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We describe a robust method for determining Pipek-Mezey (PM) Wannier functions (WF), recently introduced by J\'onsson et al. (J. Chem. Theor. Chem. 2017, 13, 460), which provide some formal advantages over the more common Boys (also known…

Chemical Physics · Physics 2024-07-30 Marjory C. Clement , Xiao Wang , Edward F. Valeev

Maximally-localized Wannier functions are quantum wavefunctions resembling atomic orbitals that are used to describe electrons in condensed matter. Since their introduction in 1997, these functions have become ubiquitous in ab initio…

Computational Physics · Physics 2026-04-09 Sabyasachi Tiwari , Bruno Cucco , Viet-Anh Ha , Feliciano Giustino

A procedure to construct symmetry-adapted Wannier functions in the framework of the maximally-localized Wannier function approach[Marzari and Vanderbilt, Phys. Rev. B \textbf{56}, 12847 (1997); Souza, Marzari, and Vanderbilt, \textit{ibid.}…

Strongly Correlated Electrons · Physics 2015-06-16 R. Sakuma

We present a formal expression for Wannier functions of composite bands of 1-D Bloch electrons in terms of parallel-transported Bloch functions and their non-Abelian geometric phases. Spatial decay properties of these Wannier functions are…

Materials Science · Physics 2009-11-10 Joydeep Bhattacharjee , Umesh V Waghmare

We have constructed maximally-localized Wannier functions for prototype structures of solid molecular hydrogen under pressure, starting from LDA and tight-binding Bloch wave functions. Each occupied Wannier function can be associated with…

Materials Science · Physics 2009-10-31 Ivo Souza , Richard M. Martin , Nicola Marzari , Xinyuan Zhao , David Vanderbilt

We present a semi-automated method for obtaining an initial estimate of Wannier functions, designed to facilitate the construction of Wannier functions for describing low-energy effective models of solids, particularly those relevant to…

Strongly Correlated Electrons · Physics 2025-12-24 Tatsuki Oikawa , Kota Ido , Takahiro Misawa , Takashi Koretsune , Kazuyoshi Yoshimi

Maximally localized Wannier functions (MLWFs) are conventionally constructed by iteratively minimizing a spread functional over a high-dimensional gauge landscape. In this work, we present a non-variational constructive algorithm that…

Materials Science · Physics 2026-05-15 Yuji Hamai , Katsunori Wakabayashi

We report a $k$-point extension of the second-order co-iterative augmented Hessian (CIAH) algorithm, termed $k$-CIAH, for Pipek-Mezey (PM) localization of Wannier functions (WFs). By exploiting an efficient evaluation of the Hessian-vector…

Chemical Physics · Physics 2026-05-14 Gengzhi Yang , Hong-Zhou Ye

We review the formalisms of the self-consistent GW approximation to many-body perturbation theory and of the generation of optimally-localized Wannier functions from groups of energy bands. We show that the quasiparticle Bloch wave…

Materials Science · Physics 2009-11-13 D. R. Hamann , David Vanderbilt

We consider a real periodic Schr\"odinger operator and a physically relevant family of $m \geq 1$ Bloch bands, separated by a gap from the rest of the spectrum, and we investigate the localization properties of the corresponding composite…

Mathematical Physics · Physics 2016-01-13 Domenico Fiorenza , Domenico Monaco , Gianluca Panati

Orbital magnetic susceptibility involves rich physics such as interband effects despite of its conceptual simplicity. In order to appreciate the rich physics related to the orbital magnetic susceptibility, it is essential to derive a…

Mesoscale and Nanoscale Physics · Physics 2021-12-08 Toshikaze Kariyado , Hiroyasu Matsuura , Masao Ogata

Wannier functions provide a localized representation of spectral subspaces of periodic Hamiltonians, and play an important role for interpreting and accelerating Hartree-Fock and Kohn-Sham density functional theory calculations in quantum…

Computational Physics · Physics 2018-01-29 Anil Damle , Antoine Levitt , Lin Lin

Maximally localized Wannier functions are localized orthogonal functions that can accurately represent given Bloch eigenstates of a periodic system at a low computational cost, thanks to the small size of each orbital. Tight-binding models…

Materials Science · Physics 2019-03-15 Jae-Mo Lihm , Cheol-Hwan Park

Time-dependent Wannier functions were initially proposed as a means for calculating the polarization current in crystals driven by external fields. In this work, we present a simple gauge where Wannier states are defined based on the…

Materials Science · Physics 2024-10-29 Cristian M. Le , Hannes Hübener , Ofer Neufeld , Angel Rubio

A recently proposed approach for performing electronic-structure calculations on crystalline insulators in terms of localized orthogonal orbitals is applied to the oxides of lithium and sodium, Li2O and Na2O. Cohesive energies, lattice…

Condensed Matter · Physics 2009-10-31 Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

Construction of maximally localized Wannier functions (MLWFs) has been implemented within the linear combination of pseudo-atomic orbital (LCPAO) method. Detailed analysis using MLWFs is applied to three closely related materials, single…

Materials Science · Physics 2013-05-29 Hongming Weng , Taisuke Ozaki , Kiyoyuki Terakura

An ab initio Hartree-Fock approach aimed at directly obtaining the localized orthogonal orbitals (Wannier functions) of a crystalline insulator is described in detail. The method is used to perform all-electron calculations on the ground…

Condensed Matter · Physics 2009-10-30 Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

Maximally localized Wannier functions are widely used in electronic structure theory for analyses of bonding, electric polarization, orbital magnetization, and for interpolation. The state of the art method for their construction is based…

Materials Science · Physics 2015-12-02 Jamal I. Mustafa , Sinisa Coh , Marvin L. Cohen , Steven G. Louie

The paper presents the group theory of best localized and symmetry-adapted Wannier functions in a crystal of any given space group G or magnetic group M. Provided that the calculated band structure of the considered material is given and…

Strongly Correlated Electrons · Physics 2015-05-22 Ekkehard Krüger , Horst P. Strunk

In this work, we use Wannier functions to analyze topological phase transitions in one dimensional photonic crystals. We first review the construction of exponentially localized Wannier functions in one dimension, and show how to…

Optics · Physics 2022-06-07 Vaibhav Gupta , Barry Bradlyn