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Consider an ensemble of pure quantum states |\psi_j>, j=1,...,n taken with prior probabilities p_j respectively. We show that it is possible to increase all of the pairwise overlaps |<\psi_i|\psi_j>| i.e. make each constituent pair of the…

Quantum Physics · Physics 2009-10-31 Richard Jozsa , Juergen Schlienz

In this paper, we review the concept of entropy in connection with the description of quantum unstable systems. We revise the conventional definition of entropy due to Boltzmann and extend it so as to include the presence of complex-energy…

Quantum Physics · Physics 2018-05-09 Osvaldo Civitarese , Manuel Gadella

A complete mathematical theory of nonequilibrium thermodynamics of stochastic systems in terms of master equations is presented. As generalizations of isothermal entropy and free energy, two functions of states play central roles: the Gibbs…

Statistical Mechanics · Physics 2010-05-28 Hao Ge , Hong Qian

This paper generalizes the entropy maximization problem leading to the Boltzmann-Gibbs distribution through the nonadditive entropy $S_{q,s}(p)=k_{s}\sum^{W}_{i\geq1}p_{i}\ln_{q}1/p_{i}$, $q\in(0,1)$, which is a rescaled version of $S_{q}$…

Mathematical Physics · Physics 2025-12-02 Leandro Lyra Braga Dognini

The entropy shows an unavoidable tendency of disorder in thermostatistics according to the second thermodynamics law. This provides a minimization entropy principle for quantum thermostatistics with the von Neumann entropy and nonextensive…

Quantum Physics · Physics 2021-04-09 M. X. Luo , X. Wang

The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…

Chemical Physics · Physics 2009-12-03 Chi-Ho Cheng

Counting ad infinitum is the holographic observable to a statistical dynamics with finite states under independent repeated sampling. Entropy provides the infinitesimal probability for an observed frequency $\hat{\boldsymbol{\nu}}$ w.r.t. a…

Statistical Mechanics · Physics 2025-01-14 Hong Qian

Systems driven away from thermal equilibrium constantly deliver entropy to their environment. Determining this entropy production requires detailed information about the system's internal states and dynamics. However, in most practical…

Statistical Mechanics · Physics 2017-10-03 Gili Bisker , Matteo Polettini , Todd R. Gingrich , Jordan M. Horowitz

Large entropy fluctuations in a nonequilibrium steady state of classical mechanics were studied in extensive numerical experiments on a simple 2-freedom model with the so-called Gauss time-reversible thermostat. The local fluctuations (on a…

Chaotic Dynamics · Physics 2009-10-31 Boris Chirikov

In this paper we discuss about the validity of the Shannon entropy functional in connection with the correct Gibbs-Hertz probability distribution function. We show that there is no contradiction in using the Shannon-Gibbs functional and…

Classical Physics · Physics 2015-03-11 Alessio Gagliardi , Alessandro Pecchia

Different quantities that go by the name of entropy are used in variational principles to infer probability distributions from limited data. Shore and Johnson showed that maximizing the Boltzmann- Gibbs form of the entropy ensures that…

Statistical Mechanics · Physics 2015-06-18 Steve Pressé , Kingshuk Ghosh , Julian Lee , Ken A. Dill

In this paper, we analyze the relationship between entropy and information in the context of the mixing process of two identical ideal gases. We will argue that entropy has a special information-based feature that is enfolded in the…

Quantum Physics · Physics 2015-06-26 Afshin Shafiee , Majid Karimi

We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…

Statistical Mechanics · Physics 2020-10-13 Jianzhong Wu

We numerically determine the entropy for heat-conducting states, which is connected to the so-called excess heat considered as a basic quantity for steady-state thermodynamics in nonequilibrium. We adopt an efficient method to estimate the…

Statistical Mechanics · Physics 2016-08-17 Yoshiyuki Chiba , Naoko Nakagawa

One of the few accepted dynamical foundations of non-additive "non-extensive") statistical mechanics is that the choice of the appropriate entropy functional describing a system with many degrees of freedom should reflect the rate of growth…

Statistical Mechanics · Physics 2017-09-22 Nikolaos Kalogeropoulos

The emerging field of stochastic thermodynamics extends classical ideas of entropy, heat and work to non-equilibrium systems. One notable finding is that the second law of thermodynamics typically only holds after taking appropriate…

Statistical Mechanics · Physics 2024-02-27 Paul C Bressloff

Thermodynamics allows the application of Statistical Mechanics to finite and even small systems. As surface effects cannot be scaled away, one has to be careful with the standard arguments of splitting a system into two or bringing two…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

This short book is an elementary course on entropy, leading up to a calculation of the entropy of hydrogen gas at standard temperature and pressure. Topics covered include information, Shannon entropy and Gibbs entropy, the principle of…

Statistical Mechanics · Physics 2025-11-18 John C. Baez

If the von Neumann equation is modified by time dependent statistical weights, the time rate of entropy, the entropy exchange and production of a Schottky system are derived whose Hamiltonian does not contain the interaction with the…

Quantum Physics · Physics 2019-01-30 Wolfgang Muschik

For a certain class of isolated quantum systems, we report the existence of irreversible processes in which the energy is not dissipated. After a closed cycle in which the initial energy distribution is fully recovered, the expectation…

Quantum Physics · Physics 2015-09-30 Ricardo Puebla , Armando Relaño