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Optimization problems are prevalent in various fields, and the gradient-based gradient descent algorithm is a widely adopted optimization method. However, in classical computing, computing the numerical gradient for a function with $d$…

Quantum Physics · Physics 2023-05-12 Ronghang Chen , Shi-Yao Hou , Cong Guo , Guanru Feng

Quantum State Tomography is the task of determining an unknown quantum state by making measurements on identical copies of the state. Current algorithms are costly both on the experimental front -- requiring vast numbers of measurements --…

Quantum Physics · Physics 2018-12-18 Yihui Quek , Stanislav Fort , Hui Khoon Ng

Quantum metrology promises improved sensitivity in parameter estimation over classical procedures. However, there is an extensive debate over the question how the sensitivity scales with the resources (such as the average photon number) and…

Quantum Physics · Physics 2010-11-10 Marcin Zwierz , Carlos A. Perez-Delgado , Pieter Kok

The expectation-maximization (EM) algorithm is a powerful computational technique for finding the maximum likelihood estimates for parametric models when the data are not fully observed. The EM is best suited for situations where the…

Computation · Statistics 2018-05-14 Chanseok Park

The famous, yet unsolved, Fermi-Hubbard model for strongly-correlated electronic systems is a prominent target for quantum computers. However, accurately representing the Fermi-Hubbard ground state for large instances may be beyond the…

Obtaining the expectation value of an observable on a quantum computer is a crucial step in the variational quantum algorithms. For complicated observables such as molecular electronic Hamiltonians, a common strategy is to present the…

Quantum Physics · Physics 2022-04-20 Tzu-Ching Yen , Aadithya Ganeshram , Artur F. Izmaylov

In many-body quantum systems, the quantum Fisher information an observer can obtain is susceptible to decoherence. Consequently, quantum enhanced metrology, such as Heisenberg scaling, cannot usually be achieved. We show, via two distinct…

Quantum Physics · Physics 2022-12-06 Le Hu , Shengshi Pang , Andrew Jordan

Variational quantum algorithms are considered one of the most promising methods for obtaining near-term quantum advantages; however, most of these algorithms are only expressed in the conventional quantum circuit scheme. The roadblock to…

Quantum Physics · Physics 2024-07-30 Zheng Qin , Xiufan Li , Yang Zhou , Shikun Zhang , Rui Li , Chunxiao Du , Zhisong Xiao

Many hybrid quantum-classical algorithms for the application of ground state energy estimation in quantum chemistry involve estimating the expectation value of a molecular Hamiltonian with respect to a quantum state through measurements on…

Quantum state estimation is important for various quantum information processes, including quantum communications, computation, and metrology, which require the characterization of quantum states for evaluation and optimization. We present…

Quantum Physics · Physics 2026-04-15 C. Vargas , L. Pereira , A. Delgado

Within the context of hybrid quantum-classical optimization, gradient descent based optimizers typically require the evaluation of expectation values with respect to the outcome of parameterized quantum circuits. In this work, we explore…

The efficient computation of observables beyond the total energy is a key challenge and opportunity for fault-tolerant quantum computing approaches in quantum chemistry. Here we consider the symmetry-adapted perturbation theory (SAPT)…

Accurately estimating the properties of quantum systems is a central challenge in quantum computing and quantum information. We propose a method to obtain unbiased estimators of multiple observables with low statistical error by…

Quantum Physics · Physics 2025-07-25 Stefano Mangini , Daniel Cavalcanti

Achieving ultimate bounds in estimation processes is the main objective of quantum metrology. In this context, several problems require measurement of multiple parameters by employing only a limited amount of resources. To this end,…

Squeezed light enables quantum-enhanced phase estimation, with crucial applications in both fundamental physics and emerging technologies. To fully exploit the advantage provided by this approach, estimation protocols must remain optimal…

Quantum Physics · Physics 2025-10-17 Giorgio Minati , Enrico Urbani , Nicolò Spagnolo , Valeria Cimini , Fabio Sciarrino

Computation of observables and their gradients on near-term quantum hardware is a central aspect of any quantum algorithm. In this work, we first review standard approaches to the estimation of observables with and without quantum amplitude…

Large machine learning models are revolutionary technologies of artificial intelligence whose bottlenecks include huge computational expenses, power, and time used both in the pre-training and fine-tuning process. In this work, we show that…

Quantum Physics · Physics 2024-01-15 Junyu Liu , Minzhao Liu , Jin-Peng Liu , Ziyu Ye , Yunfei Wang , Yuri Alexeev , Jens Eisert , Liang Jiang

We discuss a surprisingly simple scheme for accounting (and removal) of error in observables determined from quantum algorithms. A correction to the value of the observable is calculated by first measuring the observable with all error…

Quantum Physics · Physics 2018-04-20 Matthew Otten , Stephen Gray

The paper investigates the techniques of quantum computation in metrological predictions, with a particular emphasis on enhancing prediction potential through variational parameter estimation. The applicability of quantum simulations and…

Quantum Physics · Physics 2025-01-31 Vaidik A Sharma , N. Madurai Meenachi , B. Venkatraman
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