Internal Energy, Fundamental Thermodynamic Relation, and Gibbs' Ensemble Theory as Laws of Statistical Counting
Statistical Mechanics
2025-01-14 v1 Probability
Abstract
Counting ad infinitum is the holographic observable to a statistical dynamics with finite states under independent repeated sampling. Entropy provides the infinitesimal probability for an observed frequency w.r.t. a probability prior . Following Callen's postulate and through Legendre-Fenchel transform, without help from mechanics, we show an internal energy emerges; it provides a linear representation of real-valued observables with full or partial information. Gibbs' fundamental thermodynamic relation and theory of ensembles follow mathematically. is to what is to in Fourier analysis.
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Cite
@article{arxiv.2209.14337,
title = {Internal Energy, Fundamental Thermodynamic Relation, and Gibbs' Ensemble Theory as Laws of Statistical Counting},
author = {Hong Qian},
journal= {arXiv preprint arXiv:2209.14337},
year = {2025}
}
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5 pages