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We use energies and forces predicted within response operator based quantum machine learning (OQML) to perform geometry optimization and transition state search calculations with legacy optimizers. For randomly sampled initial coordinates…

Chemical Physics · Physics 2022-07-25 S. Heinen , G. F. von Rudorff , O. A. von Lilienfeld

We systematically determine ground-state and saddle-point shapes and masses for 1305 heavy and superheavy nuclei with $Z=98-126$ and $N=134-192$, including odd-$A$ and odd-odd systems. From these, we derive static fission barrier heights,…

Nuclear Theory · Physics 2021-04-14 P. Jachimowicz , M. Kowal , J. Skalski

Bilevel optimization has arisen as a powerful tool in modern machine learning. However, due to the nested structure of bilevel optimization, even gradient-based methods require second-order derivative approximations via Jacobian- or/and…

Machine Learning · Computer Science 2022-06-07 Daouda Sow , Kaiyi Ji , Yingbin Liang

Meta-learning that uses implicit gradient have provided an exciting alternative to standard techniques which depend on the trajectory of the inner loop training. Implicit meta-learning (IML), however, require computing $2^{nd}$ order…

Machine Learning · Computer Science 2023-10-31 Fady Rezk

The framework of transition state theory (TST) provides a powerful way for analyzing the dynamics of physical and chemical reactions. While TST has already been successfully used to obtain reaction rates for systems with a single…

Chemical Physics · Physics 2021-02-26 Johannes Reiff , Matthias Feldmaier , Jörg Main , Rigoberto Hernandez

The landscape of condensed matter physics is facing an unprecedented data surge driven by high-throughput ab initio workflows and rapidly expanding experimental datasets. Traditional first-principles methods such as Density Functional…

Mesoscale and Nanoscale Physics · Physics 2026-04-20 Mahyar Hassani-Vasmejani , Hosein Alavi-Rad , Meysam Bagheri Tagani

In this paper, we study the problem of escaping from saddle points in smooth nonconvex optimization problems subject to a convex set $\mathcal{C}$. We propose a generic framework that yields convergence to a second-order stationary point of…

Machine Learning · Computer Science 2018-10-10 Aryan Mokhtari , Asuman Ozdaglar , Ali Jadbabaie

The combinations of machine learning with ab initio methods have attracted much attention for their potential to resolve the accuracy-efficiency dilemma and facilitate calculations for large-scale systems. Recently, equivariant message…

Computational Physics · Physics 2025-09-08 Zhixin Liang , Yunlong Wang , Chi Ding , Junjie Wang , Hui-Tian Wang , Dingyu Xing , Jian Sun

Access to the potential energy Hessian enables determination of the Gibbs free energy, and certain approaches to transition state search and optimization. Here, we demonstrate that off-the-shelf pretrained Open Catalyst Project (OCP)…

Materials Science · Physics 2024-10-08 Brook Wander , Joseph Musielewicz , Raffaele Cheula , John R. Kitchin

The design of high-entropy alloys (HEA) with desired properties is challenging due to their large compositional space. While various machine learning (ML) models can predict specific HEA solid-solution phases (SS), predicting high-entropy…

Materials Science · Physics 2023-06-27 Jie Qi , Diego Ibarra Hoyos , S. Joseph Poon

Initial value problems -- a system of ordinary differential equations and corresponding initial conditions -- can be used to describe many physical phenomena including those arise in classical mechanics. We have developed a novel approach…

Computational Physics · Physics 2025-05-27 Jack Griffiths , Steven A. Wrathmall , Simon A. Gardiner

The dynamics of Deep Linear Networks (DLNs) is dramatically affected by the variance $\sigma^2$ of the parameters at initialization $\theta_0$. For DLNs of width $w$, we show a phase transition w.r.t. the scaling $\gamma$ of the variance…

Machine Learning · Statistics 2022-02-01 Arthur Jacot , François Ged , Berfin Şimşek , Clément Hongler , Franck Gabriel

Ab initio instanton rate theory is a computational method for rigorously including tunnelling effects into calculations of chemical reaction rates based on a potential-energy surface computed on the fly from electronic-structure theory.…

Chemical Physics · Physics 2018-05-08 Gabriel Laude , Danilo Calderini , David P. Tew , Jeremy O. Richardson

Understanding and accurately predicting hydrogen diffusion in materials is challenging due to the complex interactions between hydrogen defects and the crystal lattice. These interactions span large length and time scales, making them…

Predicting the evolution of systems that exhibit spatio-temporal dynamics in response to external stimuli is a key enabling technology fostering scientific innovation. Traditional equations-based approaches leverage first principles to…

Machine Learning · Computer Science 2023-05-02 Francesco Regazzoni , Stefano Pagani , Matteo Salvador , Luca Dede' , Alfio Quarteroni

Machine learning interatomic potentials (MLIPs) have achieved remarkable accuracy on standard benchmarks, yet their ability to reproduce molecular kinetics -- critical for reaction rate calculations -- remains largely unexplored. We…

Machine learning (ML) models utilizing structure-based features provide an efficient means for accurate property predictions across diverse chemical spaces. However, obtaining equilibrium crystal structures typically requires expensive…

Materials Science · Physics 2021-04-22 Yunxing Zuo , Mingde Qin , Chi Chen , Weike Ye , Xiangguo Li , Jian Luo , Shyue Ping Ong

Deep learning has led to a paradigm shift in artificial intelligence, including web, text and image search, speech recognition, as well as bioinformatics, with growing impact in chemical physics. Machine learning in general and deep…

The problem of classifying turbulent environments from partial observation is key for some theoretical and applied fields, from engineering to earth observation and astrophysics, e.g. to precondition searching of optimal control policies in…

Fluid Dynamics · Physics 2022-10-19 Michele Buzzicotti , Fabio Bonaccorso

Training neural networks on image datasets generally require extensive experimentation to find the optimal learning rate regime. Especially, for the cases of adversarial training or for training a newly synthesized model, one would not know…

Machine Learning · Computer Science 2019-10-28 Koyel Mukherjee , Alind Khare , Ashish Verma