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Statistical thermodynamics delivers the probability distribution of the equilibrium state of matter through the constrained maximization of a special functional, entropy. Its elegance and enormous success have led to numerous attempts to…

Statistical Mechanics · Physics 2023-06-22 Themis Matsoukas

The fact that a temperature and an entropy may be associated with horizons in semi-classical general relativity has led many to suspect that spacetime has microstructure. If this is indeed the case then its description via Riemannian…

Statistical Mechanics · Physics 2011-10-28 Cenalo Vaz

In this study, we present a reformulation of classical equilibrium thermodynamics by replacing the obscure and ambiguous concept of entropy with the clear and intuitive concept of information stored in a thermodynamic system. Specifically,…

Statistical Mechanics · Physics 2025-01-15 Faical Barzi , Kaoutar Fethi

This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

In this paper, the foundations of classical phenomenological thermodynamics are being thoroughly revisited. A new rigorous basis for thermodynamics is laid out in the main text and presented in full detail in the appendix. All relevant…

Mathematical Physics · Physics 2020-02-24 Philipp Kammerlander , Renato Renner

I argue here that both the first and second laws of thermodynamics, generally understood to be quintessentially physical in nature, can be equally well described as being about certain types of information without the need to invoke…

Data Analysis, Statistics and Probability · Physics 2013-10-02 V. J. Vieland

We numerically determine the entropy for heat-conducting states, which is connected to the so-called excess heat considered as a basic quantity for steady-state thermodynamics in nonequilibrium. We adopt an efficient method to estimate the…

Statistical Mechanics · Physics 2016-08-17 Yoshiyuki Chiba , Naoko Nakagawa

Counting ad infinitum is the holographic observable to a statistical dynamics with finite states under independent repeated sampling. Entropy provides the infinitesimal probability for an observed frequency $\hat{\boldsymbol{\nu}}$ w.r.t. a…

Statistical Mechanics · Physics 2025-01-14 Hong Qian

We present a novel derivation of the constraints required to obtain the underlying principles of statistical mechanics using a maximum entropy framework. We derive the mean value constraints by use of the central limit theorem and the…

Statistical Mechanics · Physics 2017-03-30 Diego Granziol , Stephen Roberts

We study the informational underpinnings of thermodynamics and statistical mechanics, using an abstract framework, general probabilistic theories, capable of describing arbitrary physical theories. This allows one to abstract the…

Quantum Physics · Physics 2019-01-25 Carlo Maria Scandolo

In statistical mechanics the zeroth law of thermodynamics is taken as a postulate which, as its name indicates, logically precedes the first and second laws. Treating it as a postulate has consequences for how temperature is introduced into…

Statistical Mechanics · Physics 2025-02-11 Kim Sharp

We describe recent progress towards deriving the Fundamental Laws of thermodynamics (the 0th, 1st and 2nd Law) from nonequilibrium quantum statistical mechanics in simple, yet physically relevant models. Along the way, we clarify some basic…

Mathematical Physics · Physics 2007-05-23 Walid K. Abou Salem , Juerg Froehlich

This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized…

Quantum Physics · Physics 2015-08-14 Marius Krumm

We propose an extension of the principle of virtual work of mechanics to random dynamics of mechanical systems. The total virtual work of the interacting forces and inertial forces on every particle of the system is calculated by…

Statistical Mechanics · Physics 2008-01-28 Qiuping A. Wang

The deep problems caused from the limitations of theoretical framework itself can only be clarified by extending and reconstructing of the theoretical framework, we extend classical theoretical framework of thermodynamics, break through the…

Chemical Physics · Physics 2025-01-17 Tang Suye

Thermodynamics is usually developed starting from entropy and the maximum entropy principle. We investigate here to what extent one can replace entropy with relative entropy which has several advantages, for example in the context of local…

Statistical Mechanics · Physics 2020-11-17 Stefan Floerchinger , Tobias Haas

Assuming a classical statistical system of point particles the fundamental equations of continuum thermomechanics (continuity equation, equation of motion, and energy equation) shall be derived exactly. The macroscopic state functions…

Statistical Mechanics · Physics 2010-06-03 Walter Noll

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

Quantum Physics · Physics 2026-03-26 Gian Paolo Beretta

We show how the macroscopic state variables pressure, entropy and temperature of equilibrium thermodynamics can be consistently derived from the (quantum) chaotic spectral structure of one or two particles in two-dimensional domains. This…

The microscopic foundation of the generalized equilibrium statistical mechanics based on the Tsallis entropy is given by using the Gibbs idea of statistical ensembles of the classical and quantum mechanics. The equilibrium distribution…

Statistical Mechanics · Physics 2007-05-23 A. S. Parvan