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A combined scattering mechanism involving the states of free electron-hole pairs (exciton continuum) and discrete excitons as intermediate states in the multi-phonon Raman scattering leads to (1) a strong increase of the scattering…

Condensed Matter · Physics 2009-10-28 I. G. Lang , A. V. Prokhorov , M. Cardona , V. I. Belitsky , A. Cantarero , S. T. Pavlov

We present an ab initio computational approach for the calculation of resonant Raman intensities, including both excitonic and non-adiabatic effects. Our diagrammatic approach, which we apply to two prototype, semiconducting layered…

Mesoscale and Nanoscale Physics · Physics 2020-10-01 Sven Reichardt , Ludger Wirtz

The weakly screened electron-hole interactions in an atomically thin semiconductor not only downshift its excitation spectrum from a quasiparticle one, but also redistribute excitation energies and wavefunction characters with profound…

Mesoscale and Nanoscale Physics · Physics 2018-10-24 Yuanxi Wang , Bruno R. Carvalho , Vincent H. Crespi

The optical properties of the two-dimensional (2D) crystals are dominated by tightly bound electron-hole pairs (excitons) and lattice vibration modes (phonons). The exciton-phonon interaction is fundamentally important to understand the…

Materials Science · Physics 2021-02-09 Qing-Hai Tan , Yu-Jia Sun , Xue-Lu Liu , Yanyuan Zhao , Qihua Xiong , Ping-Heng Tan , Jun Zhang

Excitons are neutral excitations that are composed of electrons and holes bound together by their attractive Coulomb interaction. The electron and the hole forming the exciton also interact with the underlying atomic lattice, and this…

Materials Science · Physics 2024-01-18 Zhenbang Dai , Chao Lian , Jon Lafuente-Bartolome , Feliciano Giustino

The dipole-dipole interactions between excitons are of paramount importance in the nanoscale structures. When two excitons are placed together they can exchange the energy can manifest in the resonant Raman cross sections. We provide…

Mesoscale and Nanoscale Physics · Physics 2024-04-09 Anna Wroblewska , Niclas S. Mueller , Mariusz Zdrojek , Stephanie Reich , Georgy Gordeev

We studied the intensity of resonant Raman scattering due to optical phonons in a planar II-VI-type semiconductor microcavity in the regime of strong coupling between light and matter. Two different sets of independent experiments were…

Strongly Correlated Electrons · Physics 2009-10-20 A. Bruchhausen , L. M. Leon Hilario , A. A. Aligia , A. M. Lobos , A. Fainstein , B. Jusserand , R. Andre

Raman spectra obtained by the inelastic scattering of light by crystalline solids contain contributions from first-order vibrational processes (e.g. the emission or absorption of one phonon, a quantum of vibration) as well as higher-order…

Materials Science · Physics 2017-08-22 Yannick Gillet , Stefan Kontur , Matteo Giantomassi , Claudia Draxl , Xavier Gonze

The excitonic insulator, a quantum mechanical state arising from exciton condensation, was proposed theoretically many years ago but has yet to be experimentally confirmed. The discovery of correlated transition metal oxides based on $4d$…

Strongly Correlated Electrons · Physics 2024-10-18 Hidemaro Suwa , Shang-Shun Zhang , Cristian D. Batista

A theoretical model of resonant hyper-Raman scattering by an ensemble of spherical semiconductor quantum dots has been developed. The electronic intermediate states are described as Wannier-Mott excitons in the framework of the envelope…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 E. Menendez-Proupin , C. Trallero-Giner , A. Garcia-Cristobal

The resonance effects on the Raman spectra from 5 to 900 cm-1 of few-layer MoS2 thin films up to 14-layers were investigated by using six excitation energies. For the main first-order Raman peaks, the intensity maximum occurs at ~2.8 eV for…

Materials Science · Physics 2015-02-06 Jae-Ung Lee , Jaesung Park , Young-Woo Son , Hyeonsik Cheong

Anisotropic two-dimensional (2D) semiconductors recently have emerged as a promising platform for polarization-controlled Raman amplification. In this study, we probe energy-dependent resonant Raman scattering in few layer ReS2 under…

Optics · Physics 2025-07-22 Pritam Das , Devarshi Chakrabarty , Neha Gill , Sajal Dhara

Resonance Raman scattering, which probes electrons, phonons and their interplay in crystals, is extensively used in two-dimensional materials. Here we investigate Raman modes in MoSe$_2$ at different laser excitation energies from 2.33 eV…

Exciton polaritons are hybrid particles of excitons (bound electron-hole pairs) and cavity photons, which are renowned for displaying Bose Einstein condensation and other coherent phenomena at elevated temperatures. However, their formation…

Mesoscale and Nanoscale Physics · Physics 2024-08-29 Kenneth Choo , Olivier Bleu , Jesper Levinsen , Meera M. Parish

While polarons --- charges bound to a lattice deformation induced by electron-phonon coupling --- are primary photoexcitations at room temperature in bulk metal-halide hybrid organic-inorganic perovskites (HOIP), excitons --- Coulomb-bound…

Materials Science · Physics 2020-04-14 Ajay Ram Srimath Kandada , Carlos Silva

Few-layer tungsten diselenide (WSe2) is investigated using circularly polarized Raman spectroscopy with up to eight excitation energies. The main E2g1 and A1g modes near 250 cm-1 appear as a single peak in the Raman spectrum taken without…

Mesoscale and Nanoscale Physics · Physics 2019-06-11 Sanghun Kim , Kangwon Kim , Jae-Ung Lee , Hyeonsik Cheong

The elementary optical excitations in two dimensional semiconductors hosting itinerant electrons are attractive and repulsive polarons -- excitons that are dynamically screened by electrons. Exciton-polarons have hitherto been studied in…

Resonant Raman scattering in semiconductor quantum dots with spherical shape is theoretically investigated. The Frohlich-like interaction between electronic states and optical vibrations has been considered. The Raman profiles are studied…

Condensed Matter · Physics 2009-10-31 E. Menendez-Proupin , J. L. Pena , C. Trallero-Giner

We use the Kramers-Heisenberg approach to derive a general expression for the resonant Raman scattering cross section from a one-dimensional (1D) system explicitly accounting for excitonic effects. The result should prove useful for…

Other Condensed Matter · Physics 2009-11-11 A. N. Vamivakas , A. Walsh , Y. Yin , M. S. Unlu , B. B. Goldberg , A. K. Swan

A novel type of exciton-phonon bound state -- interlayer polaron -- in a double-layer two-dimensional semiconductor with transition metal dichalcogenides as an example, is predicted. In these systems the interaction of the interlayer…

Materials Science · Physics 2020-10-06 M. A. Semina , M. M. Glazov , E. Ya. Sherman
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