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A theoretical framework is proposed for an energy decomposition scheme along the reaction coordinate, in which the ensemble average of the potential energy weighted with reactive flux intensity is decomposed into energy components at the…
Symmetry imposes constraints on open quantum systems, affecting the dissipative properties in nonequilibrium processes. Superradiance is a typical example in which the decay rate of the system is enhanced via a collective system-bath…
We derive general expressions for the free energy, entropy production and entropy extraction rates for a Brownian particle that walks in a viscous medium where the dynamics of its motion is governed by the Langevin equation. It is shown…
The "de Sitter constraint" on the space of effective scalar field theories consistent with superstring theory provides a lower bound on the slope of the potential of a scalar field which dominates the evolution of the Universe, e.g., a…
We explore the fundamental limits on thermodynamic irreversibility when cooling a quantum system in the presence of a finite-size reservoir. First, we prove that for any non-interacting $n$-particle reservoir, the entropy production…
A longstanding challenge in nonequilibrium thermodynamics is to predict the emergence of self-organized behaviours and functionalities typical of living matter. Despite the progress with classical complex systems, it remains far from…
The thermodynamics with medium effects expressed by the dispersion relation of the temperature and density dependent particle mass is studied. Many previous treatments have been reviewed. A new thermodynamical treatment based on the…
A recombination reaction model for high-temperature chemical kinetics is derived from ab initio simulations data. A kinetic recombination rate model is derived using a recently developed ab initio state-specific dissociation model and the…
This article reports about a novel extension of dissipative particle dynamics (DPD) that allows the study of the collective dynamics of complex chemical and structural systems in a spatially resolved manner with a combinatorially complex…
Situations where a spontaneous process of energy or matter transfer is enhanced by an external device are widespread in nature (human sweating system, enzyme catalysis, facilitated diffusion across bio-membranes, industrial heat…
The dissipation--coherence bound is a conjectured tradeoff between entropy production and the quality of stochastic oscillations. We show that this tradeoff follows from the higher-order thermodynamic uncertainty relation together with a…
We consider the hydrodynamic behavior of some conservative particle systems with degenerate jump rates without exclusive constraints. More precisely, we study the particle systems without restrictions on the total number of particles per…
Small thermodynamic systems exhibit peculiar behavior different from that observed in long-scale systems. Non-equilibrium processes taking place in those systems are strongly influenced by the presence of fluctuations which can be large.…
We study the thermodynamic limit of the six-vertex model with domain wall boundary and reflecting end. We evaluated the partition function explicitly in special cases. We calculated the homogeneous limit of the Tsuchiya determinant formula…
We prove a lower bound on the relative entropy between two finite-dimensional states in terms of their entropy difference and the dimension of the underlying space. The inequality is tight in the sense that equality can be attained for any…
Thermodynamic uncertainty relations have emerged as universal bounds on current fluctuations in non-equilibrium systems. Here we derive a new bound for a particular class of run-and-tumble type processes using the mathematical framework of…
A multiscale theory of interacting continuum mechanics and thermodynamics of mixtures of fluids, electrodynamics, polarization and magnetization is proposed. The mechanical (reversible) part of the theory is constructed in a purely…
In discrete-state Markovian systems, many important properties of correlations functions and relaxation dynamics depend on the spectrum of the rate matrix. Here we demonstrate the existence of a universal trade-off between thermodynamic and…
The existence of global weak solutions to a parabolic energy-transport system in a bounded domain with no-flux boundary conditions is proved. The model can be derived in the diffusion limit from a kinetic equation with a linear collision…
We compare the decay rates of excited populations directly calculated within a Keldysh formalism to the equation of motion of the population itself for a Hubbard-Holstein model in two dimensions. While it is true that these two approaches…