English

Internal Energy, Fundamental Thermodynamic Relation, and Gibbs' Ensemble Theory as Laws of Statistical Counting

Statistical Mechanics 2025-01-14 v1 Probability

Abstract

Counting ad infinitum is the holographic observable to a statistical dynamics with finite states under independent repeated sampling. Entropy provides the infinitesimal probability for an observed frequency ν^\hat{\boldsymbol{\nu}} w.r.t. a probability prior p{\bf p}. Following Callen's postulate and through Legendre-Fenchel transform, without help from mechanics, we show an internal energy μ\boldsymbol{\mu} emerges; it provides a linear representation of real-valued observables with full or partial information. Gibbs' fundamental thermodynamic relation and theory of ensembles follow mathematically. μ\boldsymbol{\mu} is to ν^\hat{\boldsymbol{\nu}} what ω\omega is to tt in Fourier analysis.

Keywords

Cite

@article{arxiv.2209.14337,
  title  = {Internal Energy, Fundamental Thermodynamic Relation, and Gibbs' Ensemble Theory as Laws of Statistical Counting},
  author = {Hong Qian},
  journal= {arXiv preprint arXiv:2209.14337},
  year   = {2025}
}

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5 pages