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Predictive first-principles calculations suggest graphitic-like GaN to be theoretically possible. Thus far, it has not been experimentally reported. We report on GaN monolayer in a buckled geometry obtained in confinement at graphene/SiC…

We demonstrate a technique to produce thin graphene layers on C-face of SiC under ultra high vacuum conditions. A stack of two SiC substrates comprising a half open cavity at the interface is used to partially confine the depleted Si atoms…

Materials Science · Physics 2013-04-23 C. Celebi , C. Yanik , A. G. Demirkol , Ismet I. Kaya

The evolution of electronic structure of graphene nanoribbons (GNRs) as a function of the number of layers stacked together is investigated using \textit{ab initio} density functional theory (DFT) including interlayer van der Waals…

Materials Science · Physics 2011-10-28 Neerav Kharche , Yu Zhou , Kevin P. O'Brien , Swastik Kar , Saroj K. Nayak

Defects in graphene are both a boon and a bane for applications - they can induce uncontrollable effects but can also provide novel ways to manipulate the properties of pristine graphene. Nanoporous Graphene, which contains nanoscopic…

Materials Science · Physics 2023-10-09 Ji Wei Yoon

Recent progress in porous carbon materials has highlighted the importance of structural design in controlling emergent physicochemical properties. In this context, hydrogen-substituted graphdiyne (HsGDY), a three-dimensional framework…

We investigated the growth of twisted graphene on graphene/silicon carbide (SiC-G) templates by metal-free chemical vapor deposition (CVD) through a sequential thermal (ST) process, which exploits the ultraclean surface of SiC-G without…

Materials Science · Physics 2024-02-08 Yao Yao , Taiki Inoue , Makoto Takamura , Yoshitaka Taniyasu , Yoshihiro Kobayashi

Twisted van der Waals multilayers are widely regarded as a rich platform to access novel electronic phases, thanks to the multiple degrees of freedom such as layer thickness and twist angle that allow control of their electronic and…

We demonstrate the growth of graphene nanocrystals by molecular beam methods that employ a solid carbon source, and that can be used on a diverse class of large area dielectric substrates. Characterization by Raman and Near Edge X-ray…

Functional nano-templates enable self-assembly of otherwise impossible arrangements of molecules. A particular class of such templates is that of sp2 hybridized single layers of hexagonal boron nitride or carbon (graphene) on metal…

Atomic and Molecular Clusters · Physics 2010-09-28 Haifeng Ma , Mario Thomann , Jeanette Schmidlin , Silvan Roth , Martin Morscher , Thomas Greber

This work demonstrates the unique approach of introducing divacancy imperfections in topological Stone-Wales type defected graphene quantum dots for harvesting both singlet and triplet excitons, essential for fabricating fluorescent organic…

Mesoscale and Nanoscale Physics · Physics 2022-08-09 Tushima Basak , Tista Basak , Alok Shukla

We study the dependence of mechanical conformations of graphene sheets located on flat substrates on the density of unilateral (one-side) attachment of hydrogen, fluorine or chlorine atoms to them. It is shown that chemically modified…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Alexander V. Savin , Yuriy A. Kosevich

Graphene-based nanofolds (GNFs) are edge-connected 2D stacked monolayers originated from single-layer graphene. Graphene-based nanoscrolls (GNSs) are nanomaterials with geometry resembling graphene layers rolled up into a spiral…

Materials Science · Physics 2021-09-23 Marcelo Lopes Pereira Junior , Luiz Antonio Ribeiro Junior

The fundamental properties of graphene are making it an attractive material for a wide variety of applications. Various techniques have been developed to produce graphene and recently we discovered the synthesis of large area graphene by…

Graphene nanoribbons display an imperfectly understood transport gap. We measure transport through nanoribbon devices of several lengths. In nanoribbons of length greater than or equal to 250 nm we observe transport through multiple quantum…

Mesoscale and Nanoscale Physics · Physics 2009-01-02 Kathryn Todd , Hung-Tao Chou , Sami Amasha , David Goldhaber-Gordon

Ordered configurations of hydrogen adatoms on graphene have long been proposed, calculated and searched for. Here we report direct observation of several ordered configurations of H adatoms on graphene by scanning tunneling microscopy. On…

In a multi-layer electronic system, stacking order provides a rarely-explored degree of freedom for tuning its electronic properties. Here we demonstrate the dramatically different transport properties in trilayer graphene (TLG) with…

Mesoscale and Nanoscale Physics · Physics 2012-01-23 W. Bao , L. Jing , Y. Lee , J. Velasco , P. Kratz , D. Tran , B. Standley , M. Aykol , S. B. Cronin , D. Smirnov , M. Koshino , E. McCann , M. Bockrath , C. N. Lau

Graphynes and graphdiynes are generic names for families of two-dimensional carbon allotropes, where acetylenic groups connect benzenoid-like hexagonal rings, with the co-existence of sp and sp2 hybridized carbon atoms. The main differences…

Mesoscale and Nanoscale Physics · Physics 2018-03-02 Daniel Solis , Daiane D. Borges , Cristiano F. Woellner , Douglas S. Galvao

This work analyzes carrier transport, the relaxation of non-equilibrium charge, and the electronic structure of fluorinated graphene (FG) films with graphene quantum dots (GQDs). The FG films with GQDs were fabricated by means of chemical…

Mesoscale and Nanoscale Physics · Physics 2022-05-03 I. V. Antonova , N. A. Nebogatikova , V. Ya. Prinz

Carbon foams are hypothetical carbon allotropes that contain graphite-like (sp$^2$ carbon) segments, connected by sp$^3$ carbon atoms, resulting in porous structures. In this work the DFTB (Density Functional based Tight-Binding) method…

Materials Science · Physics 2013-02-15 Gotthard Seifert , Agnieszka Kuc , Thomas Heine

We use scanning tunneling microscopy and spectroscopy to study epitaxial graphene grown on a C-face 4H-SiC(000-1) substrate. The results reveal amazing nano-objects at the graphene/SiC interface leading to electronic interface states. Their…

Mesoscale and Nanoscale Physics · Physics 2009-11-12 S. Vizzini , H. Enriquez , S. Chiang , H. Oughaddou , P. Soukiassian