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Lithium phosphorus oxynitride (LiPON) is a well-known amorphous thin film solid electrolyte that has been extensively studied in the last three decades. Despite the promises to pair with Li metal anode and various cathode materials, the…

The ionic conduction properties of the technologically important two-dimensional (2D) layered battery material Na2Mn3O7, with exceptional small-voltage hysteresis between charge and discharge curves, have been investigated as a function of…

Materials Science · Physics 2021-06-24 Bikash Saha , A. K. Bera , S. M. Yusuf

Disordered rocksalt (DRX) Li3V2O5 is a promising candidate for anode in rechargeable lithium-ion batteries because of its ideal low voltage, high rate capability, and superior cycling stability. Herein, we presents a comprehensive study of…

Materials Science · Physics 2022-08-31 Xingyu Guo , Chi Chen , Shyue Ping Ong

Li+ transport within a solid electrolyte interphase (SEI) in lithium ion batteries has challenged molecular dynamics (MD) studies due to limited compositional control of that layer. In recent years, experiments and ab initio simulations…

Chemical Physics · Physics 2018-01-29 Ajay Muralidharan , Mangesh I. Chaudhari , Lawrence R. Pratt , Susan B. Rempe

Designing optimal formulations is a major challenge in developing electrolytes for the next generation of rechargeable batteries due to the vast combinatorial design space and complex interplay between multiple constituents. Machine…

High temperature superconductivity in cuprates is realized by doping the Mott insulator with charge carriers. A central issue is how such an insulating state can evolve into a conducting or superconducting state when charge carriers are…

The predissociation dynamics of lithium iodide (LiI) in the first excited A-state is investigated for molecules in the gas phase and embedded in helium nanodroplets, using femtosecond pump-probe photoionization spectroscopy. In the gas…

Atomic and Molecular Clusters · Physics 2015-03-03 H. Schmidt , J. von Vangerow , F. Stienkemeier , A. S. Bogomolov , A. V. Baklanov , D. M. Reich , W. Skomorowski , C. P. Koch , M. Mudrich

We have carried out extensive isokinetic {\it ab initio} molecular dynamic simulations to investigate the finite temperature properties of the impurity doped cluster Li$_6$Sn along with the host cluster Li$_7$. The data obtained from about…

Condensed Matter · Physics 2009-11-10 Kavita Joshi , D. G. Kanhere

High-concentration aqueous electrolytes have shown promise as candidates for a safer, lower-cost battery system. Ionic conductivity is a key property required in high performing electrolytes; the Advanced Electrolyte Model (AEM) has…

Recent experimental studies confirmed that a long searched conventional superconducting phase in graphene can be induced via lithium deposition. However, the canonical character of the lithium-decorated graphene (LiC$_{6}$) superconductor…

Superconductivity · Physics 2019-06-26 Dominik Szczȩśniak , Radosław Szczȩśniak

Solid-state electrolytes for Li-ion batteries are attracting growing interest as they allow building safer batteries, also using lithium metal anodes. Here we studied a compound in the lithium superionic conductor (LISICON) family, i.e.…

Materials Science · Physics 2020-10-07 E. Gilardi , G. Materzanini , L. Kahle , M. Doebeli , S. Lacey , X. Cheng , N. Marzari , D. Pergolesi , A. Hintennach , T. Lippert

Iron-based superconductors have grown to be a new continent of high Tc superconductors comparable to cuprates. The optimal critical temperature (Tc) of 56 K in electron-doped 1111-type iron oxypnictides attracts considerable attention of…

Superconductivity · Physics 2020-02-27 Soshi Iimura , Hideo Hosono

Despite significant potential as energy storage materials for electric vehicles due to their combination of high energy density per unit cost and reduced environmental and ethical concerns, Co-free lithium ion batteries based off layered Mn…

The pursuit of room-temperature ambient-pressure superconductivity in novel materials has sparked interest, with recent reports suggesting such properties in Cu-substituted lead apatite, known as LK-99. However, these claims lack…

Materials Science · Physics 2023-09-01 Songge Yang , Guangchen Liu , Yu Zhong

A porous electrode resulting from unregulated Li growth is the major cause of the low Coulombic efficiency and potential safety hazards of rechargeable Li metal batteries. Strategies aiming to achieve large granular Li deposits have been…

Flat monolayers of silver II fluoride, which could be obtained by epitaxial deposition on an appropriate substrate, have been recently predicted to exhibit very strong antiferromagnetic superexchange and to have large potential for ambient…

In this study, we determined the effect of doping with the noble metal Ag on Ir$_2$Te$_4$ superconductors. Based on the resistivity, magnetization, and heat capacity, we explored the changes in the superconductivity and charge density wave…

Arsenic doping in silicides has been much less studied compared with phosphorus. In this study, superconductivity is successfully induced by As doping in Mo$_5$Si$_3$. The superconducting transition temperature ($T_c$) reaches 7.7 K, which…

Superconductivity · Physics 2022-10-03 Bin-Bin Ruan , Jun-Nan Sun , Meng-Hu Zhou , Qing-Song Yang , Ya-Dong Gu , Gen-Fu Chen , Lei Shan , Zhi-An Ren

V$_{2}$O$_{5}$ in its $\omega$ phase (Li$_{3}$V$_{2}$O$_{5}$) with excess lithium is a potential alternative to the graphite anode for lithium-ion batteries at low temperature and fast charging conditions due to its safer voltage (0.6 V vs…

Chemical composition provides a powerful route to tune the electronic ground state of iron-based superconductors and other quantum materials, yet access to highly doped phases remains limited. Here we demonstrate that high-pressure thermal…