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When a solid plate is withdrawn from a partially wetting liquid, a liquid layer dewets the moving substrate. High-speed imaging reveals alternating thin and thick regions in the entrained layer in the transverse direction at steady state.…

Fluid Dynamics · Physics 2020-11-18 Mengfei He

An accurate prediction of the surface potential at the air-water interface is critical to calculating ion hydration free energies and electrochemical half-cell potentials. Using Density Functional Theory (DFT), model interfacial…

Materials Science · Physics 2010-09-22 Kevin Leung

The flow near a moving contact line depends on the dynamic contact angle, viscosity ratio, and capillary number. We report experiments involving immersing a plate into a liquid bath, concurrently measuring the interface shape, interfacial…

Fluid Dynamics · Physics 2024-12-04 Charul Gupta , Anjishnu Choudhury , Lakshmana D Chandrala , Harish N Dixit

The contribution to the free energy for a film of liquid of thickness $h$ on a solid surface, due to the interactions between the solid-liquid and liquid-gas interfaces is given by the binding potential, $g(h)$. The precise form of $g(h)$…

Soft Condensed Matter · Physics 2015-07-08 Adam P. Hughes , Uwe Thiele , Andrew J. Archer

We present a modification to our recently published SAFT-based classical density functional theory for water. We have recently developed and tested a functional for the averaged radial distribution function at contact of the hard-sphere…

Soft Condensed Matter · Physics 2015-06-17 Eric J. Krebs , Jeff B. Schulte , David Roundy

From hydrogels and plastics to liquid crystals, soft solids cover a wide array of synthetic and biological materials that play key enabling roles in advanced technologies such as 3D printing, soft robotics, wearable electronics,…

Soft Condensed Matter · Physics 2022-11-15 Surjyasish Mitra , Quoc Vo , Marcus Lin , Tuan Tran

The characterization of the wetting on superhydrophobic surfaces is rather complex. Usual contact angle experiments are difficult to perform and the lateral movement of droplets as well as the pinning at point defects on the surface can…

We use direct numerical simulations to investigate the interaction between the temperature field of a fluid and the temperature of small particles suspended in the flow, employing both one and two-way thermal coupling, in a statistically…

Fluid Dynamics · Physics 2020-01-08 Maurizio Carbone , Andrew D. Bragg , Michele Iovieno

Superhydrophobic surfaces play an important role in the development of new product coatings such as cars, but also in mechanical engineering, especially design of turbines and compressors. Thus a vital part of the design of these surfaces…

While fluids near a solid surface are at the core of applications in energy storage/conversion, electrochemistry/electrowetting and adsorption/catalysis, their nanoscale behavior remains only partially deciphered. Beyond conventional…

Soft Condensed Matter · Physics 2026-01-07 Cecilia Herrero , Lyderic Bocquet , Benoit Coasne

Although density functional theory provides reliable predictions for the static properties of simple fluids under confinement, a theory of comparative accuracy for the transport coefficients has yet to emerge. Nonetheless, there is evidence…

Molecular dynamics simulations are used to study the behavior of closely-fitting spherical and ellipsoidal particles moving through a fluid-filled cylinder at nanometer scales. The particle, the cylinder wall and the fluid solvent are all…

Soft Condensed Matter · Physics 2007-05-23 German Drazer , Boris Khusid , Joel Koplik , Andreas Acrivos

We study wetting droplets formed of active Brownian particles in contact with a repulsive potential barrier, in a wedge geometry. Our numerical results demonstrate a transition between partially wet and completely wet states, as a function…

Statistical Mechanics · Physics 2023-10-12 Francesco Turci , Robert L. Jack , Nigel B. Wilding

The line tension of an electrolyte wetting a non-polar substrate is computed analytically and numerically. The results show that, depending on the value of the apparent contact angle, positive or negative line tension values may be…

Chemical Physics · Physics 2014-11-06 Aaron Dörr , Steffen Hardt

We provide a complete description of the low temperature wetting transition for the two dimensional Solid-On-Solid model. More precisely we study the integer-valued field $(\phi(x))_{x\in \mathbb Z^2}$, associated associated to the energy…

Mathematical Physics · Physics 2018-07-04 Hubert Lacoin

By combining methods of kinetic and density functional theory, we present a description of molecular fluids which accounts for their microscopic structure and thermodynamic properties as well as for the hydrodynamic behavior. We focus on…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Umberto Marini Bettolo Marconi , Simone Melchionna

Convective flows coupled with solidification or melting in water bodies play a major role in shaping geophysical landscapes. Particularly in relation to the global climate warming scenario, it is essential to be able to accurately quantify…

Fluid Dynamics · Physics 2021-03-11 Ziqi Wang , Enrico Calzavarini , Chao Sun , Federico Toschi

Plasma treatment of polymer films results in their electrical charging, which in turn gives rise to an increase in their surface energy. The process results in pronounced hydrophilization of the polymer surfaces. A phenomenological theory…

We introduce a new computationally efficient and accurate classical density-functional theory for water and apply it to hydration of hard spheres and inert gas atoms. We find good agreement with molecular dynamics simulations for the…

Statistical Mechanics · Physics 2010-01-16 Sahak A. Petrosyan , David Roundy , Jean-Francois Briere , Tomas A. Arias

Fluids with competing short range attraction and long range repulsive interactions between the particles can exhibit a variety of microphase separated structures. We develop a lattice-gas (generalised Ising) model and analyse the phase…

Soft Condensed Matter · Physics 2016-01-20 Blesson Chacko , Christopher Chalmers , Andrew J. Archer