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The density functional approach for classical associating fluids is used to explore the wetting phase diagrams for model systems consisting of water and graphite-like solid surfaces chemically modified by a small amount of grafted chain…

Soft Condensed Matter · Physics 2025-06-26 O. Pizio

As a first step towards a microscopic understanding of the effective interaction between colloidal particles suspended in a solvent we study the wetting behavior of one-component fluids at spheres and fibers. We describe these phenomena…

Condensed Matter · Physics 2015-06-25 T. Bieker , S. Dietrich

The wetting of solid surfaces by fluids is a problem of great practical importance that has been extensively studied over the years. Most often, the experimental work has involved measurements of the contact angle made by a liquid on the…

Statistical Mechanics · Physics 2007-05-23 S. Curtarolo , M. J. Bojan , G. Stan , M. W. Cole , W. A. Steele

We discuss the effect of an external electric field on the wetting of a solid surface by liquid. To this end, we use a model of the two-level-atom fluid for which the changes in interatomic interactions due to the presence of the field can…

Soft Condensed Matter · Physics 2017-02-20 Vasyl Myhal , Oleg Derzhko

A microscopic density functional theory is used to investigate the adsorption of short chains on attractive solid surfaces. We analyze the structure of the adsorbed fluid and investigate how the wetting transition changes with the change of…

Soft Condensed Matter · Physics 2007-05-23 P. Bryk , S. Sokolowski

In part 1, we proposed a model of dynamics of wetting for slow movements near a contact line formed at the interface of two immiscible fluids and a solid when viscous dissipation remains bounded. The contact line is not a material line and…

Classical Physics · Physics 2008-01-15 Henri Gouin

We develop a classical density functional for water which combines the White Bear fundamental-measure theory (FMT) functional for the hard sphere fluid with attractive interactions based on the Statistical Associating Fluid Theory…

Soft Condensed Matter · Physics 2013-09-10 Jessica Hughes , Eric Krebs , David Roundy

We have explored the phase behavior of a set of water-like models in slit pores of nanoscopic dimensions. The interaction between water and pore walls mimics the graphite surface. A version of density functional method is used as…

Soft Condensed Matter · Physics 2021-10-12 O. Pizio , S. Sokolowski , V. M. Trejos

We use molecular simulations to demonstrate the connection between transverse water-water correlations and wetting phenomena for a range of hydrophobic to hydrophilic solid surfaces.Near superhydrophobic surfaces, the correlations are long…

Soft Condensed Matter · Physics 2014-09-10 Rahul Godawat , Sumanth N. Jamadagni , Vasudevan Venkateshwaran , Shekhar Garde

The phenomenon of electrowetting, i.e., the dependence of the macroscopic contact angle of a fluid on the electrostatic potential of the substrate, is analyzed in terms of the density functional theory of wetting. It is shown that…

Soft Condensed Matter · Physics 2014-05-07 Markus Bier , Ingrid Ibagon

The understanding of the spreading of liquids on solid surfaces is an important challenge for contemporary physics. Today, the motion of the contact line formed at the intersection of two immiscible fluids and a solid is still subject to…

Classical Physics · Physics 2009-11-13 Henri Gouin

Surface properties of mixtures of charged platelike colloids and salt in contact with a charged planar wall are studied within density functional theory. The particles are modeled by hard cuboids with their edges constrained to be parallel…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Ludger Harnau , S. Dietrich

We study the behavior of very thin liquid films wetting homogeneous planar and spherical substrates. In order to describe a simple fluid at very small scales, we employ a classical density functional theory (DFT). Here, we model a fluid…

Statistical Mechanics · Physics 2017-01-10 Andreas Nold

We use a density functional approach to calculate the contact angle of the water model on a heterogeneous, graphite-like surface. The surface heterogeneity results from the pre-adsorption of a layer of spherical species. The pre-adsorbed…

Soft Condensed Matter · Physics 2022-10-04 K. Dąbrowska , O. Pizio , S. Sokołowski

We study the equilibrium of a liquid film on an attractive spherical substrate for an intermolecular interaction model exhibiting both fluid-fluid and fluid-wall long-range forces. We first reexamine the wetting properties of the model in…

Statistical Mechanics · Physics 2013-10-04 Andreas Nold , Alexandr Malijevský , Serafim Kalliadasis

Previously, it has been shown that the direct correlation function for a Lennard-Jones fluid could be modeled by a sum of that for hard-spheres, a mean-field tail and a simple linear correction in the core region constructed so as to…

Statistical Mechanics · Physics 2008-08-20 James F. Lutsko

Wetting is fundamental to many technological applications that involve the motion of the fluid-fluid interface on a solid. While static wetting is well understood in the context of thermodynamic equilibrium, dynamic wetting is more…

Fluid Dynamics · Physics 2021-08-16 Shahriar Afkhami

In the classic theory of solid adhesion, surface energy drives deformation to increase contact area while bulk elasticity opposes it. Recently, solid surface stress has been shown also to play an important role in opposing deformation of…

Soft Condensed Matter · Physics 2016-02-17 K. E. Jensen , R. Sarfati , R. W. Style , R. Boltyanskiy , A. Chakrabarti , M. K. Chaudhury , E. R. Dufresne

Within an Onsager-like density functional theory we explore the thermodynamic and structural properties of an isotropic and nematic fluid of hard needle-like colloids in contact with a hard substrate coated with a soft short-ranged…

Soft Condensed Matter · Physics 2009-11-11 K. Shundyak , R. van Roij

We propose a sharp-interface model for solid-state dewetting of thin films with wetting potential, where the wetting effect is incorporated through a thickness-dependent surface energy. The model is governed by surface diffusion together…

Numerical Analysis · Mathematics 2026-04-29 Weijie Huang , Xinran Ruan
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