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Hydrogen-terminated diamond is known for its p-type surface conductivity, which arises from a near-surface hole accumulation layer induced by adsorbed acceptor species. Here, we demonstrate that these surface acceptors also form optically…

Surface electronic properties of undoped hydrogen terminated diamond covered with adsorbates or in electrolyte solutions are summarized. The formation of a conductive layer at the surface of diamond is discussed based on Hall effect,…

Materials Science · Physics 2020-05-11 Christoph E. Nebel

Recent experiments on the silicon terminated $3\times 2$ SiC(100) surface indicated an unexpected metallic character upon hydrogen adsorption. This effect was attributed to the bonding of hydrogen to a row of Si atoms and to the…

Materials Science · Physics 2009-11-11 R. Di Felice , C. M. Bertoni , C. A. Pignedoli , A. Catellani

We have studied the electronic properties, in relation to their structural properties, of monolayers of 1-octadecene attached on a hydrogen-terminated (111) silicon surface. The molecules are attached using the free-radical reaction between…

Materials Science · Physics 2009-11-10 Corinne Miramond , Dominique Vuillaume

We have performed a scanning tunneling microscopy and spectroscopy study of potassium-doped C60 monolayers (KxC60) on Ag(001) in the regime of x ~ 1. Low temperature annealing (640 K) leads to the formation of two well-ordered KxC60 phases…

Materials Science · Physics 2009-08-07 M. Grobis , R. Yamachika , A. Wachowiak , Xinghua Lu , M. F. Crommie

A boron-oxide termination of the diamond (100) surface has been formed by depositing molecular boron oxide $\rm{B_2O_3}$ onto the hydrogen-terminated (100) diamond surface under ultrahigh vacuum conditions and annealing to $\rm{950^{\circ}…

Materials Science · Physics 2024-03-05 Alex K. Schenk , Rebecca Griffin , Anton Tadich , Daniel Roberts , Alastair Stacey

Surface adsorption of C$_{60}$ affects its chemical and electronic properties. Numerous studies have reported observation of bright and dark fullerenes on metal surfaces that suggest extensive surface reconstruction, however, the…

Materials Science · Physics 2021-12-01 Leonardo Forcieri , Simon Taylor , Philip Moriarty , Samuel P Jarvis

Density functional theory calculations are used to systematically investigate the structural and electronic properties of MX$_2$ transition metal dichalcogenide monolayers with M = Cr, Mo, W and X = S, Se, Te that are doped with single (V,…

Materials Science · Physics 2024-01-03 Yuqiang Gao , Paul J. Kelly

The adsorption of hydrogen on the polar Zn-ended ZnO(0001) surface has been investigated by density functional {\it ab-initio} calculations. An on top H(1x1) ordered overlayer with genuine H-Zn chemical bonds is shown to be energetically…

Materials Science · Physics 2015-05-13 N. Sanchez , S. Gallego , J. Cerdá , M. C. Muñoz

We have investigated Rb adsorption on the Si(100) surface for 0.5 and 1 monolayer coverages using the total energy method with norm-conserving pseudopotentials. For 2$\times$1 reconstruction at 1 ML coverage symmetrized dimers are found to…

Strongly Correlated Electrons · Physics 2007-05-23 E. Mete , R. Shaltaf , Ş. Ellialtıoğlu

Boron implantation with in-situ dynamic annealing is used to produce highly conductive sub-surface layers in type IIa (100) diamond plates for the search of a superconducting phase transition. Here we demonstrate that high-fluence MeV…

Materials Science · Physics 2016-06-21 L. H. Willems van Beveren , R. Liu , H. Bowers , K. Ganesan , B. C. Johnson , J. C. McCallum , S. Prawer

We investigate the atomic hydrogen adsorption on Mg(0001) by using density-functional theory within the generalized gradient approximation and a supercell approach. The coverage dependence of the adsorption structures and energetics is…

Materials Science · Physics 2009-04-29 Yanfang Li , Ping Zhang , Bo Sun , Yu Yang , Yinghui Wei

We derive a model for the highest occupied molecular orbital band of a C60 crystal which includes on-site electron-electron interactions. The form of the interactions are based on the icosahedral symmetry of the C60 molecule together with a…

Superconductivity · Physics 2009-11-07 M. Granath , S. Ostlund

We calculate the difference of the ionization energies of a core-electron of a surface alloy, i.e., a B-atom in a A_(1-x) B_x overlayer on a fcc-B(001)-substrate, and a core-electron of the clean fcc-B(001) surface using…

Materials Science · Physics 2009-10-30 M. V. Ganduglia-Pirovano , J. Kudrnovsky , M. Scheffler

Hydrogenated diamond has been regarded as a promising material in electronic device applications, especially in field-effect transistors (FETs). However, the quality of diamond hydrogenation has not yet been established, nor has the…

We present an ab initio study of the structural and electronic properties of styrene molecules adsorbed on the dimerized Si(100) surface at different coverages, ranging from the single-molecule to the full monolayer. The adsorption…

Soft Condensed Matter · Physics 2009-11-11 A. Calzolari , A. Ruini , M. J. Caldas , E. Molinari

We have carried out first-principles based DFT calculation on electronic properties of silicene monolayer on various (111) semi-conducting surfaces. We find that the relative stability and other properties of the silicene overlayer depends…

Materials Science · Physics 2013-10-07 Amrita Bhattacharya , Saswata Bhattacharya , G. P. Das

Isolated and full monolayer adsorption of various carboranethiol (C$_2$B$_{10}$H$_{12}$S) isomers on gold (111) surface have been investigated using both the standard and van der Waals density functional theoretical calculations. The effect…

Materials Science · Physics 2020-05-20 Ersen Mete , Ayşen Yılmaz , M. Fatih Danışman

High-density structures of sub-surface phosphorus dopants in silicon continue to garner interest as a silicon-based quantum computer platform, however, a much-needed confirmation of their dopant arrangement has been lacking. In this work,…

Ultra-wide bandgap and the absence of shallow dopants are the major challenges in realizing diamond based electronics. However, the surface functionalization offers an excellent alternative to tune electronic structure of diamonds. Herein,…

Materials Science · Physics 2022-08-05 N. Mohasin Sulthana , K. Ganesan , P. K. Ajikumar , S. Dhara
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