Related papers: Hyperfine-Resolved Rotational Spectroscopy of HCNH…

The calculation of the hindered roton-phonon energy levels of a hydrogen molecule in a confining potential with different symmetries is systematized for the case when the rotational angular momentum $J$ is a good quantum number. One goal of…

Rotational transitions in molecular hydrogen collisions are computed. The two most recently developed potential energy surfaces for the H2-H2 system are used from the following works: 1) A.I. Boothroyd, P.G. Martin, W.J. Keogh, M.J.…

We present a new global study of the millimeter (mm) wave, submillimeter (sub-mm) wave, and terahertz (THz) spectra of the lowest three torsional states of methyl mercaptan (CH$_3$SH). New measurements have been carried out between 50 and…

An accurate and comprehensive room temperature rotation-vibration transition line list for phosphine (31PH3) is computed using a newly refined potential energy surface and a previously constructed ab initio electric dipole moment surface.…

Rotation-vibration spectra of the nitric acid molecule, HNO\3, are calculated for wavenumbers up to 7000~\cm. Calculations are performed using a Hamiltonian expressed in internal curvilinear vibrational coordinates solved using a hybrid…

The saturated absorption spectrum of the hyperfine-less S(0) quadrupole line in the (2-0) band of H$_2$ is measured at $\lambda=1189$ nm, using the NICE-OHMS technique under cryogenic conditions (72~K). It is for the first time that a Lamb…

We have observed rovibrational transitions of acetylene and HCN near 13 microns in absorption toward GL2591. We also observed rotational lines of CS, HCN, H2CO, and HCO+. The combined data are analyzed in terms of models with a cloud…

Multipole radiofrequency ion traps are a highly versatile tool to study molecular ions and their interactions in a well-controllable environment. In particular the cryogenic 22-pole ion trap configuration is used to study ion-molecule…

We describe experimental investigations on an optical frequency standard based on a laser cooled 171Yb+ ion confined in a radiofrequency Paul trap. The electric-quadrupole transition from the 2S1/2(F=0) ground state to the 2D3/2(F=2) state…

The nucleus $^{180}$Hf is one of the most primary of examples of an axially symmetric prolate rotor. Combined with the presence of high-$K$ isomers, spectroscopic studies can provide important information on the nature of its…

Dilute frozen solutions of the single molecule magnet Ni$_4$ (S=4) have been studied using high frequency D-band (130 GHz) EPR. Despite the random orientation of the molecules, well defined EPR absorption peaks are observed, due to the…

The collision-energy resolved rate coefficient for dissociative recombination of HD+ ions in the vibrational ground state is measured using the photocathode electron target at the heavy-ion storage ring TSR. Rydberg resonances associated…

We use optical-optical double-resonance (OODR) spectroscopy with a continuous wave (CW) pump and a cavity-enhanced frequency comb probe to measure high rotational energy levels of methane in the upper part of the triacontad polyad (P6). A…

Interference between different energy eigenstates in a quantum system results in an oscillation with a frequency which is proportional to the difference in energy between the states. Such an oscillation is observable in polarized…

The shape of the UV ionizing background is reconstructed from optically thin metal absorption-line systems identified in spectra of HE2347-4342, Q1157+3143, and HS1700+6416 in the redshift interval 1.8 < z < 2.9. The systems are analyzed by…

The formyl cation (HCO+) is one of the most abundant ions in molecular clouds and plays a major role in the interstellar chemistry. For this reason, accurate collisional rate coefficients for the rotational excitation of HCO+ and its…

Optically active defects in solid-state systems have many applications in quantum information and sensing. However, unlike free atoms, which have fixed optical transition frequencies, the inhomogeneous broadening of the transitions in…

A ring crystal of ions trapped in a linear multipole trap is studied as a basis for an optical frequency standard. The equilibrium conditions and cooling possibilities are discussed through an analytical model and molecular dynamics…

Based on a novel laboratory method, 14 mm-wave lines of the molecular ion H$_2$CCCH$^+$ have been measured in high resolution, and the spectroscopic constants of this asymmetric rotor determined with high accuracy. Using the Yebes 40 m and…

We present a novel ultrastable superconducting radio-frequency (RF) ion trap realized as a combination of an RF cavity and a linear Paul trap. Its RF quadrupole mode at 34.52 MHz reaches a quality factor of $Q\approx2.3\times 10^5$ at a…