Related papers: When does the elastic regime begin in viscoelastic…
Nearly all dense suspensions undergo dramatic and abrupt thickening transitions in their flow behaviour when sheared at high stresses. Such transitions occur when the dominant interactions between the suspended particles shift from…
As an example for the interplay of structure, dynamics, and phase behavior of macromolecular systems, this article focuses on the problem of bottle-brush polymers with either rigid or flexible backbones. On a polymer with chain length…
When a viscoelastic shear-thinning drop of high elasticity hits a superhydrophobic surface, a growing tail-like filament vertically emerges from the impact spot as the contact line recedes. Notably, the ligament transitions into a…
The breakup and coalescence of drops are elementary topological transitions in interfacial flows. The breakup of a drop changes dramatically when polymers are added to the fluid. With the strong elongation of the polymers during the…
We study the rheology of dry and wet granular materials in the steady quasistatic regime using the Discrete Element Method (DEM) in a split-bottom ring shear cell with focus on the macroscopic friction. The aim of our study is to understand…
We consider one-dimensional bosonic chains with a repulsive boson-boson interaction that decays exponentially on large length-scales. This model describes transport of Cooper-pairs in a Josepshon junction array, or transport of magnetic…
The addition of minute amounts of chemically inert polyacrylamide polymer to liquids results in large instabilities under steady electro-osmotic pumping through 2:1 constrictions, demonstrating that laminar flow conditions can be broken in…
Lubricant viscoelasticity arises due to a finite polymer relaxation time ($\lambda$) and can provide beneficial effects. In applications, such as bearings, gears, biological joints, etc., where the height-to-length ratio is small ($H_0 /…
Constitutive equations are derived for the time-dependent behavior of particle-reinforced elastomers at isothermal loading with finite strains. A rubbery polymer is modelled as a network of macromolecules bridged by junctions which can slip…
We performed molecular dynamics simulations to study equilibrium and flow properties of a liquid in a nano-channel with confining surfaces coated with a layer of grafted semiflexible polymers. The coverage spans a wide range of grafting…
A number of commercial fluids, including synthetic automotive oils, food and consumer products containing polymer additives exhibit weakly rate-thickening responses in the final stages of capillarity-driven thinning, where a large…
An experimental investigation of the viscosity overshoot phenomenon observed during uniaxial extension of a low density polyethylene is pre- sented. For this purpose, traditional integral viscosity measurements on a Muenstedt type…
We extend classical Flory-Rehner theory for the expansion and compression of porous materials such as cross-linked polymer networks. The theory includes volume exclusion, affinity with the solvent, and finite stretching of the polymer…
Using experiments and a depth-averaged numerical model, we study instabilities of two-phase flows in a Hele-Shaw channel with an elastic upper boundary and a non-uniform cross-section prescribed by initial collapse. Experimentally, we find…
Liquid bridges form between particles during wet mixing with binders or by condensation due to ambient humidity. The consequences of capillary bridges can be quite drastic, creating macroscopic cohesion, as seen in sandcastles and in the…
Amorphous elastomers exhibit significant rate-stiffening and unique viscous flow characteristics across a wide range of strain rates, often undergoing glass transition above a strain rate threshold. We have developed a…
We theoretically investigate the looping dynamics of a linear polymer immersed in a viscoelastic fluid. The dynamics of the chain is governed by a Rouse model with a fractional memory kernel recently proposed by Weber et al. (S. C. Weber,…
Filamentous bio-materials such as fibrin or collagen networks exhibit an enormous stiffening of their elastic moduli upon large deformations. This pronounced nonlinear behavior stems from a significant separation between the stiffnesses…
By adding minute concentrations of a high molecular weight polymer, liquid jets or bridges collapsing under the action of surface tension develop a characteristic shape of uniform threads connecting spherical fluid drops. In this paper,…
Glassy polymers show strain hardening: at constant extensional load, their flow first accelerates, then arrests. Recent experiments under such loading have found this to be accompanied by a striking dip in the segmental relaxation time.…