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Coherence and correlations represent two related properties of a compound system. The system can be, for instance, the polarization of a photon, which forms part of a polarization-entangled two-photon state, or the spatial shape of a…

Quantum Physics · Physics 2015-12-01 Jiří Svozilík , Adam Vallés , Jan Peřina , Juan P. Torres

The independent atom ansatz of density functional theory yields an accurate analytical expression for dynamic correlation energy in the H$_{2}$ molecule: $E_{c} = 0.5(1 - \sqrt{2})(ab|ba)$ for the atom-additive self-consistent density $\rho…

Chemical Physics · Physics 2024-05-28 Alanna 'Lanie' Leung , Alexander V. Mironenko

We propose a new approach to the problem of defining the degree of entanglement between two particles in a pure state with Hilbert spaces of arbitrary finite dimensions. The central idea is that entanglement gives rise to correlations…

Quantum Physics · Physics 2007-05-23 Markus A. Cirone

We study the relation between quantum entanglement and electron correlation in quantum chemistry calculations. We prove that the Hartree-Fock (HF) wave function does not violate Bell's inequality, thus is not entangled while the…

Quantum Physics · Physics 2007-06-25 Hefeng Wang , Sabre Kais

Density matrix embedding theory (Phys. Rev. Lett. 109, 186404 (2012)) and density embedding theory ((Phys. Rev. B 89, 035140 (2014)) have recently been introduced for model lattice Hamiltonians and molecular systems. In the present work,…

Chemical Physics · Physics 2016-11-25 Ireneusz W. Bulik , Weibing Chen , Gustavo E. Scuseria

Two-dimensional Projected Entangled Pair States (PEPS) provide a unique framework giving access to detailed entanglement features of correlated (spin or electronic) systems. For a bi-partitioned quantum system, it has been argued that the…

Strongly Correlated Electrons · Physics 2015-06-22 Didier Poilblanc

A simple model coupling a one-dimensional beam particle to a one-dimensional harmonic oscillator is used to explore complementarity and entanglement. This model, well-known in the inelastic scattering literature, is presented under three…

Quantum Physics · Physics 2023-09-26 David Kordahl

We present a detailed investigation of the electronic structure and bonding characteristics of hydrogen-based molecular systems (\ch{H2+}, \ch{H2}, \ch{H2-}) using the Exact Diagonalization Ab Initio (EDABI) approach within the framework of…

Chemical Physics · Physics 2024-06-13 Maciej Hendzel , Józef Spałek

We present a significantly improved scheme of entanglement detection inspired by local uncertainty relations for a system consisting of two qubits. Developing the underlying idea of local uncertainty relations, namely correlations, we…

Quantum Physics · Physics 2016-08-16 Christian Kothe , Gunnar Björk

A weakly biased normal-metal-superconductor junction is considered as a potential device injecting entangled pairs of quasi-particles into a normal-metal lead. The two-particle states arise from Cooper pairs decaying into the normal lead…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Gordey B. Lesovik , Thierry Martin , Gianni Blatter

Using gauge transformations on electron bond operators, we derive exact duality relations between various order parameters for correlated electron systems. Applying these transformations, we find two duality relations in the generalized…

Strongly Correlated Electrons · Physics 2007-05-23 Tsutomu Momoi , Toshiya Hikihara

Bohr's complementarity and Schr\"odinger's entanglement are two prominent physical characters of quantum systems. In this letter, we formally connect them. It is known that complementarity relations for wave-particle duality are saturated…

Quantum Physics · Physics 2022-08-11 Marcos L. W. Basso , Jonas Maziero

We propose the necessary and sufficient condition for the presence of quantum entanglement in arbitrary symmetric pure states of two-level atomic systems. We introduce a parameter to quantify quantum entanglement in such systems. We express…

Quantum Physics · Physics 2011-11-22 Ram Narayan Deb

Entanglement, a defining property of quantum mechanics in which two physical subsystems cannot be seen as independent entities, challenges our everyday experience and classical intuition. However, only such strong quantum correlations…

Quantum Physics · Physics 2025-11-13 Enno Giese

In this paper, we address the challenge of obtaining a comprehensive and symmetric representation of point particle groups, such as atoms in a molecule, which is crucial in physics and theoretical chemistry. The problem has become even more…

Chemical Physics · Physics 2024-02-13 Jigyasa Nigam , Sergey N. Pozdnyakov , Kevin K. Huguenin-Dumittan , Michele Ceriotti

It was shown recently that entanglement of identical particles has a feature called dualism [Phys. Rev. Lett. 110, 140404 (2013)], which is fundamentally connected with quantum indistinguishability. Here we report an experiment that…

Quantum Physics · Physics 2016-11-18 J. -J. Ma , X. -X. Yuan , C. Zu , X. -Y. Chang , P. -Y. Hou , L. -M. Duan

We derive two complementarity relations that constrain the individual and bipartite properties that may simultaneously exist in a multi-qubit system. The first expression, valid for an arbitrary pure state of n qubits, demonstrates that the…

Quantum Physics · Physics 2009-11-10 Tracey E. Tessier

The quantum mechanical description of the chemical bond is generally given in terms of delocalized bonding orbitals, or, alternatively, in terms of correlations of occupations of localised orbitals. However, in the latter case, multiorbital…

Quantum Physics · Physics 2017-05-23 Szilárd Szalay , Gergely Barcza , Tibor Szilvási , Libor Veis , Örs Legeza

We analyze two-particle binding factors of H2, LiH, and HeH+ molecules/ions with the help of our original exact diagonalization ab intio (EDABI) approach. The interelectronic correlations are taken into account rigorously within the second…

Strongly Correlated Electrons · Physics 2022-08-24 M. Hendzel , M. Fidrysiak , J. Spałek

Recent proposals of measuring bipartite Renyi entropy experimentally involve techniques that hold exactly for non-interacting quantum particles. Here we consider the difference between such measurements and the actual Renyi entropy for…

Strongly Correlated Electrons · Physics 2012-05-02 Norm M. Tubman , Jeremy McMinis