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In what has been described as the fourth age of Quantum Chemistry, variational nuclear motion programs are now routinely being used to obtain the vibration-rotation levels and corresponding wavefunctions of small molecules to the sort of…

Chemical Physics · Physics 2016-09-23 Jonathan Tennyson

A rigorous quantum description of molecular dynamics with a particular emphasis on internal observables is developed accounting explicitly for kinetic couplings between nuclei and electrons. Rotational modes are treated in a genuinely…

Chemical Physics · Physics 2015-07-07 Sylvain D. Brechet , Francois A. Reuse , Klaus Maschke , Jean-Philippe Ansermet

The limits of linear electrodynamics are reviewed, and possible directions of nonlinear extension are explored. The central theme is that the qualitative character of the empirical successes of quantum electrodynamics must be used as a…

High Energy Physics - Theory · Physics 2007-05-23 David Delphenich

On the basis of our recent model of a one-dimensional (1D) completed scattering we argue that Leggett's principles of macroscopic realism must and can be extended onto the level of single electrons and atoms. These principles need three…

Quantum Physics · Physics 2007-05-23 N. L. Chuprikov

Quantum matter, the research field studying phases of matter whose properties are intrinsically quantum mechanical, draws from areas as diverse as hard condensed matter physics, materials science, statistical mechanics, quantum information,…

Computational Physics · Physics 2020-08-21 Juan Carrasquilla

Recent progress in quantum electrodynamics (QED) calculations of highly charged ions is reviewed. The theoretical predictions for the binding energies, the hyperfine splittings, and the g factors are presented and compared with available…

Atomic Physics · Physics 2013-09-24 A. V. Volotka , D. A. Glazov , G. Plunien , V. M. Shabaev

The self-field approach to quantum electrodynamics (QED) is used to study the bound state problem in light-front two-dimensional QED with massive matter fields. A composite matter field describing bound states is introduced and the…

High Energy Physics - Theory · Physics 2009-10-31 Fuad M. Saradzhev

Classical molecular dynamics (MD) is a well established and powerful tool in various fields of science, e.g. chemistry, plasma physics, cluster physics and condensed matter physics. Objects of investigation are few-body systems and…

Strongly Correlated Electrons · Physics 2016-02-03 Vladimir Filinov , Michael Bonitz , Alexei Filinov , Volodymyr Golubnychiy

We present a framework for relativistic quantum metrology that is useful for both Earth-based and space-based technologies. Quantum metrology has been so far successfully applied to design precision instruments such as clocks and sensors…

Quantum Physics · Physics 2014-05-23 Mehdi Ahmadi , David Edward Bruschi , Carlos Sabín , Gerardo Adesso , Ivette Fuentes

We study quantum electrodynamics (QED) in the light-front dynamical form by using null-plane causal perturbation theory. We establish the equivalence with instant dynamics for the scattering processes, whose normalization allows to…

High Energy Physics - Theory · Physics 2022-08-17 O. A. Acevedo , B. M. Pimentel

The ever-growing intersection of quantum electrodynamics (QED) and molecular processes has shown remarkable and unanticipated advancements in altering molecular properties and reactivity by exploiting light-matter couplings. In recent…

Chemical Physics · Physics 2023-11-09 Xinyang Li , Yu Zhang

The quantum vacuum constitutes a fascinating medium of study, in particular since near-future laser facilities will be able to probe the nonlinear nature of this vacuum. There has been a large number of proposed tests of the low-energy,…

High Energy Physics - Theory · Physics 2010-04-23 Mattias Marklund , Joakim Lundin

The technique of quantum electrodynamics (QED) calculations of energy levels in the helium atom is reviewed. The calculations start with the solution of the Schr\"odinger equation and account for relativistic and QED effects by perturbation…

Atomic Physics · Physics 2021-07-14 Vladimir A. Yerokhin , Vojtech Patkos , Krzysztof Pachucki

The extraordinary success in laser cooling, trapping, and coherent manipulation of atoms has energized the efforts in extending this exquisite control to molecules. Not only are molecules ubiquitous in nature, but the control of their…

Atomic Physics · Physics 2022-04-27 D. Mitra , K. H. Leung , T. Zelevinsky

The Rydberg formula along with the Ritz quantum defect ansatz has been a standard theoretical tool used in atomic physics since before the advent of quantum mechanics, yet this approach has remained limited by its non-relativistic…

Atomic Physics · Physics 2022-12-12 David M. Jacobs

Atomic high-precision measurements have become a competitive and essential technique for tests of fundamental physics, the Standard Model, and our theory of gravity. It is therefore self-evident that such measurements call for a consistent…

Quantum Physics · Physics 2024-05-24 Tobias Asano , Enno Giese , Fabio Di Pumpo

Solving the electronic Schr\"odinger equation for changing nuclear coordinates provides access to the Born-Oppenheimer potential energy surface. This surface is the key starting point for almost all theoretical studies of chemical processes…

Chemical Physics · Physics 2022-01-14 Markus Reiher

We describe here the coherent formulation of electromagnetism in the non-relativistic quantum-mechanical many-body theory of interacting charged particles. We use the mathematical frame of the field theory and its quantization in the spirit…

Quantum Physics · Physics 2022-08-01 Ladislaus Alexander Bányai , Mircea Bundaru

Quantum thermodynamics seeks to extend non-equilibrium stochastic thermodynamics to small quantum systems where non-classical features are essential to its description. Such a research area has recently provided meaningful theoretical and…

In recent years simulations of chemistry and condensed materials has emerged as one of the preeminent applications of quantum computing, offering an exponential speedup for the solution of the electronic structure for certain strongly…

Quantum Physics · Physics 2022-01-19 Torin F. Stetina , Anthony Ciavarella , Xiaosong Li , Nathan Wiebe