Atomic structure calculations of helium with correlated exponential functions
Abstract
The technique of quantum electrodynamics (QED) calculations of energy levels in the helium atom is reviewed. The calculations start with the solution of the Schr\"odinger equation and account for relativistic and QED effects by perturbation expansion in the fine-structure constant . The nonrelativistic wave function is represented as a linear combination of basis functions depending on all three interparticle radial distances, , and . The choice of the exponential basis functions of the form allows us to construct an accurate and compact representation of the nonrelativistic wave function and to efficiently compute matrix elements of numerous singular operators representing relativistic and QED effects. Calculations of the leading QED effects of order (where is the electron mass) are complemented with the systematic treatment of higher-order and QED effects.
Keywords
Cite
@article{arxiv.2107.06134,
title = {Atomic structure calculations of helium with correlated exponential functions},
author = {Vladimir A. Yerokhin and Vojtech Patkos and Krzysztof Pachucki},
journal= {arXiv preprint arXiv:2107.06134},
year = {2021}
}