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Two-dimensional semiconducting materials have a wide range of applications in various fields due to their excellent properties and rich physics. Here, we report a detailed investigation of the temperature dependent Raman and…

Materials Science · Physics 2025-05-05 Atul G. Chakkar , Deepu Kumar , Ashok Kumar , Mahesh Kumar , Pradeep Kumar

We use a combination of polarized Raman spectroscopy experiment and model magnetism-phonon coupling calculations to study the rich magneto-Raman effect in the two-dimensional (2D) magnet $\mathrm{CrI_3}$. We reveal a novel…

Strong electron-phonon interaction which limits electronic mobility of semiconductors can also have significant effects on phonon frequencies. The latter is the key to the use of Raman spectroscopy for nondestructive characterization of…

Spin-phonon interactions in 2D magnetic materials are crucial in advancing next-generation spintronic devices. Therefore, identifying new materials with significant spin-phonon interactions is of great importance. In this context, MnSe,…

Materials Science · Physics 2025-02-27 Suman Kalyan Pradhan , Arnab Bera , Soham Das , Yongli Yu , Jicheng Wang , Rui Wu

The photoluminescence spectra of band-edge transitions in GaN is studied as a function of temperature. The parameters that describe the temperature dependence red-shift of the band-edge transition energy and the broadening of emission line…

Materials Science · Physics 2009-11-11 Niladri Sarkar , Subhasis Ghosh

The lattice dynamics of FeSb2 is investigated by the first-principles DFT calculations and Raman spectroscopy. All Raman and infra-red active phonon modes are properly assigned. The calculated and measured phonon energies are in good…

Materials Science · Physics 2012-05-30 N. Lazarevic , M. M. Radonjic , D. Tanaskovic , Rongwei Hu , C. Petrovic , Z. V. Popovic

We report high pressure Raman experiments of Black phosphorus up to 24 GPa. The line widths of first order Raman modes A$^1_g$, B$_{2g}$ and A$^2_g$ of the orthorhombic phase show a minimum at 1.1 GPa. Our first-principles density…

Strongly Correlated Electrons · Physics 2017-09-20 Satyendra Nath Gupta , Anjali Singh , Koushik Pal , Biswanath Chakraborti , D. V. S. Muthu , U V Waghmare , A. K. Sood

We present a systematic study of the structure and lattice dynamics at room temperature, and the phonon behavior at low temperatures in orthorhombic Gd$_{1-x}$Y$_{x}$MnO$_{3}$ manganites, with 0 $\leq$ x $\leq$ 0.4, using powder x-ray…

Strongly Correlated Electrons · Physics 2014-12-31 R. Vilarinho , E. C. Queirós , A. Almeida , P. B. Tavares , J. Agostinho Moreira

Infrared reflectivity spectra of cubic SrMnO$_{3}$ ceramics reveal 18 % stiffening of the lowest-frequency phonon below the antiferromagnetic phase transition occurring at T$_{N}$ = 233 K. Such a large temperature change of the polar phonon…

The interactions among lattice, charge, and spin degrees of freedom fundamentally shape material properties. In FeSe, symmetry-breaking perturbations serve as highly sensitive probes of these couplings. Previous work has shown that defects…

The detailed temperature dependence of the infrared-active mode in Fe$_{1.03}$Te ($T_N\simeq 68$ K) and Fe$_{1.13}$Te ($T_N\simeq 56$ K) has been examined, and the position, width, strength, and asymmetry parameter determined using an…

Strongly Correlated Electrons · Physics 2016-05-18 C. C. Homes , Y. M. Dai , J. Schneeloch , R. D. Zhong , G. D. Gu

We present a density functional perturbation theory approach to estimate the transition temperature of the charge density wave transition of TiSe2. The softening of the phonon mode at the L-point where in TiSe2 a giant Kohn anomaly occurs,…

Materials Science · Physics 2015-12-02 Dinh Loc Duong , Marko Burghard , J. Christian Schoen

In this work we study phonon-phonon coupling in bismuth vanadate (BiVO4), known for its second-order transition involving a variety of coupling mechanisms. Using Raman spectroscopy as a probe, we identify two optical coupled phonon modes of…

Materials Science · Physics 2023-06-09 Christina Hill , Georgy Gordeev , Mael Guennou

Raman scattering excitation (RSE) is an experimental technique in which the spectrum is made up by sweeping the excitation energy when the detection energy is fixed. We study the low-temperature ($T$=5~K) RSE spectra measured on four high…

We report a temperature-dependent Raman scattering investigation of DyScO3 and GdScO3 single crystals from room temperature up to 1200 {\deg}C. With increasing temperature, all modes decrease monotonously in wavenumber without anomaly,…

Materials Science · Physics 2010-04-13 O. Chaix-Pluchery , D. Sauer , J. Kreisel

The isospin-phonon coupling in Sr2IrO4 is investigated by temperature dependent phonon Raman scattering. Anomalous behavior in the frequency of all studied optical phonons is observed below the magnetic transition temperature TN ~240 K. The…

Strongly Correlated Electrons · Physics 2019-04-23 Kousik Samanta , Danilo Rigitano , Pascoal Jose Giglio Pagliuso , Eduardo Granado

The electrical conductivity and Raman spectroscopy measurements have been performed on MoS$_2$ at high pressures up to 90 GPa and variable temperatures down to 5 K. We find that the temperature dependence of the resistance in a metallic…

Materials Science · Physics 2018-06-27 Zi-Yu Cao , Jia-Wei Hu , Alexander F. Goncharov , Xiao-Jia Chen

We calculate the temperature dependence of NMR relaxation rate and electrical resistivity for coupling to a local, strongly anharmonic phonon mode. We argue that the two-phonon Raman process is dominating NMR relaxation. Due to the strong…

Superconductivity · Physics 2007-10-30 Thomas Dahm , Kazuo Ueda

The optical reflectivity of Pb$_{0.865}$Sn$_{0.135}$Se and Pb$_{0.75}$Sn$_{0.25}$Se solid solutions was measured in the THz spectral region energetically corresponding to bulk optical phonon excitations and in the temperature range from 40…

An experimental study of optical phonon modes, both normal and interface (IF) phonons, in bilayer strain-coupled InAs/GaAs_(1-x)Sb_x quantum dot heterostructures has been presented by means of low-temperature polarized Raman scattering. The…

Mesoscale and Nanoscale Physics · Physics 2024-09-17 Priyesh Kumar , Sudip Kumar Deb , Subhananda Chakrabarti , Jhuma Saha