Related papers: Hyperfine-Resolved Rotational Spectroscopy of HCNH…
The absolute photodetachment cross section of OH- anions at a rotational and translational temperature of 170K is determined by measuring the detachment-induced decay rate of the anions in a multipole radio-frequency ion trap. In comparison…
A comprehensive, calculated line list of frequencies and transition probabilities for the singly deuterated isotopologue of H3+, H2D+, is presented. The line list, called ST1, contains over 22 million rotational-vibrational transitions…
We have studied natural purity $^{4}$He single crystals and polycrystals between 10 and 600 mK using a torsional oscillator with a 2 cm$^{3}$ rigid cell made of sapphire with a smooth geometry. As the temperature was lowered, we observed…
The photoelectron spectrum of water has been recorded in the vicinity of the ${\mathrm {\tilde A^+}}$ $\leftarrow$ $\tilde{\mathrm{X}}$ transition between 112 000 and 116 000 cm$^{-1}$ (13.89-14.38 eV). The high-resolution allowed the…
We demonstrate a new spectroscopic method for studying electronic transitions in molecules with extremely broad range of angular momentum. We employ an optical centrifuge to create narrow rotational wave packets in the ground electronic…
$^{133}\text{Ba}^+$ has been identified as an attractive ion for quantum information processing due to the unique combination of its spin-1/2 nucleus and visible wavelength electronic transitions. Using a microgram source of radioactive…
The chloroniumyl cation, HCl$^+$, has been recently identified in space from Herschel's spectra. A joint analysis of extensive vis-UV spectroscopy emission data together with a few high resolution and high accuracy mm-wave data provided the…
The rotationally resolved spectrum of the A ^1Pi_u <- X ^1Sigma^+_g 000-000 transition of C3, centered at 4051.6A, has been observed along 10 translucent lines of sight. To interpret these spectra, a new method for the determination of…
SH$^+$ is a surprisingly widespread molecular ion in diffuse interstellar clouds. There, it plays an important role triggering the sulfur chemistry. In addition, SH$^+$ emission lines have been detected at the UV-illuminated edges of dense…
The largest hyperfine interaction coefficients in the hydrogen molecular ion HD$^+$, i.e. the electron-proton and electron-deuteron spin-spin scalar interactions, are calculated with estimated uncertainties slightly below 1~ppm. The…
We present the results from arcsecond resolution observations of various line transitions at 1.3 mm toward hypercompact HII region G28.20-0.04N. With the SMA data, we have detected and mapped the transitions in the CH$_{3}$CN, CO,…
The projected systematic uncertainties of single trapped Ytterbium-ion optical frequency standards are estimated for the quadrupole and octupole transitions which are at wavelengths 435.5 nm and 467 nm, respectively. Finite temperature of…
Transient field-resolved spectroscopy enables studies of ultrafast dynamics in molecules, nanostructures, or solids with sub-cycle resolution, but previous work has so far concentrated on extracting the dielectric response at frequencies…
We describe a high-resolution spectroscopy method, in which the detection of single excitation events is enhanced by a complete loss of coherence of a superposition of two ground states. Thereby, transitions of a single isolated atom nearly…
We consider the spin-exchange (SE) cross section in electron scattering from $^3$He\,{\scriptsize II}, which drives the hyperfine-changing \hbox{3.46 cm} (8.665 GHz) line transition. Both the analytical quantum defect method --- applicable…
Iridium ions near $4f$-$5s$ level crossings are the leading candidates for a new type of atomic clocks with a high projected accuracy and a very high sensitivity to the temporal variation of the fine structure constant $\alpha$. To identify…
The wide span and high density of lines in its rovibrational spectrum render hydrogen cyanide a useful spectroscopic media for referencing absolute frequencies of lasers in optical communication and dimensional metrology. We determined, for…
The nitrogen-vacancy (NV) centers (NCVSi) - in 4H silicon carbide (SiC) constitute an ensemble of spin S = 1 solid state qubits interacting with the surrounding 14N and 29Si nuclei. As quantum applications based on a polarization transfer…
Longstanding problems in the comparison of very accurate hyperfine-shift measurements to theory were partly overcome by precise measurements on few-electron highly-charged ions. Still the agreement between theory and experiment is…
HC$_3$N is an ubiquitous molecule in interstellar environments, from external galaxies, to Galactic interstellar clouds, star forming regions, and planetary atmospheres. Observations of its rotational and vibrational transitions provide…