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Tip-enhanced nano-spectroscopy and -imaging, such as tip-enhanced photoluminescence (TEPL), tip-enhanced Raman spectroscopy (TERS), and others, have become indispensable from materials science to single molecule studies. However, the…

Band gap tuning in two-dimensional transitional metal dichalcogenides (TMDs) is crucial in fabricating new optoelectronic devices. High resolution photoluminescence (PL) microscopy is needed for accurate band gap characterization. We…

Optics · Physics 2017-04-13 Chenwei Tang , Shuai Jia , Weibing Chen , Jun Lou , Dmitri V. Voronine

The plasmonic tip of a scanning tunnelling microscope (STM) is functionalized with a single fluorescent molecule and is scanned on a plasmonic substrate. The tunneling current flowing through the tip-molecule-substrate junction generates a…

Methods for nanoscale material characterization are in ever-increasing demand, especially those that can provide a broader range of information at once. Near-field techniques based on combinations of scanning probe microscopy (SPM) and…

Applied Physics · Physics 2020-11-11 Alvaro Rodriguez , Tim Verhagen , Martin Kalbac , Jana Vejpravova , Otakar Frank

We investigate electroluminescence of single molecular emitters on NaCl on Ag(111) and Au(111) with submolecular resolution in a low-temperature scanning probe microscope with tunneling current, atomic force and light detection…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Jiří Doležal , Pablo Merino , Jesus Redondo , Lukáš Ondič , Aleš Cahlík , Martin Švec

Here, we introduce and experimentally demonstrate optical amplification and stimulated emission from a single optically pumped molecular tunneling junction of a scanning tunneling microscope. The gap between a sharp gold tip and a flat gold…

Optics · Physics 2014-01-09 K. Braun , A. M. Kern , X. Wang , H. Adler , H. Peisert , T. Chasse , D. Zhang , A. J. Meixner

We explore theoretically the electroluminescence of single molecules. We adopt a local-electrode framework that is appropriate for scanning tunneling microscopy (STM) experiments where electroluminescence originates from individual…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 John Buker , George Kirczenow

A promising route for the development of opto-elelctronic technology is to use terahertz radiation to modulate the optical properties of semiconductors. Here we demonstrate the dynamical control of photoluminescence (PL) emission in…

A scanning tunneling microscope (STM) can do more than atomic imaging and manipulation. Its tunneling current can also be used for the excitation of light, converting electron energy to photon energy. STM based single-molecule…

Optics · Physics 2019-01-01 Yao Zhang , Yang Zhang , Zhenchao Dong

Two-dimensional (2D) materials and heterostructures have recently gained wide attention due to potential applications in optoelectronic devices. However, the optical properties of the heterojunction have not been properly characterized due…

Applied Physics · Physics 2020-01-29 Zachary H Withers , Sharad Ambardar , Xiaoyi Lai , Jiru Liu , Alina Zhukova , Dmitri V Voronine

Light sources on the scale of single molecules can be addressed and characterized on their proper sub-nanometer scale by scanning tunneling microscopy induced luminescence (STML). Such a source can be driven by defined short charge pulses…

Mesoscale and Nanoscale Physics · Physics 2021-06-15 Anna Rosławska , Pablo Merino , Christopher C. Leon , Abhishek Grewal , Markus Etzkorn , Klaus Kuhnke , Klaus Kern

Scanning the sharp metal tip of a scanning tunneling microscope (STM) over a molecule allows tuning the coupling between the tip plasmon and a molecular fluorescence emitter. This allows access to local variations of fluorescence field…

Mesoscale and Nanoscale Physics · Physics 2025-07-09 Abhishek Grewal , Hiroshi Imada , Kuniyuki Miwa , Miyabi Imai-Imada , Kensuke Kimura , Rafael Jaculbia , Klaus Kuhnke , Klaus Kern , Yousoo Kim

The tip of a scanning tunnelling microscope can inject hot electrons into a surface with atomic precision. Their subsequent dynamics and eventual decay can result in atomic manipulation of an adsorbed molecule, or in light emission from the…

Chemical Physics · Physics 2019-07-19 Rebecca M. Purkiss , Henry G. Etheridge , Peter A. Sloan , Kristina R. Rusimova

The radiance of thermal emission, as described by Planck law, depends only on the emissivity and temperature of a body, and increases monotonically with the temperature rise at any emitted wavelength. Nonthermal radiation, such as…

Optics · Physics 2020-12-23 N Kruger , M Kurtulik , N Revivo , A Manor , T Sabapathy , C Rotschild

Understanding the fundamental mechanisms of optoelectronic excitation and relaxation pathways on the single-molecule level has only recently been started by combining scanning tunneling microscopy (STM) and spectroscopy (STS) with…

We investigate the modification of photoluminescence (PL) from single semiconductor nanocrystal quantum dots (NCs) in proximity of metal and semiconducting Atomic Force Microscope (AFM) tips. The presence of the tip alters the radiative…

Chemical Physics · Physics 2016-09-28 Yuval Ebenstein , Eyal Yoskovitz , Ronny Costi , Asaf Aharoni , Uri Banin

The interplay between the oxidation state and the optical properties of molecules plays a key role for applications in displays, sensors or molecular-based memories. The fundamental mechanisms occurring at the level of a single-molecule…

Mesoscale and Nanoscale Physics · Physics 2018-08-15 Benjamin Doppagne , Michael C. Chong , Hervé Bulou , Alex Boeglin , Fabrice Scheurer , Guillaume Schull

Single molecule detection, sequencing and conformational mapping of aptamers are important for improving medical and biosensing technologies and for better understanding of biological processes at the molecular level. We obtain vibrational…

Biomolecules · Quantitative Biology 2016-12-05 Siyu He , Hongyuan Li , Zhe He , Dmitri V. Voronine

The coupling of nanostructures with emitters opens ways for the realization of man-made subwavelength light emitting elements. In this article, we investigate the modification of fluorescence when an emitter is placed close to a…

Other Condensed Matter · Physics 2009-11-13 S. Kuehn , G. Mori , M. Agio , V. Sandoghdar

In this article we present coherent control of above-threshold photoemission from a tungsten nanotip achieving nearly perfect modulation. Depending on the pulse delay between fundamental (1560 nm) and second harmonic (780 nm) pulses of a…

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