory (DFT)…

Materials Science · Physics 2025-08-20 Kulbhushan Mishra , Shishir Kumar Pandey , S. Chaudhuri , Rajeev Rawat , P. A. Bhobe

The discovery of intrinsic magnetic topological order in $\rm MnBi_2Te_4$ has invigorated the search for materials with coexisting magnetic and topological phases. These multi-order quantum materials are expected to exhibit new topological…

The high temperature ferromagnetism in Sr3YCo4O10+delta perovskite, whose origin has been the subject of a considerable debate, has been studied by neutron powder diffraction and synchrotron X-ray diffraction measurements. Oxygen vacancy…

We combine spin polarised density functional theory and thermodynamic mean field theory to describe the phase transitions of antiperovskite manganese nitrides. We find that the inclusion of the localized spin contribution to the entropy,…

Materials Science · Physics 2016-10-25 Marco Piazzi , Jan Zemen , Vittorio Basso

Nuclear magnetic resonance (NMR), neutron diffaction (ND), x-ray diffraction, magnetic susceptibility and specific heat measurements on the frustrated A-site spinel CoAl2O4 compound reveal a collinear antiferromagnetic ordering below Tn =…

Strongly Correlated Electrons · Physics 2016-11-26 B. Roy , Abhishek Pandey , Q. Zhang , T. W. Heitmann , D. Vaknin , D. C. Johnston , Y. Furukawa

A prominent character of two-dimensional magnetic systems is the enhanced spin fluctuations, which however reduce the ordering temperature. Here we report that a magnetic field of only one-thousandth of the Heisenberg superexchange…