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The 4H\textsubscript{b} polytype of TaS$_2$ is a natural heterostructure of H and T-type layers. Intriguing recent evidence points towards a possibly chiral superconducting ground state, unlike the superconductivity found in other polytypes…

4Hb-TaS_2, a van der Waals superlattice comprising alternate stacked Ising superconducting 1H-TaS_2 and cluster Mott insulating 1T-TaS_2, exhibits emergent properties beyond those of its constituent layers. Notable phenomena include…

A new frontier in condensed matter physics is to stack atomically thin layered-materials with different properties and create intriguing phenomena which do not exist in any of the constituent layers. Transition metal dichalcogenide…

The superconducting TMD 4Hb-TaS$_2$ consists of alternating layers of H and T structures, which in their bulk form are metallic and Mott-insulating, respectively. Recently, this compound has been proposed as a candidate chiral…

Superconductivity · Physics 2021-06-30 David Dentelski , Ezra Day-Roberts , Turan Birol , Rafael M. Fernandes , Jonathan Ruhman

The natural van der Waals heterostructure 4H$_b$-TaS$_2$ composed of alternating 1T- and 1H-TaS$_2$ layers serves as a platform for investigating the electronic correlations and layer-dependent properties of novel quantum materials. The…

Mesoscale and Nanoscale Physics · Physics 2025-10-07 R. Mathew Roy , X. Feng , M. Wenzel , V. Hasse , C. Shekhar , M. G. Vergniory , C. Felser , A. V. Pronin , M. Dressel

A recent experiment on the bulk compound 4Hb-TaS$_2$ reveals an unusual time-reversal symmetry-breaking superconducting state that possesses a magnetic memory not manifest in the normal state. Here we provide a mechanism for this…

Superconductivity · Physics 2024-07-10 Chunxiao Liu , Shubhayu Chatterjee , Thomas Scaffidi , Erez Berg , Ehud Altman

Here we use low-temperature scanning tunneling microscopy and spectroscopy (STM/STS) to reveal the roles of the narrow electronic band in two 1T-TaS$_2$-related materials (bulk 1T-TaS$_2$ and 4Hb-TaS$_2$). 4Hb-TaS$_2$ is a superconducting…

Mesoscale and Nanoscale Physics · Physics 2024-08-19 Chenhaoping Wen , Jingjing Gao , Yuan Xie , Qing Zhang , Pengfei Kong , Jinghui Wang , Yilan Jiang , Xuan Luo , Jun Li , Wenjian Lu , Yu-Ping Sun , Shichao Yan

The $\sqrt{13}\times\sqrt{13}$ charge density wave state of the T polytype of MX$_2$ (M=Nb,Ta, X=S, Se) is known to host a half-filled flat band, which electronic correlations drive into a Mott insulating state. When T polytypes are coupled…

Materials Science · Physics 2024-06-26 Irián Sánchez-Ramírez , Maia G. Vergniory , Fernando de Juan

We present a comprehensive first-principles investigation of defects in 4$H_b$-TaS$_2$. In this layered transition metal dichalcogenide, charge transfer between alternating Mott-insulating 1T and metallic 1H layers gives rise to exotic…

Materials Science · Physics 2026-03-26 Siavash Karbasizadeh , Wooin Yang , Wonhee Ko , Haidong Zhou , An-Ping Li , Tom Berlijn , Sai Mu

Recently, unusual $\pi$ phase shifts in Little-Parks experiments performed on two systems derived from the layered superconductor 2H-TaS$_2$ were reported. These systems share the common feature that additional layers have been inserted…

Superconductivity · Physics 2023-11-15 Mark H. Fischer , Patrick A. Lee , Jonathan Ruhman

Layered van der Waals (vdW) materials are emerging as one of the most versatile directions in the field of quantum condensed matter physics. They allow an unprecedented control of electronic properties via stacking of different types of…

Superconductivity · Physics 2020-08-18 A. Ribak , R. Majlin Skiff , M. Mograbi , P. K. Rout , M. H. Fischer , J. Ruhman , K. Chashka , Y. Dagan , A. Kanigel

The layered transition metal dichalcogenide compounds 1T-TaS2 and 4H-TaS2 are well known for their exotic properties, which include charge density wave, superconductivity, Mott transition, etc., and lately quantum spin liquid. Here, we…

The transition metal dichalcogenide 4H$_{b}$-TaS$_{2}$ exhibits characteristics of topological edge modes and two-component superconductivity with time-reversal symmetry breaking (TRSB). The nature of the superconducting order parameter is…

Superconductivity · Physics 2025-07-29 Yuwei Zhou , Fanyu Meng , Yanen Huang , Jiawen Zhang , Jin Zhan , Ye Chen , Yu Liu , Hechang Lei , Michael Smidman , Huiqiu Yuan

Charge density wave (CDW) and their interplay with correlated and topological quantum states are forefront of condensed matter research. The 4$H_{b}$-TaS$_2$ is a CDW ordered quantum heterostructure that is formed by alternative stacking of…

Realization of Kondo lattice in superconducting van der Waals materials not only provides a unique opportunity for tuning the Kondo lattice behavior by electrical gating or intercalation, but also is helpful for further understanding the…

We present the ultralow-temperature thermal conductivity measurements on single crystals of transition-metal dichalcogenide material 4Hb-TaS$_{2}$, which has recently been proposed as a topological superconductor candidate. In zero field, a…

Electron correlation is a main driver of exotic quantum phases and their interplay. The 4Hb-TaS2 system, possessing intrinsic heterostructure of 1T- and 1H-TaS2 monolayers, offers a unique opportunity to control electron correlation by…

Strongly Correlated Electrons · Physics 2026-01-30 Wooin Yang , Siavash Karbasizadeh , Hoyeon Jeon , Saban Hus , Arthur P. Baddorf , Sai Mu , Tom Berlijn , Haidong Zhou , Wonhee Ko , An-Ping Li

Most superconductors have an isotropic, single component order parameter, and are well described by the BCS theory for superconductivity. Unconventional, multiple components superconductors are exceptionally rare and are much less…

We find chiral charge order in the superconductor 2H-TaS2 using Scanning Tunneling Microscopy and Spectroscopy (STM/S) at 0.1 K. Topographic images show hexagonal atomic lattice and charge density wave (CDW) with clockwise and…

1T-TaS$_2$ undergoes successive phase transitions upon cooling and eventually enters an insulating state of mysterious origin. Some consider this state to be a band insulator with interlayer stacking order, yet others attribute it to Mott…

Strongly Correlated Electrons · Physics 2020-08-26 Y. D. Wang , W. L. Yao , Z. M. Xin , T. T. Han , Z. G. Wang , L. Chen , C. Cai , Yuan Li , Y. Zhang
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