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In this review we first discuss extension of Bohr's 1913 molecular model and show that it corresponds to the large-D limit of a dimensional scaling (D-scaling) analysis, as developed by Herschbach and coworkers. In a separate but synergetic…

It can be argued that electron correlation, as a concept, deserves the same prominence in general chemistry as molecular orbital theory. We show how it acts as Nature's "chemical glue" at both the molecular and supramolecular levels.…

Chemical Physics · Physics 2022-01-10 Jan M. L. Martin

We examine the mode entanglement and correlation of two fermionic particles. We study the one- and two-mode entropy and a global characteristic, the one-body entanglement entropy. We consider not only angular momentum coupled states with…

Nuclear Theory · Physics 2021-02-03 A T Kruppa , J Kovács , P Salamon , Ö Legeza

We consider two quantum dots described by the Anderson-impurity model with one electron per dot. The goal of our work is to study the decay of a maximally entangled state between the two electrons localized in the dots. We prepare the…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 C. A. Büsser , I. de Vega , F. Heidrich-Meisner

Various topics concerning the entanglement of composite quantum systems are considered with particular emphasis concerning the strict relations of such a problem with the one of attributing objective properties to the constituents. Most of…

Quantum Physics · Physics 2007-05-23 Giancarlo Ghirardi , Luca Marinatto , Tullio Weber

Entanglement, which is an essential characteristic of quantum mechanics, is the key element in potential practical quantum information and quantum communication systems. However, there are many open and fundamental questions (relating to…

Quantum Physics · Physics 2015-05-18 G. W. Ford , Yang Gao , R. F. O'Connell

The Resonating Valence Bond theory of the chemical bond was introduced soon after the discovery of quantum mechanics and has contributed to explain the role of electron correlation within a particularly simple and intuitive approach where…

Computational Physics · Physics 2025-01-09 Sandro Sorella , Andrea Zen

An historical overview is given of the relevant steps that allowed the genesis of the quantum theory of the chemical bond, starting from the appearance of the new quantum mechanics and following later developments till approximately 1931.…

History and Philosophy of Physics · Physics 2013-09-19 S. Esposito , A. Naddeo

We witness for the first time the generation of bound entanglement of two photon qutrits, whose existence has been predicted by the Horodecki family in 1998. Detection of these heavily mixed entangled states, from which no pure entanglement…

Quantum Physics · Physics 2013-08-22 Beatrix C. Hiesmayr , Wolfgang Löffler

It is well known that entanglement under Lorentz boosts is highly dependent on the boost scenario in question. For single particle states, a spin-momentum product state can be transformed into an entangled state. However, entanglement is…

Quantum Physics · Physics 2021-09-23 Marcos Basso , Jonas Maziero

We compute the entanglement entropy of a wide class of exactly solvable models which may be characterized as describing matter coupled to gauge fields. Our principle result is an entanglement sum rule which states that entropy of the full…

Strongly Correlated Electrons · Physics 2013-09-11 Brian Swingle

Electron correlation effects are essential for an accurate ab initio description of molecules. A quantitative a priori knowledge of the single- or multi-reference nature of electronic structures as well as of the dominant contributions to…

Quantum Physics · Physics 2012-12-18 Katharina Boguslawski , Paweł Tecmer , Örs Legeza , Markus Reiher

We introduce a general framework for detecting genuine multipartite entanglement and non full-separability in multipartite quantum systems of arbitrary dimensions based on correlation tensors. Regarding genuine multipartite entanglement our…

Quantum Physics · Physics 2011-12-08 Julio I. de Vicente , Marcus Huber

The manifestation of entanglement within geometric phase is elucidated for spatially-structured bi-photons. Entanglement parameters are shown to influence holonomy in two distinct ways: through statistical superpositions of separable…

Quantum Physics · Physics 2024-10-21 Mark T. Lusk

The efficient experimental verification of entanglement requires an identification of the essential physical properties that distinguish entangled states from non-entangled states. Since the most characteristic feature of entanglement is…

Quantum Physics · Physics 2007-05-23 Holger F. Hofmann , Shigeki Takeuchi

In [arXiv:2207.03377] the first closed formula of a faithful entanglement measure applicable to realistic electron systems has been derived. In the present work, we build on this key achievement with the ultimate goal of guiding the…

Quantum Physics · Physics 2023-12-12 Lexin Ding , Gesa Dünnweber , Christian Schilling

An exact solution of the problem of two-atom one- and two-mode Jaynes-Cummings model with intensity-dependent coupling is presented. Asymptotic solutions for system state vectors are obtained in the approximation of large initial coherent…

Quantum Physics · Physics 2014-04-04 E. K. Bashkirov

We present exact results for the dynamical structure function, i.e.~the density-density correlations for the 1/r^2 system of interacting particles at three special values of the coupling constant. The results are interpreted in terms of…

Condensed Matter · Physics 2016-08-31 E. R. Mucciolo , B. S. Shastry , B. D. Simons , B. L. Altshuler

The evolution of entanglement for two identical two-level atoms coupled to a resonant thermal field is studied for two different families of input states. Entanglement enhancement is predicted for a well defined region of the parameter…

Quantum Physics · Physics 2009-11-13 Kamil Bradler , Rocio Jauregui

We analyze the time evolution of quantum entanglement in a model consisting of two two-level atoms interacting with a two-mode electromagnetic field for a variety of initial states and interatomic separations. We study two specific atomic…

Quantum Physics · Physics 2015-03-19 K. Sinha , N. I. Cummings , B. L. Hu