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In the pursuit of developing routes to enhance magnetic Kitaev interactions in {\alpha}-RuCl3, as well as probing doping effects, we investigate the electronic properties of {\alpha}-RuCl3 in proximity to graphene. We study…

Strongly Correlated Electrons · Physics 2019-12-11 Sananda Biswas , Ying Li , Stephen M. Winter , Johannes Knolle , Roser Valenti

We investigate the electronic properties of a graphene and $\alpha$-ruthenium trichloride (hereafter RuCl$_3$) heterostructure, using a combination of experimental and theoretical techniques. RuCl$_3$ is a Mott insulator and a Kitaev…

We report a study of electronic transport in van der Waals heterostructures composed of flakes of the antiferromagnetic Mott insulator a-RuCl_3 placed on top of monolayer graphene Hall bars. While the zero-field transport shows a strong…

Strongly Correlated Electrons · Physics 2019-12-11 Boyi Zhou , J. Balgley , P. Lampen-Kelley , J. -Q. Yan , D. G. Mandrus , E. A. Henriksen

Work function-mediated charge transfer in graphene/$\alpha$-RuCl$_3$ heterostructures has been proposed as a strategy for generating highly-doped 2D interfaces. In this geometry, graphene should become sufficiently doped to host surface and…

Single layer $\alpha$-ruthenium trichloride ($\rm\alpha-RuCl_3$) has been proposed as a potential quantum spin liquid. Graphene/$\rm RuCl_3$ heterobilayers have been extensively studied with a focus on the large interlayer electron transfer…

Strongly Correlated Electrons · Physics 2023-08-02 Jingtian Shi , A. H. MacDonald

Intercalation reactions modify the charge density in van der Waals (vdW) materials through coupled electronic-ionic charge accumulation, and are susceptible to modulation by interlayer hybridization in vdW heterostructures. Here, we…

Proximity effects induced in the 2D Dirac material graphene potentially open access to novel and intriguing physical phenomena. Thus far, the coupling between graphene and ferromagnetic insulators has been experimentally established.…

The layered Mott insulator ${\alpha}$-RuCl${_3}$ has been extensively studied as a potential Kitaev quantum spin liquid candidate. Here, by constructing heterostructures with graphite, we employed electron tunneling measurements on…

Strongly Correlated Electrons · Physics 2023-05-08 Xiaohu Zheng , Ke Jia , Junhai Ren , Chongli Yang , Xingjun Wu , Youguo Shi , Katsumi Tanigaki , Rui-Rui Du

Charge transfer is a common phenomenon in van der Waals heterostructures with proper work function mismatch, which enables electrostatic gating to control band alignment and interlayer charge distributions. This provides a tunable platform…

Strongly Correlated Electrons · Physics 2026-01-16 Yanran Shi , Min Li , Xin Lu , Jianpeng Liu

Ultrathin polymer-graphene heterostructures are promising materials for next generation optoelectronic and photovoltaic technologies, while the influence of the polymer's structural variation on interfacial charge transfer remains unclear.…

Materials Science · Physics 2025-12-25 Yosra Mater , Salih Demirci , V. Ongun Özçelik

We report a comparative neutron single crystal diffraction study of the structural and magnetic properties of layered halides CrCl$_3$ and $\alpha$-RuCl$_3$, which host a honeycomb arrangement of transition metal ions with distinct…

Strongly Correlated Electrons · Physics 2026-05-13 Zachary Morgan , Iris Ye , Jiasen Guo , Michael A McGuire , Jiaqiang Yan

We demonstrate electrically switchable, non-volatile dipoles in graphene/thin hBN/$\alpha$-RuCl$_3$ heterostructures, stabilized purely by interfacial charge transfer across an atomically thin dielectric barrier. This mechanism requires no…

Multilayer graphene with different stacking sequences has emerged as a powerful setting for correlated and topological phases. In parallel, progress in graphene heterostructures with magnetic or correlated materials-most notably the Kitaev…

Strongly Correlated Electrons · Physics 2026-02-03 Aleksandar Razpopov , Shirin Mozaffari , Takahiro Matsuoka , Matthew Cothrine , Nan Huang , Roser Valentí , David Mandrus

Creating heterostructures with graphene/graphite is a practical method for charge-doping $\alpha$-RuCl$_3$, but not sufficient to cause the insulator-to-metal transition. In this study, detailed scanning tunneling microscopy/spectroscopy…

Strongly Correlated Electrons · Physics 2024-01-05 Xiaohu Zheng , Ogasawara Takuma , Huaxue Zhou , Chongli Yang , Xin Han , Gang Wang , Junhai Ren , Youguo Shi , Katsumi Tanigaki , Rui-Rui Du

The extreme versatility of two-dimensional van der Waals (vdW) materials derives from their ability to exhibit new electronic properties when assembled in proximity with dissimilar crystals. For example, although graphene is inherently…

Transition metal thriclorides, with $4d$ or $5d$ electrons, are materials at the forefront of recent studies about the interplay of spin-orbit coupling and strong Coulomb interactions. Within our first-principles calculations (DFT+$U$+SOC)…

Materials Science · Physics 2022-10-19 P. H. Souza , D. P. de Andrade Deus , W. H. Brito , R. H. Miwa

MXene-based heterostructures have received considerable interest owing to their unique properties. Herein, we examine various heterostructures of a prototypical MXene and graphene using density functional theory. We find that the adhesion…

Mesoscale and Nanoscale Physics · Physics 2019-02-27 Rui Li , Weiwei Sun , Cheng Zhan , Paul R. C. Kent , De-en Jiang

The magnetism of Kitaev materials has been widely studied, but their charge properties and the coupling to other degrees of freedom are less known. Here we investigate the charge states of $\alpha$-RuCl$_3$, a promising Kitaev quantum spin…

Strongly Correlated Electrons · Physics 2024-08-27 Xiaohu Zheng , Zhengxin Liu , Cuiwei Zhang , Huaxue Zhou , Chongli Yang , Youguo Shi , Katsumi Tanigaki , Rui-Rui Du

We report the transport properties of ${\alpha}$-RuCl$_3$/bilayer graphene heterostructures, where carrier doping is induced by a work function difference, resulting in distinct electron and hole populations in ${\alpha}$-RuCl3 and bilayer…

Interface interactions in 2D vertically stacked heterostructures play an important role in optoe-lectronic applications, photodetectors based on graphene/InSe heterostructures had shown promising performance nowadays. However, nonlinear…

Optics · Physics 2023-05-12 Jialin Li , Lizhen Wang , Yuzhong Chen , Yujie Li , Haiming Zhu , Linjun Li , Limin Tong1
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