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The high-pressure and high-temperature thermodynamic properties of iridium are studied using density functional theory in combination with the quasi-harmonic approximation, where both the contributions to the free energy of phonons and of…

Materials Science · Physics 2024-01-24 Balaram Thakur , Xuejun Gong , Andrea Dal Corso

The recent experimental discoveries about excitation energy transfer (EET) in light harvesting antenna (LHA) attract a lot of interest. As an open non-equilibrium quantum system, the EET demands more rigorous theoretical framework to…

Statistical Mechanics · Physics 2015-06-15 Xin Chen , Jianshu Cao , Robert Silbey

As a fundamental physical quantity of thermal phonons, temporal coherence participates in a broad range of thermal and phononic processes, while a clear methodology for the measurement of phonon coherence is still lacking. In this Lettter,…

Applied Physics · Physics 2023-05-03 Zhongwei Zhang , Yangyu Guo , Marc Bescond , Masahiro Nomura , Sebastian Volz , Jie Chen

The calculation of material phonon thermal conductivity from density functional theory calculations requires computationally expensive evaluation of anharmonic interatomic force constants and has remained a computational bottleneck in the…

Materials Science · Physics 2024-09-04 Yagyank Srivastava , Ankit Jain

We have implemented a generic method, based on the 2n+1 theorem within density functional perturbation theory, to calculate the anharmonic scattering coefficients among three phonons with arbitrary wavevectors. The method is used to study…

Materials Science · Physics 2014-06-24 Lorenzo Paulatto , Francesco Mauri , Michele Lazzeri

The low-temperature thermal conductivity in polycrystalline graphene is theoretically studied. The contributions from three branches of acoustic phonons are calculated by taking into account scattering on sample borders, point defects and…

Materials Science · Physics 2015-06-05 D. V. Kolesnikov , V. A. Osipov

Phonon size effects induce ballistic transport in nanomaterials, challenging Fourier's law. Nondiffusive heat transport is captured by the Peierls-Boltzmann transport equation (BTE), commonly solved under the relaxation time approximation…

Mesoscale and Nanoscale Physics · Physics 2020-03-10 Giuseppe Romano

Simulations (e.g. Zhou et al., Phys. Rev. B 79, 115201 (2009)) show nonlocal effects of the ballistic/diffusive crossover. The local temperature has nonlinear spatial variation not contained in the local Fourier law…

Materials Science · Physics 2018-05-02 Philip B. Allen

We report first-principles phonon frequencies and anharmonic thermodynamic properties of h.c.p. Re and Tc calculated within the quasi-harmonic approximation, including Gr\"uneisen parameters, temperature-dependent lattice parameters,…

Materials Science · Physics 2017-07-06 Mauro Palumbo , Andrea Dal Corso

Steady-state thermal transport in nanostructures with dimensions comparable to the phonon mean-free-path is examined. Both the case of contacts at different temperatures with no internal heat generation and contacts at the same temperature…

Mesoscale and Nanoscale Physics · Physics 2017-03-08 Jan Kaiser , Tianli Feng , Jesse Maassen , Xufeng Wang , Xiulin Ruan , Mark Lundstrom

The Self-Consistent Harmonic Approximation (SCHA) describes atoms in solids, including quantum fluctuations and anharmonic effects, in a non-perturbative way. It computes ionic free energy variationally, constraining the atomic…

Materials Science · Physics 2024-10-21 Antonio Siciliano , Lorenzo Monacelli , Francesco Mauri

The thermal and lattice dynamical properties of seven silicon clathrate framework structures are investigated with ab initio density functional methods (frameworks I, II, IV, V, VII, VIII, and H). The negative thermal expansion (NTE)…

Materials Science · Physics 2014-01-28 Ville J. Härkönen , Antti J. Karttunen

We have used ab-initio density functional theory technique to understand the phase transitions and structural changes in various high temperature/pressure phases of LiAlO2. The electronic band structure as well as phonon spectra are…

Materials Science · Physics 2018-06-05 Baltej Singh , M. K. Gupta , R. Mittal , S. L. Chaplot

In this paper, we investigate the transport coefficients of a strongly coupled plasma in the context of holographic QCD models based on Einstein-dilaton gravity that are compatible with linear confinement at zero temperature. At finite…

High Energy Physics - Theory · Physics 2025-07-21 Nairy A. Villarreal , Luis A. H. Mamani , Alfonso Ballon-Bayona , Alex S. Miranda , Vilson T. Zanchin

We study resonance for the Helmholz equation with a finite frequency in a plasmonic material of negative dielectric constant in two and three dimensions. We show that the quasi-static approximation is valid for diametrically small…

Analysis of PDEs · Mathematics 2015-06-12 Kazunori Ando , Hyeonbae Kang , Hongyu Liu

Ab initio based accurate simulation of phonon-assisted optical spectra of semiconductors at finite temperatures remains a formidable challenge, as it requires large supercells for phonon sampling and computationally expensive high-accuracy…

Materials Science · Physics 2025-05-07 Qiangqiang Gu , Shishir Kumar Pandey , Zhanghao Zhouyin

A definition of the Gr\"uneisen parameters for anisotropic materials is derived based on the response of phonon frequencies to uniaxial stress perturbations. This Gr\"uneisen model relates the thermal expansion in a given direction…

Materials Science · Physics 2019-02-25 Carl P. Romao

Beta eucryptite (LiAlSiO4) shows one-dimensional super-ionic conductivity as well as anisotropic thermal expansion behavior. We have performed inelastic neutron scattering measurements in beta eucryptite over 300 to 900 K and calculated the…

We calculate the rate of heating through phonon excitation implied by the noise postulated in mass-proportional-coupled collapse models, for a general noise power spectrum. For white noise with reduction rate $\lambda$, the phonon heating…

Quantum Physics · Physics 2018-05-23 Stephen L. Adler

We study the structural effects produced by the quantization of vibrational degrees of freedom in periodic crystals at zero temperature. To this end we introduce a methodology based on mapping a suitable subspace of the vibrational manifold…

Materials Science · Physics 2009-11-13 I. Scivetti , N. I. Gidopoulos , J. Kohanoff