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The ability to differentiate chiral molecules of different handedness is of great importance for chemical and life sciences. Since most of the relevant chiral molecules have their chiral transitions in the UV region, detecting their…

Atoms are usually thought of as achiral objects. However, one can construct superpositions of atomic states that are chiral [1]. Here we show how to excite such superpositions with tailored light fields both in the weak-field and…

Atomic Physics · Physics 2022-12-21 Nicola Mayer , Serguei Patchkovskii , Felipe Morales , Misha Ivanov , Olga Smirnova

Polar textures have attracted significant attention in recent years as a promising analog to spin-based textures in ferromagnets. Here, using optical second harmonic generation based circular dichroism, we demonstrate deterministic and…

Angle-resolved multiphoton ionization of fenchone and camphor by short intense laser pulses is computed by the time-dependent Single Center (TDSC) method. Thereby, the photoelectron circular dichroism (PECD) in the three-photon resonance…

Atomic and Molecular Clusters · Physics 2018-06-11 Anne D. Müller , Anton N. Artemyev , Philipp V. Demekhin

Chiral response is of tremendous importance to many fields, such as analytical chemistry, polarization manipulation and biological sensing. Here, a chiral metasurface based on rectangular holes is systematically investigated. The results…

Optics · Physics 2021-12-07 Biyuan Wu , Mingjun Wang , Yasong Sun , Feng Wu , Zhangxing Shi , Xiaohu Wu

To understand the relationship between the chirality of individual cells and that of tissues and organisms, we have developed a chiral polarized particle model to investigate the movement of cell populations on substrates. Our model…

Biological Physics · Physics 2024-07-02 Xi Li , Bin Chen

Chiroptical effects using circularly polarized light produce signals that change sign when switching either molecular handedness (enantiosensitivity) or the light helicity (circular dichroism). Here, we break this…

The circular dichroism (ICD) induced from interaction of chiral molecules with achiral plasmonic metal nanostructures has improved sensitivity of molecular chirality detection. Although experimental results have presented several orders…

Weyl semimetals are a three dimensional gapless topological phase in which bands intersect at arbitrary points -- the Weyl nodes -- in the Brillouin zone. These points carry a topological quantum number known as the \emph{chirality} and…

Strongly Correlated Electrons · Physics 2015-03-05 Pavan Hosur , Xiao-Liang Qi

We report on strong field ionization of S- and R-propylene oxide in circularly polarized two-color laser fields. We find that the relative helicity of the two single color laser fields affects the photoelectron circular dichroism (PECD).…

We report observation of electron helical dichroism on a material with chiral structure. In analogy with circular dichroism, a common technique for molecular structural fingerprinting, we use a nanofabricated forked diffraction grating to…

Materials Science · Physics 2015-07-08 Tyler R. Harvey , Jordan S. Pierce , Jordan J. Chess , Benjamin J. McMorran

Chirality, or handedness, is a geometrical property denoting a lack of mirror symmetry. Chirality is ubiquitous in nature and is associated with the non-reciprocal interactions observed in complex systems ranging from biomolecules to…

Quantum Physics · Physics 2024-08-08 Jonah S. Peter , Stefan Ostermann , Susanne F. Yelin

Chirality is ubiquitous in nature and of fundamental importance in science. The present work focuses on understanding the conditions required to modify the chirality during ultrafast electronic motion by bringing enantiomers…

Chemical Physics · Physics 2021-01-04 Sucharita Giri , Alexandra Maxi Dudzinski , Jean Christophe Tremblay , Gopal Dixit

The intermediate state dependence of photoelectron circular dichroism (PECD) in resonance-enhanced multi-photon ionization of fenchone in the gas phase is experimentally studied. By scanning the excitation wavelength from 359 to 431 nm we…

The chiral structure of liquid crystalline phases arises due to the intrinsic chirality of the constituent mesogens. While it is seemingly straightforward to quantify the macroscopic chirality by using, for instance, the cholesteric pitch…

Soft Condensed Matter · Physics 2007-05-23 Randall D. Kamien

Chirality arises from the asymmetry of matters, where two counterparts are the mirror image of each other. The interaction between circular-polarization light and quantum materials is enhanced in chiral space groups due to the structural…

Mesoscale and Nanoscale Physics · Physics 2023-09-13 Chang Niu , Shouyuan Huang , Neil Ghosh , Pukun Tan , Mingyi Wang , Wenzhuo Wu , Xianfan Xu , Peide D. Ye

We investigate how optimal control theory can be used to improve Circular Dichroism (CD) signals for A--band of fenchone measured via the photoionization yield upon further excitation. These transitions are electric dipole forbidden to…

Chirality is ubiquitous from microscopic to macroscopic phenomena in physics and biology, such as fermionic interactions and DNA duplication. In photonics, chirality has traditionally represented differentiated optical responses for right…

Optics · Physics 2019-09-02 Sunkyu Yu , Xianji Piao , Namkyoo Park

We present a rigorous finite element method to calculate circular dichroism (CD) in various systems consisting of nanostructures and oriented chiral molecules with electric quadrupole transitions. The interaction between oriented molecule…

Optics · Physics 2017-12-27 Weixuan Zhang , Tong Wu , Rongyao Wang , Xiangdong Zhang

A peculiar electron correlation effect, leading to orbital rotation upon ionization, theoretically predicted long ago, was never experimentally characterized. The effect is expected to appear prominently in the photoionization of chiral…

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