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We demonstrate a molecular rectifying junction made from a sequential self-assembly on silicon. The device structure consists of only one conjugated (p) group and an alkyl spacer chain. We obtain rectification ratios up to 37 and threshold…

In this study, we examine the mechanism of nanopore-based DNA sequencing using a voltage bias across a graphene nanoribbon. Using density functional theory and a non-equilibrium Green's function approach, we determine the transmission…

Mesoscale and Nanoscale Physics · Physics 2018-09-11 Hannah L. McFarland , Towfiq Ahmed , Jian-Xin Zhu , Alexander V. Balatsky , Jason T. Haraldsen

Nanopores that exhibit ionic current rectification (ICR) behave like diodes, such that they transport ions more efficiently in one direction than the other. Conical nanopores have been shown to rectify ionic current, but only those with at…

Chemical Physics · Physics 2022-06-08 Long Ma , Zhongwu Li , Zhishan Yuan , Chuanzhen Huang , Zuzanna S. Siwy , Yinghua Qiu

Graphene is a famous truly two-dimensional (2D) material, possessing a cone-like energy structure near the Fermi level and treated as a gapless semiconductor. Its unique properties trigger researchers to find applications of it. The gapless…

Materials Science · Physics 2024-02-22 Wei-Bang Li , Kuang-I Lin , Yu-Ming Wang , Hsien-Ching Chung , Ming-Fa Lin

The atomically-precise controlled synthesis of graphene stripes embedded in hexagonal boron nitride opens up new possibilities for the construction of nanodevices with applications in sensing. Here, we explore properties related to…

Materials Science · Physics 2017-08-21 Fabio A. L. de Souza , Wanderla L. Scopel , Rodrigo G. Amorim , Ralph H. Scheicher

We report a first-principles based study of mesoscopic quantum transport in chemically doped graphene nanoribbons with a width up to 10 nm. The occurrence of quasibound states related to boron impurities results in mobility gaps as large as…

Mesoscale and Nanoscale Physics · Physics 2009-07-09 Blanca Biel , François Triozon , X. Blase , Stephan Roche

The electronic nonlinear transport through ultra narrow graphene nanoribbons (sub-$10nm$) is studied. A stable region of negative differential resistance (NDR) appears in the I-V characteristic curve of {\it odd} zigzag graphene nanoribbons…

Mesoscale and Nanoscale Physics · Physics 2012-11-14 Hosein Cheraghchi

We examine the possibility of using graphene nanoribbons (GNRs) with directly substituted chromium atoms as spintronic device. Using density functional theory, we simulate a voltage bias across a constructed GNR in a device setup, where a…

In graphene nanoribbon junctions, the nearly perfect transmission occurs in some junctions while the zero conductance dips due to anti-resonance appear in others. We have classified the appearance of zero conductance dips for all…

Mesoscale and Nanoscale Physics · Physics 2009-09-07 Masayuki Yamamoto , Katsunori Wakabayashi

Graphene nanoribbons are one-dimensional stripes of graphene with width- and edge-structure-dependent electronic properties. They can be synthesized bottom-up in solution to obtain precise ribbon geometries. Here we investigate the optical…

Graphene nanoribbons (GNRs) are unique quasi-one-dimensional (1D) materials that have garnered a lot of research interest in the field of topological insulators. While the topological phases exhibited by GNRs are primarily governed by their…

Mesoscale and Nanoscale Physics · Physics 2024-06-21 Haiyue Huang , Mamun Sarker , Percy Zahl , C. Stephen Hellberg , Jeremy Levy , Ioannis Petrides , Alexander Sinitskii , Prineha Narang

Substituting heteroatoms and non-benzenoid carbons into nanographene structure offers an unique opportunity for atomic engineering of electronic properties. Here we show the bottom-up synthesis of graphene nanoribbons (GNRs) with embedded…

The electronic, optical and magnetic properties of graphene nanoribbons (GNRs) can be engineered by controlling their edge structure and width with atomic precision through bottom-up fabrication based on molecular precursors. This approach…

Geometric diodes, which take advantage of geometric asymmetry to achieve current flow preference, are promising for THz current rectification. Previous studies relate geometric diodes' rectification to quantum coherent or ballistic…

Applied Physics · Physics 2021-01-26 Mengmeng Bai , Yanqing Zhao , Shuting Xu , Yao Guo

Tailor-made graphene nanostructures can exhibit symmetry-protected topological boundary states that host localized spin-$1/2$ moments. However, one frequently observes charge transfer on coinage metal substrates, which results in spinless…

Down-scaling device dimensions to the nanometer range raises significant challenges to traditional device design, due to potential current leakage across nanoscale dimensions and the need to maintain reproducibility while dealing with…

Mesoscale and Nanoscale Physics · Physics 2019-01-03 Zhongcan Xiao , Chuanxu Ma , Jingsong Huang , Liangbo Liang , Wenchang Lu , Kunlun Hong , Bobby G. Sumpter , An-Ping Li , J. Bernholc

We have investigated ion current rectification properties of a recently prepared bipolar nanofluidic diode. This device is based on a single conically shaped nanopore in a polymer film whose pore walls contain a sharp boundary between…

Other Condensed Matter · Physics 2009-11-13 D. Constantin , Z. S. Siwy

Coupled nanomechanical resonators are interesting for both fundamental studies and practical applications as they offer rich and tunable oscillation dynamics. At present, the mechanical coupling in such systems is often mediated by a fixed…

Mesoscale and Nanoscale Physics · Physics 2020-11-10 G. J. Verbiest , M. Goldsche , J. Sonntag , T. Khodkov , N. von den Driesch , D. Buca , C. Stampfer

Graphene nanoribbons (GNRs) are promising two-dimensional materials with various technological applications, in particular for the armchair GNR families that have a semiconductor character. Recently, methods that allowed for the control of…

Today graphene nanoribbons and other graphene-based nanostructures can be synthesized with atomic precision. But while investigations have concentrated on straight graphene ribbons of fixed crystal orientation, ribbons with intrinsic…

Materials Science · Physics 2015-01-29 C. G. Rocha , R. Tuovinen , R. van Leeuwen , P. Koskinen